Mechanical Engineering Commons^™

Incorporation Of Poly(Tfema) In Perovskite Thin Films Using A Supercritical Fluid, Kasey Handy, Gary C. Tepper

Mechanical and Nuclear Engineering Publications

A new process is reported for the incorporation of a fluoropolymer into a solid perovskite film. Poly(trifluoroethyl methacrylate) [CH₂C(CH₃)(CO₂CH₂CF₃)]_n was delivered to methylammonium lead iodide (CH₃NH₃PbI₃) perovskite films by crystallizing the film in supercritical carbon dioxide/ethanol containing the dissolved fluoropolymer. The surface was characterized before and after fluoropolymer exposure using scanning electron microscopy, Raman spectroscopy, and contact angle measurements. The results indicate that the fluoropolymer was incorporated into the perovskite film during the supercritical fluid crystallization process. The incorporation of a hydrophobic fluoropolymer …

Laser-Induced Breakdown Spectroscopy (Libs) In A Novel Molten Salt Aerosol System, Ammon N. Williams, Supathorn Phongikaroon

Mechanical and Nuclear Engineering Publications

In the pyrochemical separation of used nuclear fuel (UNF), fission product, rare earth, and actinide chlorides accumulate in the molten salt electrolyte over time. Measuring this salt composition in near real-time is advantageous for operational efficiency, material accountability, and nuclear safeguards. Laser-induced breakdown spectroscopy (LIBS) has been proposed and demonstrated as a potential analytical approach for molten LiCl–KCl salts. However, all the studies conducted to date have used a static surface approach which can lead to issues with splashing, low repeatability, and poor sample homogeneity. In this initial study, a novel molten salt aerosol approach has been developed and explored …

Effects Of Roughness On Droplet Apparent Contact Angles On A Fiber, M. M. Amrei, M. Davoudi, G. G. Chase, H. Vahedi Tafreshi

Mechanical and Nuclear Engineering Publications

This paper reports on our investigation of the effects of surface roughness on the equilibrium shape and apparent contact angles of a droplet deposited on a fiber. In particular, the shape of a droplet on a roughened fiber is studied via the energy minimization method implemented in the surface evolver finite element code. Sinusoidal roughness varying in both the longitudinal and radial directions is considered in the simulations to study the effects of surface roughness on the most stable shape of a droplet on a fiber (corresponding a global minimum energy state). It is found that surface roughness delays droplet …

In Defense Of Science—What Would John Do?, Mohamed Gad-El-Hak

Mechanical and Nuclear Engineering Publications

Recent onslaughts on the importance of pure research to our collective well-being are trending. In this essay, I discuss the issues involved and offer a rebuttal. The thoughts are inspired by my mentor, academic sibling, and idol John Leask Lumley.

A Simulation Study Of A Radiofrequency Localization System For Tracking Patient Motion In Radiotherapy, Mark Ostyn, Siyong Kim, Woon-Hong Yeo

Mechanical and Nuclear Engineering Publications

One of the most widely used tools in cancer treatment is external beam radiotherapy. However, the major risk involved in radiotherapy is excess radiation dose to healthy tissue, exacerbated by patient motion. Here, we present a simulation study of a potential radiofrequency (RF) localization system designed to track intrafraction motion (target motion during the radiation treatment). This system includes skin-wearable RF beacons and an external tracking system. We develop an analytical model for direction of arrival measurement with radio frequencies (GHz range) for use in a localization estimate. We use a Monte Carlo simulation to investigate the relationship between a …

An Injection And Mixing Element For Delivery And Monitoring Of Inhaled Nitric Oxide, Andrew R. Martin, Chris Jackson, Samuel Fromont, Chloe Pont, Ira M. Katz, Georges Caillobotte

Mechanical and Nuclear Engineering Publications

Background

Inhaled nitric oxide (NO) is a selective pulmonary vasodilator used primarily in the critical care setting for patients concurrently supported by invasive or noninvasive positive pressure ventilation. NO delivery devices interface with ventilator breathing circuits to inject NO in proportion with the flow of air/oxygen through the circuit, in order to maintain a constant, target concentration of inhaled NO.

