Mechanical Engineering Commons^™

Thermomechanical Properties Of Novel Lanthanum Zirconate Based Thermal Barrier Coatings - An Integrated Experimental And Modeling Study, Xingye Guo

Open Access Dissertations

Thermal barrier coatings (TBCs) are refractory materials deposited on gas turbine components, which provide thermal protection for metallic components at operating conditions. The current state-of-art TBC material is yttria-stabilized zirconia (YSZ), whose service temperature is limited to 1200 celsius, due to sintering and phase transition at higher temperatures. In comparison, lanthanum zirconate (La2Zr2O7, LZ) has become a promising candidate material for TBCs due to its lower thermal conductivity and higher phase stability compared to YSZ.

The primary objective of this thesis is to design a novel robust LZ-based TBC system suitable for applications beyond 1200 celsius. Due to LZ’s low …

Size Scaling Of Strength And Toughness For 3d Printed Polymer Specimens, Darren Thomas Bell

Open Access Theses

To find material systems that offer low density and high strength, stiffness or toughness, hierarchically designed material systems have provided a promising research area. This thesis lays the groundwork for designing efficient micro-architectured material systems by characterizing size effects for 3d printed polymer parts. Two methods were used to analyze data from 3-point bend tests for specimens of varying size: the load-separation method was used for finding the point of crack growth initiation and Bazant’s method was used to find shape independent strength at failure. The strength values were used as inputs for finding size independent material constants within a …

Energy Localization And Heat Generation In Composite Energetic Systems Under High-Frequency Mechanical Excitation, Jesus O. Mares

Open Access Dissertations

In this work, the ability to use high frequency mechanical excitation to generate significant heating within plastic bonded explosives, as well as single energetic particles embedded within a viscoelastic binder, is studied. In this work, the fundamental mechanisms associated with the conversion of high-frequency mechanical excitation to heat as applied to these composite energetic systems are thoroughly investigated.

High-frequency contact excitation has been used to generate a significant amount of heat within samples of PBX 9501 and representative inert mock materials. Surface temperature rises on the order of 10 °C were observed at certain frequencies over a range from 50 …

Passive Thermal Management Using Phase Change Materials, Yash Yogesh Ganatra

Open Access Theses

The trend of enhanced functionality and reducing thickness of mobile devices has led to a rapid increase in power density and a potential thermal bottleneck since thermal limits of components remain unchanged. Active cooling mechanisms are not feasible due to size, weight and cost constraints. This work explores the feasibility of a passive cooling system based on Phase Change Materials (PCMs) for thermal management of mobile devices. PCMs stabilize temperatures due to the latent heat of phase change thus increasing the operating time of the device before threshold temperatures are exceeded. The primary contribution of this work is the identification …

Modeling Transport Phenomena And Uncertainty Quantification In Solidification Processes, Kyle S. Fezi

Open Access Dissertations

Direct chill (DC) casting is the primary processing route for wrought aluminum alloys. This semicontinuous process consists of primary cooling as the metal is pulled through a water cooled mold followed by secondary cooling with a water jet spray and free falling water. To gain insight into this complex solidification process, a fully transient model of DC casting was developed to predict the transport phenomena of aluminum alloys for various conditions. This model is capable of solving mixture mass, momentum, energy, and species conservation equations during multicomponent solidification. Various DC casting process parameters were examined for their effect on transport …

Modeling Picking On Pharmaceutical Tablets, Shrikant Swaminathan

Open Access Dissertations

Tablets are the most popular solid dosage form in the pharmaceutical industry because they are cheap to manufacture, chemically and mechanically stable and easy to transport and fairly easy to control dosage. Pharmaceutical tableting operations have been around for decades however the process is still not well understood. One of the common problems faced during the production of pharmaceutical tablets by powder compaction is sticking of powder to the punch face, This is known as 'sticking'. A more specialized case of sticking is picking when the powder is pulled away form the compact in the vicinity of debossed features. In …

Analytical And Experimental Investigation Of Microstructural Alterations In Bearing Steel In Rolling Contact Fatigue, Sina Mobasher Moghaddam

Open Access Dissertations

Rolling Contact Fatigue (RCF) is one the most common failure modes in bearings. RCF is usually associated with particular microstructural alterations. Such alterations (i.e. white etching cracks, butterflies, etc.) which lead to RCF failure are known to be among the most concerning matters to bearing industry.

In the current work, an analytical as well as experimental approaches are used to investigate “butterfly wing” formation, crack initiation and propagation from inclusions. A new damage evolution equation coupled with a FE model is employed to account for the effect of mean stresses and alternating stresses simultaneously to investigate butterfly formation. The proposed …

Machining As A Mechanical Property Test Revisited, David L. Smith

Open Access Theses

There is much need for data on mechanical behavior of metals at high strains and strain rates. This need is dictated by modeling of processes like forming and machining, wherein the material in the deformation zone is subjected to severe deformation conditions atypical of conventional material property tests such as tension and torsion. Accurate flow stress data is an essential input for robust prediction of process outputs. Similar requirements arise from applications in high speed ballistic penetration and design of materials for armor. Since the deformation zone in cutting of metals is characterized by unique and extreme combinations of strain, …

Delamination Of C/Pekk I-Beam Using Virtual Crack Closure Technique And Cohesive Zone Method, Greeshma Ramakrishna

Open Access Theses

A damage study is conducted on a carbon epoxy/PEKK (poly-ether-ketone-ketone) thermoplastic composite I-Beam, with a pre crack of 100 mm modeled between the top flange and the filler (butt joint between filler and web). This project is in collaboration with Fokker Aerostructures, Netherlands and is part of the Thermoplastic Primary Aircraft Structure innovation program (TAPAS). The C/PEKK I-Beam is modeled after a section of the Gulfstream G650 aircraft's centre beam, which was previously a carbon fiber/epoxy hat-stiffened skin construction. The objective of the thesis is to identify if the crack propagates in the I-Beam within the load range that act …

