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Full-Text Articles in Mechanical Engineering
Techno-Economic Analysis Of A Secondary Air Stripper Process, J. R. Heberle, Heather Nikolic, Jesse Thompson, Kunlei Liu, Lora L. Pinkerton, David Brubaker, James C. Simpson, Song Wu, Abhoyjit S. Bhown
Techno-Economic Analysis Of A Secondary Air Stripper Process, J. R. Heberle, Heather Nikolic, Jesse Thompson, Kunlei Liu, Lora L. Pinkerton, David Brubaker, James C. Simpson, Song Wu, Abhoyjit S. Bhown
Center for Applied Energy Research Faculty and Staff Publications
We present results of an initial techno-economic assessment on a post-combustion CO2 capture process developed by the Center for Applied Energy Research (CAER) at the University of Kentucky using Mitsubishi Hitachi Power Systems’ H3-1 aqueous amine solvent. The analysis is based on data collected at a 0.7 MWe pilot unit combined with laboratory data and process simulations. The process adds a secondary air stripper to a conventional solvent process, which increases the cyclic loading of the solvent in two ways. First, air strips additional CO2 from the solvent downstream of the conventional steam-heated thermal stripper. This extra stripping …
Thermal Degradation Pathways Of Aqueous Diamine Co2 Capture Solvents, Jesse Thompson, Henry Richburg, Kunlei Liu
Thermal Degradation Pathways Of Aqueous Diamine Co2 Capture Solvents, Jesse Thompson, Henry Richburg, Kunlei Liu
Center for Applied Energy Research Faculty and Staff Publications
Diamines have shown promise as CO2 capture solvents, yet very little is known about their pathway for thermal degradation. In this study, diamine thermal degradation was quantitatively monitored in lab-scale experiments on four aqueous diamine solvents; ethylenediamine (EDA) 1,2-propanediamine (1,2-DAP), 1,3-diaminopropane (1,3-DAP) and N-methyl-1,2-ethanediamine (NMEDA), to gain a more comprehensive understanding of their degradation pathway(s). The major degradation products were identified by high resolution time-of-flight mass spectrometry (TOF-MS). Degradation pathways were proposed showing that the primary thermal degradation route for this class of amine are through carbamate formation followed by intermolecular cyclization to form an imidazolidinone or nucleophilic attack …
Solubility And Thermodynamic Modeling Of Carcinogenic Nitrosamines In Aqueous Amine Solvents For Co2 Capture, Jesse Thompson, Naser Matin, Kunlei Liu
Solubility And Thermodynamic Modeling Of Carcinogenic Nitrosamines In Aqueous Amine Solvents For Co2 Capture, Jesse Thompson, Naser Matin, Kunlei Liu
Center for Applied Energy Research Faculty and Staff Publications
A better understanding of key fundamental properties of nitrosamines, including their solubility in aqueous amine solvents, is needed to understand and accurately model the vapor-phase emission levels from operating CO2 capture systems. In this work, the first experimental Henry's volatility coefficient of a nitrosamine was obtained with a novel method using static headspace solid phase micro extraction (SPME) and gas chromatography mass spectrometry (GC/MS). The experimentally determined Henry's volatility coefficient of nitrosopyrrolidine (NPY) was found to be around 0.02 (dimensionless) at 25 °C, and falls in the range of a semi-volatile compound. A linear temperature dependency of the Henry's …