Methods

In the present article, a NO injection and mixing element is presented. The device borrows from the design of static elements to promote rapid mixing of injected NO-containing gas with breathing circuit gases. Bench experiments are reported to demonstrate …

Microstructured Thin Film Nitinol For A Neurovascular Flow-Diverter, Yanfei Chen, Connor Howe, Yongkuk Lee, Seongsik Cheon, Woon-Hong Yeo, Youngjae Chun

Mechanical and Nuclear Engineering Publications

A cerebral aneurysm occurs as a result of a weakened blood vessel, which allows blood to flow into a sac or a ballooned section. Recent advancement shows that a new device, ‘flow-diverter’, can divert blood flow away from the aneurysm sac. People found that a flow-diverter based on thin film nitinol (TFN), works very effectively, however there are no studies proving the mechanical safety in irregular, curved blood vessels. Here, we study the mechanical behaviors and structural safety of a novel microstructured TFN membrane through the computational and experimental studies, which establish the fundamental aspects of stretching and bending mechanics …

Young's Modulus Of [111] Germanium Nanowires, M. Maksud, J. Yoo, C. T. Harris, N. K. R. Palapati, A. Subramanian

Mechanical and Nuclear Engineering Publications

This paper reports a diameter-independent Young’s modulus of 91.9 ± 8.2 GPa for [111] Germaniumnanowires (Ge NWs). When the surface oxide layer is accounted for using a core-shell NW approximation, the YM of the Ge core approaches a near theoretical value of 147.6 ± 23.4 GPa. The ultimate strength of a NW device was measured at 10.9 GPa, which represents a very high experimental-to-theoretical strength ratio of ∼75%. With increasing interest in this material system as a high-capacity lithium-ion battery anode, the presented data provide inputs that are essential in predicting its lithiation-induced stress fields and fracture behavior.

Hybrid Tio2 Solar Cells Produced From Aerosolized Nanoparticles Of Water-Soluble Polythiophene Electron Donor Layer, Marshall L. Sweet, Joshua G. Clarke, Dmitry Pestov, Gary C. Tepper, James T. Mcleskey Jr.

Mechanical and Nuclear Engineering Publications

Hybrid solar cells (HSCs) with water soluble polythiophene sodium poly[2-(3-thienyl)-ethyloxy-4-butylsulfonate] (PTEBS) thin films produced using electrospray deposition (ESD) were fabricated, tested, and modeled and compared to devices produced using conventional spin coating. A single device structure of FTO/TiO2/PTEBS/Au was used to study the effects of ESD of the PTEBS layer on device performance. ESD was found to increase the short circuit current density (J_sc) by a factor of 2 while decreasing the open circuit voltage (V_oc) by half compared to spin coated PTEBS films. Comparable efficiencies of 0.009% were achieved from both device construction types. Current-voltage …

Self-Healing Of Ionomeric Polymers With Carbon Fibers From Medium-Velocity Impact And Resistive Heating, Vishnu Baba Sundaresan, Andrew Morgan, Matt Castellucci

Mechanical and Nuclear Engineering Publications

Self-healing materials science has seen significant advances in the last decade. Recent efforts have demonstrated healing in polymeric materials through chemical reaction, thermal treatment, and ultraviolet irradiation. The existing technology for healing polymeric materials through the aforementioned mechanisms produces an irreversible change in the material and makes it unsuitable for subsequent healing cycles. To overcome these disadvantages, we demonstrate a new composite self-healing material made from an ionomer (Surlyn) and carbon fiber that can sustain damage from medium-velocity impact and heal from the energy of the impact. Furthermore, the carbon fiber embedded in the polymer matrix results in resistive heating …

On Applications And Limitations Of One-Dimensional Capillarity Formulations For Media With Heterogeneous Wettability, T. M. Bucher, H. Vahedi Tafreshi

Mechanical and Nuclear Engineering Publications

Force-balance-based one-dimensional algebraic formulations that are often used in characterizing the capillarity of a multi-component system (e.g., predicting capillary height rise inporous media) are discussed. It is shown that such formulations fail to provide accurate predictions when the distribution of wetting (or non-wetting) surfaces is not homogeneous. A more general mathematical formulation is suggested and used to demonstrate that for media with heterogeneous wettability, hydrophilic (or hydrophobic) surfaces clustered in groups will have less contribution to the overall capillarity of the system.

