Mechanical Engineering Commons^™

Heat-Driven Self-Cooling System Based On Thermoelectric Generation Effect, Robel Kiflemariam

FIU Electronic Theses and Dissertations

This research entails the first comprehensive and systematic study on a heat-driven, self-cooling application based on the thermoelectric generation effect. The system was studied using the first and second laws of thermodynamics to provide a solid and basic understanding of the physical principles governing the system. Multiphysics equations that relate heat transfer, fluid dynamics and thermoelectric generation are derived. The equations are developed with increasing complexity, from the basic Carnot heat engine to externally and internally irreversible engines. A computational algorithm to systematically use the fundamental equations has been presented and computer code is implemented based on the algorithm.

Experiments …

Modeling Of Chemical-Mechanical Couplings In Anode-Supported Solid Oxide Fuel Cells And Reliability Analysis, Xinfang Jin, Xingjian Xue

Xingjian "Chris" Xue

Oxygen ionic transport in conducting ceramics is an important mechanism enabling solid oxide fuel cell (SOFC) technology. The multi-physicochemical processes lead to the fact that the distribution of oxygen vacancy site fraction is not uniform in a positive-electrode electrolyte negative-electrode (PEN) assembly. Different oxygen vacancy concentrations induce different volumetric expansion of ceramics, resulting in complicated chemical–mechanical coupling phenomena and chemical stress in SOFCs. In this research, a mathematical model is developed to study oxygen ionic transport induced chemical stress in an SOFC. The model is validated using experimental polarization curves. Comprehensive simulations are performed to investigate chemical stress distribution in …

In Situ Synthesis Of Ultrafine Ss-Mno2/Polypyrrole Nanorod Composites For High-Performance Supercapacitors, Jianfeng Zang, Xiaodong Li

Xiaodong Li

We report a remarkable observation that is at odds with the established notion that β-MnO2 was regarded as an undesirable candidate for supercapacitor applications. The specific capacitance of β-MnO2 can reach as high as 294 F g−1, which is comparable to the best crystallographic structure, like α-MnO2. The key is to substantially decrease the size of β-MnO2 powders to ultra small regime. We demonstrate a facile, simple, and effective approach to synthesizing ultrafine (<10 nm in diameter) β-MnO2/polypyrrole nanorod composite powders for high-performance supercapacitor electrodes. Our observation may encourage a revisit of the other good or even bad candidate …