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Missouri University of Science and Technology

Chemical Engineering

Mechanical and Aerospace Engineering Faculty Research & Creative Works

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Full-Text Articles in Mechanical Engineering

Synergic Titanium Nitride Coating And Titanium Doping By Atomic Layer Deposition For Stable- And High-Performance Lifepo₄, Yan Gao, Jonghyun Park, Xinhua Liang Dec 2018

Synergic Titanium Nitride Coating And Titanium Doping By Atomic Layer Deposition For Stable- And High-Performance Lifepo₄, Yan Gao, Jonghyun Park, Xinhua Liang

Mechanical and Aerospace Engineering Faculty Research & Creative Works

Atomic layer deposition (ALD) method has emerged as a promising technique to address the dissolution and poor conductivity of electrode materials of lithium ion batteries. In this work, surface modification of LiFePO4 (LFP) was carried out by titanium nitride (TiN) ALD, during which a Ti doping into LFP occurred simultaneously. X-ray photoelectron spectroscopy (XPS) and electrochemical tests were performed to prove the Ti doping, and the composition of TiN layer on the surface of LFP particles was interpreted as a combination of TiN and titanium oxynitride (TiOxNy). Owing to the synergy of TiN coating and …


Shape-Based Separation Of Micro-/Nanoparticles In Liquid Phases, Behrouz Behdani, Saman Monjezi, Mason J. Carey, Curtis G. Weldon, Jie Zhang, Cheng Wang, Joontaek Park Sep 2018

Shape-Based Separation Of Micro-/Nanoparticles In Liquid Phases, Behrouz Behdani, Saman Monjezi, Mason J. Carey, Curtis G. Weldon, Jie Zhang, Cheng Wang, Joontaek Park

Mechanical and Aerospace Engineering Faculty Research & Creative Works

The production of particles with shape-specific properties is reliant upon the separation of micro-/nanoparticles of particular shapes from particle mixtures of similar volumes. However, compared to a large number of size-based particle separation methods, shape-based separation methods have not been adequately explored. We review various up-to-date approaches to shape-based separation of rigid micro-/nanoparticles in liquid phases including size exclusion chromatography, field flow fractionation, deterministic lateral displacement, inertial focusing, electrophoresis, magnetophoresis, self-assembly precipitation, and centrifugation. We discuss separation mechanisms by classifying them as either changes in surface interactions or extensions of size-based separation. The latter includes geometric restrictions and shape-dependent transport …


Effect Of Viscoplastic Flow Rules On The Initiation And Growth Of Shear Bands At High Strain Rates, R. C. Batra, Chang-Soo Kim Jan 1990

Effect Of Viscoplastic Flow Rules On The Initiation And Growth Of Shear Bands At High Strain Rates, R. C. Batra, Chang-Soo Kim

Mechanical and Aerospace Engineering Faculty Research & Creative Works

Marchand and Duffy have reported detailed measurements of the temperature and strain as a shear band develops in a HY-100 steel. Assuming their torsional tests in thin-wall tubes can be adequately modeled by a viscoplastic block undergoing overall adiabatic simple shearing deformations, we investigate the effect of modeling the viscoplastic response of the material by a.power law, and flow rules proposed by Litonski, Bodner and Partom, and Johnson and Cook. Each of these flow rules is first calibrated by using the test data at a nominal strain-rate of 3300 s-1. Then predictions from the use of these flow rules at …