Evolutionary Optimization Of Electronic Circuitry Cooling Using Nanofluid, Manu Mital

Mechanical and Nuclear Engineering Publications

Liquid cooling electronics using microchannels integrated in the chips is an attractive alternative to bulky aluminum heat sinks. Cooling can be further enhanced using nanofluids. The goals of this study are to evaluate heat transfer in a nanofluid heat sink with developing laminar flow forced convection, taking into account the pumping power penalty. The proposed model uses semi-empirical correlations to calculate effective nanofluid thermophysical properties, which are then incorporated into heat transfer and friction factor correlations in literature for single-phase flows. The model predicts the thermal resistance and pumping power as a function of four design variables that include the …

Optimizing Fiber Cross-Sectional Shape For Improving Stability Of Air–Water Interface Over Superhydrophobic Fibrous Coatings, B. Emami, Hooman Vahedi Tafreshi

Mechanical and Nuclear Engineering Publications

In this letter, a mathematical force-balance formulation is developed that can be used to predict the critical pressure, the hydrostaticpressure above which the surface starts to depart from the non-wetting state, for superhydrophobicsurfaces comprised of highly aligned fibers (e.g., biased AC-electrospun coatings) with arbitrary cross-sectional shapes. We have also developed a methodology for optimizing the fiber cross-sections to maximize the critical pressure of the surface, using the Euler–Lagrange equation. A case study is presented to better demonstrate the application of our method.

Predicting Shape And Stability Of Air–Water Interface On Superhydrophobic Surfaces Comprised Of Pores With Arbitrary Shapes And Depths, B. Emami, Dr. Hooman Vahedi Tafreshi, M. Gad-El-Hak, Gary C. Tepper

Mechanical and Nuclear Engineering Publications

An integro-differential equation for the three dimensional shape of air–water interface on superhydrophobicsurfaces comprised of pores with arbitrary shapes and depths is developed and used to predict the static critical pressure under which such surfaces depart from the non-wetting state. Our equation balances the capillary forces with the pressure of the air entrapped in the pores and that of the water over the interface. Stability of shallow and deep circular, elliptical, and polygonal pores is compared with one another and a general conclusion is drawn for designing pore shapes for superhydrophobicsurfaces with maximum stability.

Effect Of Fiber Orientation On Shape And Stability Of Air-Water Interface On Submerged Superhydrophobic Electrospun Thin Coatings, B. Emami, H. Vahedi Tafreshi, M. Gad-El-Hak, G. C. Tepper

Mechanical and Nuclear Engineering Publications

To better understand the role of fiber orientation on the stability of superhydrophobicelectrospun coatings under hydrostaticpressures, an integro-differential equation is developed from the balance of forces across the air–water interface between the fibers. This equation is solved numerically for a series of superhydrophobicelectrospun coatings comprised of random and orthogonal fiber orientations to obtain the exact 3D shape of the air–water interface as a function of hydrostaticpressure. More important, this information is used to predict the pressure at which the coatings start to transition from the Cassie state to the Wenzel state, i.e., the so-called critical transition pressure. Our results indicate …

Predicting Shape And Stability Of Air–Water Interface On Superhydrophobic Surfaces With Randomly Distributed, Dissimilar Posts, B. Emami, Hooman Vahedi Tafreshi, M. Gad-El-Hak, Gary C. Tepper

Mechanical and Nuclear Engineering Publications

A mathematical framework developed to calculate the shape of the air–water interface and predict the stability of a microfabricated superhydrophobicsurface with randomly distributed posts of dissimilar diameters and heights is presented. Using the Young–Laplace equation, a second-order partial differential equation is derived and solved numerically to obtain the shape of the interface, and to predict the critical hydrostatic pressure at which the superhydrophobicity vanishes in a submersed surface. Two examples are given for demonstration of the method’s capabilities and accuracy.

Bennett Clocking Of Nanomagnetic Logic Using Multiferroic Single-Domain Nanomagnets, Jayasimha Atulasimha, Supriyo Bandyopadhyay

Mechanical and Nuclear Engineering Publications

The authors show that it is possible to rotate the magnetization of a multiferroic (strain-coupled two-layer magnetostrictive-piezoelectric)nanomagnet by a large angle with a small electrostatic potential. This can implement Bennett clocking [Int. J. Theor. Phys.21, 905 (1982)] in nanomagnetic logic arrays resulting in unidirectional propagation of logic bits from one stage to another. This method is potentially more energy efficient than using spin-transfer torque for magnetization rotation. For realistic parameters, it is shown that a potential of ∼0.2 V applied to a multiferroicnanomagnet can rotate magnetization by nearly 90° to implement Bennett clocking.

