Mechanical Engineering Commons^™

System Analysis Of An Internal Combustion Engine (Ice) – Solid Oxide Fuel Cell (Sofc) Hybrid Cycle, Jose Javier Colon Rodriguez

Graduate Theses, Dissertations, and Problem Reports

Due to the intermittent nature of renewable energy and the rigid operation of existing coal plants, the need for flexible power generation technology is eminent. Hybrid energy systems have shown potential for flexible, grid following dynamics while maintaining higher efficiencies. The work below focuses on the performance analysis of a proposed 100 kW pressurized Internal Combustion Engine (ICE) and Solid Oxide Fuel Cell (SOFC) hybrid system. The un-utilized fuel from the SOFC stack provided the chemical energy to operate the engine. A turbocharger was used to deliver the necessary air flow for both the stack and engine. An external reformer …

Stability Of Ruddlesden-Popper Phase Lanthanum Nickelate As Air Electrode For Reversible Solid Oxide Cells, Daniel De Lorenzo Moreira

Graduate Theses, Dissertations, and Problem Reports

This thesis studied the long-term stability of Ruddlesden-Popper phase Lanthanum Nickelate under operating conditions as the air electrode for Reversible Solid Oxide Cells (R-SOC). Renewable energies have gone through increase in popularity throughout the last decades, mainly due to the consequences of the rapid population growth in the world. These new energies have been pointed as the rightful successor of fossil fuel energies in order to decrease the environmental impact of our day-to-day life. Solid Oxide Fuel Cells as well as Solid Oxide Electrolysis Cells are believed to be the key to stabilizing the energy supply when environmental conditions are …

Transient Analysis Of A Solid Oxide Fuel Cell/ Gas Turbine Hybrid System For Distributed Electric Propulsion, Venkata Adithya Chakravarthula

Browse all Theses and Dissertations

Gas turbine technology for aerospace applications are approaching limits in efficiency gains as increases in efficiency today occurs in very small increments. One limitation in conventional gas turbine technology is the combustion process, which destroys most of the exergy in the cycle. To address this limitation in a traditional Brayton power cycle, a hybrid system which is integrated with Solid Oxide Fuel Cell (SOFC) and gas turbine is developed. Hybrid systems involving fuel cells have better efficiencies than conventional power generation systems. Power generation systems with improved performance from low fuel utilizations and low maintenance costs are possible. The combination …

Analysis Of A Fuel Cell Combustor In A Solid Oxide Fuel Cell Hybrid Gas Turbine Power System For Aerospace Application, Ryan R. Sinnamon

Browse all Theses and Dissertations

Over the last few years, fuel cell technology has significantly advanced and has become a mode of clean power generation for many engineering applications. Currently the dominant application for fuel cell technology is with stationary power generation. Very little has been published for applications on mobile platforms, such as unmanned aerial vehicles. With unmanned aerial vehicles being used more frequently for national defense and reconnaissance, there is a need for a more efficiency, longer endurance power system that can support the increased electrical loads onboard. It has already been proven by others that fuel cell gas turbine hybrid systems can …

Modeling Of Chemical-Mechanical Couplings In Solid Oxide Cells And Reliability Analysis, Xinfang Jin

Theses and Dissertations

Solid oxide fuel cell (SOFC) has been well demonstrated as a promising clean energy conversion technology. For practical applications, the SOFC systems should have both good electrochemical performance and high reliability. The SOFCs are usually operated under very aggressive conditions, e.g., high temperatures (600-1000oC) and extremely low oxygen partial pressures (anode electrode). These aggressive operating conditions could lead to a variety of material system degradations, imposing great challenges on meeting lifetime requirement of SOFC commercial applications. It is therefore essential to increase the understanding of fundamental SOFC degradation mechanisms.

The basic structure of SOFCs is a positive electrode-electrolyte-negative electrode (PEN) …

Multi-Physicochemical Modeling Of Solid Oxide Fuel Cells And Electrolyzer Cells, Yuanyuan Xie

Theses and Dissertations

Multi-physicochemical models are developed for solid oxide fuel cells and electrolysis cells. The models describe the complicated transport processes of charge (electron/ion) conservation, mass/species conservation, momentum conservation, and energy conservation. Transport processes are coherently coupled with chemical reforming processes, surface elementary reaction processes, as well as electro-oxidation processes of both hydrogen and carbon monoxide. The models are validated with experimental data and utilized for fundamental mechanism studies of SOFCs fueled with different type of fuels, such as hydrogen, hydrocarbon, e.g., methane, H2S, and their mixtures. The fundamental mechanisms associated with syngas generation using electrolysis cell are also extensively investigated using …