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Full-Text Articles in Mechanical Engineering

Porphyrin Interaction With Dna-Based Carbon Nanotubes And Regeneration For Light Harvesting, Sawyer E. Morgan, Hanyu Zhang, Jong Hyun Choi Aug 2014

Porphyrin Interaction With Dna-Based Carbon Nanotubes And Regeneration For Light Harvesting, Sawyer E. Morgan, Hanyu Zhang, Jong Hyun Choi

The Summer Undergraduate Research Fellowship (SURF) Symposium

Limitations to current solar cells include the high cost of pure silicon and poor current transfer within cells. An emerging alternative is single-walled carbon nanotubes (SWCNTs), which when combined with DNA and porphyrin chromophores can generate a current when absorbing light. We sought to find a chromophore and conditions that would promote bonding to the SWCNTs and improve light harvesting, while being able to regenerate on the film after being damaged. This was experimentally tested by first making SWCNT films on conducting glass slides. These were then functionalized in solutions of chromophore and spectra were measured to determine the bonding …


Dna Based Carbon Nanotube Porphyrin Nanohybrids Molecular Recognization And Regeneration, Molly M. Riccitelli, Hanyu Zhang, Jong Hyun Choi Oct 2013

Dna Based Carbon Nanotube Porphyrin Nanohybrids Molecular Recognization And Regeneration, Molly M. Riccitelli, Hanyu Zhang, Jong Hyun Choi

The Summer Undergraduate Research Fellowship (SURF) Symposium

In the search to improve solar cells, scientists are exploring new materials that will provide better current transfer. One material that has emerged as a strong contender is the single walled carbon nanotube (SWNT). Current DNA-SWNT based films combined with chromophores have poor operational lifetimes compared to commercial solar cells. Once exposed to light the chromophore begins to degrade, eventually rendering the solar cell unusable. To solve this problem, we used a method involving multiple steps. First we found which DNA sequences formed structures around the SWNT that could hold the most chromophores by using a spectrophotometer to test the …


Synthesis And Characterization Of Nucleic Acid-Functionalized Nanomaterials, Brianna S. Carroll, Jong Hyun Choi Oct 2013

Synthesis And Characterization Of Nucleic Acid-Functionalized Nanomaterials, Brianna S. Carroll, Jong Hyun Choi

The Summer Undergraduate Research Fellowship (SURF) Symposium

Motor proteins such as kinesin move along microtubules in order to transport cellular cargos throughout the cell by obtaining energy from RNA hydrolysis which allows the cell to complete the tasks needed to stay alive. In this work, we developed synthetic molecular motors using DNA enzymes (DNAzyme) and fluorescent nanomaterials which mimic the functions and structures of motor proteins. A DNAzyme-capped CdS nanoparticle and a RNA-functionalized single-walled carbon nanotube (SWCNT) were used as a walker and a track in the motor platform, respectively. As a walking mechanism, the DNAzyme cleaved the RNA substrates in the presence of metal cations. The …