Hydrothermal Preparation Of Gd+3 -Doped Titanate Nanotubes: Magnetic Properties And Photovoltaic Performance, Hoda S. Hafez, M Saif, James T. Mcleskey Jr., M.S.A. Abdel-Mottaleb, I S. Yahia, T Story, W Knoff

Mechanical and Nuclear Engineering Publications

Pure and Gd+3 -doped titanate nanotubes (TNTs) materials were synthesized by a hydrothermal method. Their morphology, optical properties, thermal stability, and magnetic properties were characterized by X-ray diffraction (XRD), transmission electron microscope (TEM), UV-Vis spectroscopy, thermal analysis, and magnetic measurements. It was found that doping renders Gd+3-TNT visible light active and results in smaller crystallite size and larger surface area as well as higher thermal stability compared to pure titanate nanotubes. The estimated magnetic moments point to presence of weak antiferromagnetic interaction. Application of the prepared Gd+3-TNT for modifying conventional photoanodes in polymer solar cells was attempted. Preliminary results show …

Nanostructured Solid-State Hybrid Photovoltaic Cells Fabricated By Electrostatic Layer-By-Layer Deposition, Rolf Kniprath, James T. Mcleskey Jr., Jürgen P. Rabe, Stefan Kirstein

Mechanical and Nuclear Engineering Publications

We report on the fabrication of hybrid organic/inorganic photovoltaic cells utilizing layer-by-layer deposition of water-soluble polyions and nanocrystals. A bulk heterojunction structure was created consisting of alternating layers of the p-conductive polythiophene derivative poly[2-(3-thienyl)-ethoxy-4-butylsulfonate] and n-conductive TiO2nanoparticles. We fabricated working devices with the heterostructure sandwiched between suitable charge carrier blocking layers and conducting oxide and metal electrodes, respectively. We analyzed the influence of the thickness and nanostructure of the active layer on the cell performance and characterized the devices in terms of static and transient current response with respect to illumination and voltage conditions. We observed reproducible and stable photovoltaic …

A Realistic Modeling Of Fluid Infiltration In Thin Fibrous Sheets, Sudhakar Jaganathan, Hooman Vahedi Tafreshi, Behnam Pourdeyhimi

Mechanical and Nuclear Engineering Publications

In this paper, a modeling study is presented to simulate the fluid infiltration in fibrous media. The Richards’ equation of two-phase flow in porous media is used here to model the fluid absorption in unsaturated/partially saturated fibrous thin sheets. The required consecutive equations, relative permeability, and capillary pressure as functions of medium’s saturation are obtained via fiber-level modeling and a long-column experiment, respectively. Our relative permeability calculations are based on solving the Stokes flow equations in partially saturated three-dimensional domains obtained by imaging the sheets’ microstructures. The Richards’ equation, together with the above consecutive correlations, is solved for fibrous media …

Correlation Of Tellurium Inclusions And Carrier Lifetime In Detector Grade Cadmium Zinc Telluride, Ezzat S. Elshazly, Gary C. Tepper

Mechanical and Nuclear Engineering Publications

Carrier lifetimes and telluriuminclusion densities in detector grade cadmiumzinc telluride crystals grown by the high pressure Bridgman method were optically measured using pulsed laser microwavecavity perturbation and infrared microscopy. Excess carriers were produced in the material using a pulsed laser with a wavelength of 1064 nm and pulse width of 7 ns, and the electronic decay was measured at room temperature. Spatial mapping of lifetimes and defect densities in cadmiumzinc telluride was performed to determine the relationship between telluriumdefect density and trapping. A strong correlation was found between the volume fraction of telluriuminclusions and the carrier trapping time.

Electrokinetic Separation Of Co-Solutes Into Bimodal Fibers By Electrospinning, Chunya Wu, Shinobu Nagata, Gary C. Tepper, James T. Mcleskey Jr.

Mechanical and Nuclear Engineering Publications

Composite and chemically/physically distinct fibers of sodium poly[2-(3-thienyl)-ethoxy-4-butylsulfonate] (PTEBS) and polyethylene oxide (PEO) were formed by electrospinning from a homogeneous aqueous solution containing PTEBS and PEO co-solutes. Composite nanofibers of diameter of ∼60nm were electrospun from an aqueous solution. The addition of ammonium hydroxide (NH4OH) to the water solution resulted in “bimodal” electrospun fibers consisting of distinct large diameter white PEO fiber segments and small diameter black PTEBS fiber segments. The optical absorptionspectrum of the composite PTEBS/PEO nanofibers did not exhibit the characteristic peak around 460nm, which is present in the bulk spectrum.