The Role Of Microstructure On The Combustion And Impact Behavior Of Mechanically Activated Nickel/Aluminum Reactive Composites, Benjamin Aaron Mason

Open Access Dissertations

Metal-based reactive composites are a class of materials that consist of at least one metals, such as Ni/Al, that have high-energy densities and can produce significant energy output during exothermic reaction after thermal or mechanical initiation. However, conventionally these materials typically have slow reaction rates and are difficult to ignite at typical micron particle size ranges limiting their application. Therefore, mechanical activation techniques have been used to create materials with high surface areas and smaller characteristic dimensions in order to increase combustion velocity and ignition sensitivity. Their combustion and mechanical impact behavior is being studied to develop the understanding needed …

Investigation Of Microstructural Alterations In M50 And 52100 Steel Using Nanoindentation, Kristin R. Paulson

Open Access Theses

Bearing steels are used in rolling elements and are designed to withstand heavy loads for an extended period of time. At the end of life, microstructural alterations within the material have been observed and are linked to failure. In this study, a three ball-on-rod fatigue tester was used to test M50 and 52100 steel cylindrical rods at differing loads of 4.0 GPa, 4.5 GPa, and 5.0 GPa and in lubricated and unlubricated conditions to 10 8 cycles in an attempt to produce microstructural alterations. Microstructural alterations characterized as butterflies were observed and investigated further in two M50 samples that were …

Measurement Of The Responses Of Polyurethane And Confortm Foams And The Development Of A System Identification Technique To Estimate Polyurethane Foam Parameters From Experimental Impulse Responses, Vaidyanadan Sundaram

Open Access Theses

Flexible polyurethane foam is the main cushioning element used in car seats. Optimization of an occupied seat's static and dynamic behavior requires models of foam that are accurate over a wide range of excitation and pre-compression conditions. Experiments were conducted to measure the response of foam over a wide range of excitation which include slowly varying uniaxial compression tests on a 3 inch cube foam sample, base excitation and impulse excitation test on a foam-mass system. The foam used was the same in all of the experiments, thus obtaining all the responses on the same foam sample which helps eliminate …

Dissolution Rate And Mechanism Of Metals In Molten Aluminum Alloy A380, Hengyu Zhu

Open Access Theses

Shot sleeve is a very easily worn out part in a high-pressure die-casting machine due to serious dissolution of the area underneath the pouring hole. It is because during a normal pouring process, the high temperature molten aluminum will impact and dissolve that area of the shot sleeve by complex chemical and physical process. Rotation experiment was carried out to H13 and four kinds of refractory metal samples. SEM and EDS pictures were taken in order to investigate the microstructure and the dissolution mechanism of these materials. This suggests a high strength niobium is an ideal material for that area …

Synthesis And Characterization Of Bulk Metallic Glasses Prepared By Laser Direct Deposition, Xiaoyang Ye

Open Access Theses

Fe-based and Zr-based metallic glasses have attracted extensive interest for structural applications due to their excellent glass forming ability, superior mechanical properties, unique thermal and corrosion properties. In this study, the feasibility of synthesizing metallic glasses with good ductility by laser direct deposition is explored. Both in-situ synthesis with elemental powder mixture and ex-situ synthesis with prealloyed powder are discussed. Microstructure and properties of laser direct deposited metallic glass composites are analyzed.^ Synthesis of Fe-Cr-Mo-W-Mn-C-Si-B metallic glass composite with a large fraction of amorphous phase was accomplished using laser direct deposition. X-ray diffraction (XRD) and transmission electron microscopy investigations revealed …

Solution To Certain Problems In The Failure Of Composite Structures, Jonathan Goodsell

Open Access Dissertations

The present work contains the solution of two problems in composite structures. In the first, an approximate elasticity solution for prediction of the displacement, stress and strain fields within the m-layer, symmetric and balanced angle-ply composite laminate of finite-width subjected anticlastic bending deformation is developed. The solution is shown to recover classical laminated plate theory predictions at interior regions of the laminate and thereby illustrates the boundary layer character of this interlaminar phenomenon. The results exhibit the anticipated response in congruence with the solutions for uniform axial extension and uniform temperature change, where divergence of the interlaminar shearing stress is …

Mechanisms Of Microstructure Formation Under The Influence Of Ultrasonic Vibrations, Milan Rakita

Open Access Dissertations

Positive effects of ultrasound on crystallization have been known for almost 90 years. Application of ultrasound has been very successful in many industries, most notably in chemistry, creating a new branch of science - sonochemistry. However, ultrasonication has not found wide commercial application in the solidification processing. The reason for that is the complexity of underlying phenomena and the lack of predicting models which correlate processing parameters with the properties of a product. The purpose of this study is to give some contribution toward better understanding of mechanisms that lead to changes in the solidifying microstructure. It has been found …

Synthesis Of Graphene Nanomaterials And Their Application In Electrochemical Energy Storage, Guoping Xiong

Open Access Dissertations

The need to store and use energy on diverse scales in a modern technological society necessitates the design of large and small energy systems, among which electrical energy storage systems such as batteries and capacitors have attracted much interest in the past several decades. Supercapacitors, also known as ultracapacitors, or electrochemical capacitors, with fast power delivery and long cycle life are complementing or even replacing batteries in many applications. The rapid development of miniaturized electronic devices has led to a growing need for rechargeable micro-power sources with high performance. Among different sources, electrochemical micro-capacitors or micro-supercapacitors provide higher power density …