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Synthesis And Characterization Of Poly(Butylene Oxide) Grafted Carbon Nanofibers, Carlos Ramos, Ram Thapa, Karen Lozano, Mircea Chipara, Domingo Ferrer, Jose J. Gutierrez
Synthesis And Characterization Of Poly(Butylene Oxide) Grafted Carbon Nanofibers, Carlos Ramos, Ram Thapa, Karen Lozano, Mircea Chipara, Domingo Ferrer, Jose J. Gutierrez
Mechanical Engineering Faculty Publications and Presentations
The grafting of polybutylene oxide onto purified and functionalized carbon nanofibers is reported. Grafting was possible after the insertion of 2-(formyloxy)ethyl 2-bromo-2-methylpropanoate onto the carbon nanofibers. The polymerization of tetrahydrofuran was mediated by copper(I) bromide and 1,1,4,7-pentamethyl diethylenetriamine. The polymer-grafted carbon nanofibers were characterized by Raman spectrsocopy, Transmission Electron Microscopy, and Thermogravimetric Analysis. TEM images of CNF-COOH (A), CNF-PBO (B), completely open tip of CNF-COOH, and coated tip of CNF-PBO (D) are shown in the left panel. The right panel depicts the distribution of bromine (blue), and carbon (red) atoms inside and in the vicinity of CNF-Br (as obtained by …