Mechanical Engineering Commons^™

Synthesis Of Sea Urchin-Like Nico2o4 Via Charge-Driven Self-Assembly Strategy For High Performance Lithium-Ion Batteries, Bin Wang, Chi-Wing Tsang, Ka Ho Li, Yuanyuan Tang, Yanping Mao, Xiao-Ying Lu

Faculty of Science & Technology (THEi)

In this study, hydrothermal synthesis of sea urchin-like NiCo2O4 was successfully demonstrated by a versatile charge-driven self-assembly strategy using positively charged poly(diallydimethylammonium chloride) (PDDA) molecules. Physical characterizations implied that sea urchin-like microspheres of ~ 2.5 μm in size were formed by self-assembly of numerous nanoneedles with a typical dimension of ~ 100 nm in diameter. Electrochemical performance study confirmed that sea urchin-like NiCo2O4 exhibited high reversible capacity of 663 mAh g−1 after 100 cycles at current density of 100 mA g−1. Rate capability indicated that average capacities of 1085, 1048, 926, 642, 261, and 86 mAh g−1 could be achieved …