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Full-Text Articles in Mechanical Engineering
Electrochemical Glucose Sensors Enhanced By Methyl Viologen And Vertically Aligned Carbon Nanotube Channels, Benjamin J. Brownlee, Meisam Bahari, John H. Harb, Jonathan C. Claussen, Brian D. Iverson
Electrochemical Glucose Sensors Enhanced By Methyl Viologen And Vertically Aligned Carbon Nanotube Channels, Benjamin J. Brownlee, Meisam Bahari, John H. Harb, Jonathan C. Claussen, Brian D. Iverson
Faculty Publications
Free-standing, vertically aligned carbon nanotubes (VACNTs) were patterned into 16 μm diameter microchannel arrays for flow-through electrochemical glucose sensing. Non-enzymatic sensing of glucose was achieved by the chemical reaction of glucose with methyl viologen (MV) at an elevated temperature and pH (0.1 M NaOH), followed by the electrochemical reaction of reduced-MV with the VACNT surface. The MV sensor required no functionalization (including no metal) and was able to produce on average 3.4 electrons per glucose molecule. The current density of the MV sensor was linear with both flow rate and glucose concentration. Challenges with interference chemicals were mitigated by operating …
Electrochemical Glucose Sensors Enhanced By Methyl Viologen And Vertically Aligned Carbon Nanotube Channels, Benjamin J. Brownlee, Meisam Bahari, John N. Harb, Jonathan C. Claussen, Brian D. Iverson
Electrochemical Glucose Sensors Enhanced By Methyl Viologen And Vertically Aligned Carbon Nanotube Channels, Benjamin J. Brownlee, Meisam Bahari, John N. Harb, Jonathan C. Claussen, Brian D. Iverson
Faculty Publications
Freestanding, vertically aligned carbon nanotubes (VACNTs) were patterned into 16 μm diameter microchannel arrays for flow-through electrochemical glucose sensing. Non-enzymatic sensing of glucose was achieved by the chemical reaction of glucose with methyl viologen (MV) at an elevated temperature and pH (0.1 M NaOH), followed by the electrochemical reaction of reduced-MV with the VACNT surface. The MV sensor required no functionalization (including no metal) and was able to produce on average 3.4 electrons per glucose molecule. The current density of the MV sensor was linear with both flow rate and glucose concentration. Challenges with interference chemicals were mitigated by operating …
Bubble Nucleation In Superhydrophobic Microchannels Due To Subcritical Heating, Adam Cowley, Daniel Maynes, Julie Crockett, Brian D. Iverson
Bubble Nucleation In Superhydrophobic Microchannels Due To Subcritical Heating, Adam Cowley, Daniel Maynes, Julie Crockett, Brian D. Iverson
Faculty Publications
This work experimentally studies the effects of single wall heating on laminar flow in a high-aspect ratio superhydrophobic microchannel. When water that is saturated with air is used as the working liquid, the non-wetted cavities on the superhydrophobic surfaces act as nucleation sites and allow air to effervesce out of the water and onto the surface when heated. Previous works in the literature have only considered the opposite case where the water is undersaturated and absorbs air out the cavities for a microchannel setting. The microchannel considered in this work consists of a rib/cavity structured superhydrophobic surface and a glass …