Geometrical Modeling Of Fibrous Materials Under Compression, Benoit Maze, Hooman Vahedi Tafreshi, Behnam Pourdeyhimi

Mechanical and Nuclear Engineering Publications

Many fibrous materials such as nonwovens are consolidated via compaction rolls in a so-called calendering process. Hot rolls compress the fiber assembly and cause fiber-to-fiber bonding resulting in a strong yet porous structure. In this paper, we describe an algorithm for generating three dimensional virtual fiberwebs and simulating the geometrical changes that happen to the structure during the calendering process. Fibers are assumed to be continuous filaments with square cross sections lying randomly in the x or y direction. The fibers are assumed to be flexible to allow bending over one another during the compression process. Lateral displacement is not …

An Electrospray-Based, Ozone-Free Air Purification Technology, Gary Tepper, Royal Kessick, Dmitry Pestov

Mechanical and Nuclear Engineering Publications

A zero-pressure-drop, ozone-free air purification technology is reported. Contaminated air was directed into a chamber containing an array of electrospray wick sources. The electrospray sources produce an aerosol of tiny, electrically charged aqueous droplets.Charge was transferred from the droplets onto polar and polarizable species in the contaminated air stream and the chargedcontaminants were extracted using an electric field and deposited onto a metal surface. Purified air emerged from the other end of the chamber. The very small aqueous electrospray droplets completely evaporate so that the process is essentially dry and no liquid solvent is collected or recirculated. The air purification …

Hybrid Solar Cells From Water-Soluble Polymers, James T. Mcleskey Jr., Qiquan Qiao

Mechanical and Nuclear Engineering Publications

We report on the use of a water-soluble, light-absorbing polythiophene polymer to fabricate novel photovoltaic devices. The polymer is a water-soluble thiophene known as sodium poly[2-(3-thienyl)-ethoxy-4-butylsulfonate] or PTEBS. The intention is to take advantage of the properties of conjugated polymers (flexible, tunable, and easy to process) and incorporate the additional benefits of water solubility (easily controlled evaporation rates and environmentally friendly). The PTEBS polythiophene has shown significant photovoltaic response and has been found to be effective for making solar cells. To date, solar cells in three different configurations have been produced: titanium dioxide (TiO2) bilayer cells, TiO2 bulk heterojunction solar …

Water-Soluble Polythiophene∕Nanocrystalline Tio2 Solar Cells, Qiquan Qiao, James T. Mcleskey Jr.

Mechanical and Nuclear Engineering Publications

We report the characteristics of polymer∕nanocrystalline solar cells fabricated using an environmentally friendly water-soluble polythiophene and TiO2 in a bilayer configuration. The cells were made by dropping the polymer onto a TiO2nanocrystallinefilm and then repeatedly sweeping a clean glass rod across the polymer as it dried. The devices showed an open circuit voltage of 0.81 V, a short circuit current density of 0.35mA/cm2, a fill factor of 0.4, and an energy conversion efficiency of 0.13%. The water-soluble polythiophene showed significant photovoltaic behavior and the potential for use in solar cells.

Characteristics Of Water-Soluble Polythiophene: Tio2 Composite And Its Application In Photovoltaics, Qiquan Qiao, Lianyong Su, James Beck, James T. Mcleskey Jr.

Mechanical and Nuclear Engineering Publications

We have studied the characteristics of composites of an environmentally friendly water-soluble polythiophene sodium poly[2-(3-thienyl)-ethoxy-4-butylsulfonate] (PTEBS) and TiO2. We observed that the ultraviolet-visible absorption spectrum of low molecular weight PTEBS is redshifted possibly due to the formation of aggregates. Cyclic voltammetry reveals the values of highest occupied molecular orbitals and lowest unoccupied molecular orbitals for PTEBS. A factor of 7 in photoluminescence quenching indicates that the exciton dissociation and charge separation occur successfully at the PTEBS: TiO2 (1:1 by weight) interface. This enhances the possibility that the separated charges will reach the electrodes before recombining. Scanning electron micrograph images show …

Microscale Polymeric Helical Structures Produced By Electrospinning, Royal Kessick, Gary C. Tepper

Mechanical and Nuclear Engineering Publications

Microscale helical coils consisting of a composite of one conducting and one nonconducting polymer were produced using electrospinning. The nonconducting polymer was poly(ethylene oxide) and the conducting polymer was poly(aniline sulfonic acid). The coil structures were studied over a range of processing conditions and fiber composition. The data suggest that the helical structures are formed due to viscoelastic contraction upon partial neutralization of the charged fibers. Polymeric microcoils may find applications in microelectromechanical systems, advanced optical components, and drug delivery systems.