Mechanical Engineering Commons^™

Interfacial Engineering Of Nickel-Rich Layered Oxide Cathodes Via Atomic Layer Deposition (Ald), Xin Wang

Graduate Theses and Dissertations

Layered nickel-rich cathodes LiNixMnyCozO2 (NMCs, x + y + z =1, x ≥ 0.6) are regarded as one of the most promising cathode materials for next-generation lithium-ion batteries (LIBs), given their remarkably reduced cost and increased capacity compared to the conventional LiCoO2 cathode. However, the deployment of these Ni-rich cathodes has been hindered by the continuous loss of practical capacity and reduction in average working voltage, inherently due to their interfacial, structural, and thermodynamic instability. To address these issues, interfacial engineering via surface modification has been well-recognized as an effective strategy and a large number of coating materials have been …

Hobby Grade Lithium-Ion Batteries For Spacecraft Applications: Establishing An Automated Electrical Characteristics Testing Procedure For Flight Acceptance Of Non-Space-Grade Small Secondary Batteries, Braidon Hughes

Graduate Theses and Dissertations

Li-ion batteries are widely used due to the large amount of rechargeable energy they pack into a small, light package. This higher energy density makes Li-ion batteries ideal for small satellite applications, specifically CubeSats. CubeSats have grown in popularity in higher level education due to the National Aeronautics and Space Administration’s implementation of the Cube Satellite Launch Initiative, making it easier and cheaper to conduct small, low orbit missions. Because these CubeSats are occupying the same space as a crewed spacecraft, it is imperative that they are safe. There are numerous reports of Li-ion batteries creating fires that result in …

Nonmetallic Jet Impingement Thermal Management For Power Electronics Via Additive Manufacturing, Reece Whitt

Graduate Theses and Dissertations

The increase in energy demanded by transportation and energy sectors has necessitated highly efficient thermal management for reliable power electronics operations. Conventional cooling techniques are limited by their inability to target switching location hot spot temperatures, leading to non-uniform thermal gradients. These devices, such as cold plates and heat sinks, also utilize heavy metallic structures that can accentuate electromagnetic interferences generated by high voltage switching processes. This work proposes a non-metallic jet impingement cooler for more customized thermal management, while simultaneously reducing the harmful effects of electromagnetic interferences. Additive manufacturing is utilized to enable jet impingement zones to target individual …

Combined Stressors In Reliability Failure Modes In Flip-Chip Electronic Packaging, Mahsa Montazeri

Graduate Theses and Dissertations

The trend toward miniaturization of electronic devices to fulfill Moore’s law introduces new reliability concerns to the electronic packaging process while worsening existing primary challenges. In solder interconnect specifically, temperature cycling is one of the prominent failure threats. However, with further downscaling of the flip-chip solder connections, electromigration also present a precarious failure mode in these interconnects. On the other hand, understanding the degradation mechanism in solders is crucial for the power electronic products' reliability considering the industrial tendency to replace wirebonds with solder attachment while improving the current carry capacity. This dissertation utilizes FEA simulation and an experimental approach …

Mission Profile Effects On Automotive Drivetrain Electronics Reliability: Modeling And Mitigation, Bakhtiyar Mohammad Nafis

Graduate Theses and Dissertations

The reliability of electronic devices is dependent upon the conditions to which they are subject. Temperature variations coupled with differences in thermal expansion between bonded materials results in thermomechanical stresses to build up, which can instigate failure in the interconnects or other critical regions. With the move towards electrification in the automotive industry, there is the increasingly important consideration of powertrain electronics reliability, the pertinent conditions being governed by the drive cycle or mission profile of the vehicle. The mission profile determines the power dissipated by the electronic devices, which determines the peak and mean temperature, temperature swing and the …

Development Of Novel Battery Materials For Lithium-Ion Batteries And Beyond, Jiyu Cai

Graduate Theses and Dissertations

As fossil fuels are depleting and causing environmental issues, it becomes imperative to widely implement renewable energies (e.g., solar and wind power). In this context, electrical energy storage (EES) systems are essential to accommodate the intermittent supply and uneven distribution of renewable energies. To this end, high-energy-density EES devices are highly demanded, such as rechargeable batteries. This dissertation presents my efforts in developing novel battery materials for lithium-ion batteries (LIBs), sodium-ion batteries (SIBs), and solidstate lithium batteries (SSLBs). These efforts include electrochemical evaluations of battery materials, surface modifications of electrodes via atomic layer deposition (ALD), and advanced characterizations of batteries …

High Temperature Degradation In Gan-Based Hall Effect Sensors, Alexis Anne Krone

Graduate Theses and Dissertations

This research focuses on understanding the effects of accelerated aging through temperature and environment on novel gallium nitride-based Hall effect magnetic field sensors and determining device reliability under electric vehicle operating conditions. The device reliability was modeled using accelerated aging for the temperatures of 200 °C, 350 °C, 450 °C, and 600 °C under various time steps unique to each temperature and either air, which is identical to operating circumstances, or argon, which would model the hermetic packaging environment. Using a high temperature furnace and oven, devices underwent high temperature storage tests at a chosen temperature and time step. Afterwards, …

Towards A Cyber-Physical Manufacturing Cloud Through Operable Digital Twins And Virtual Production Lines, Md Rakib Shahriar

Graduate Theses and Dissertations

In last decade, the paradigm of Cyber-Physical Systems (CPS) has integrated industrial manufacturing systems with Cloud Computing technologies for Cloud Manufacturing. Up to 2015, there were many CPS-based manufacturing systems that collected real-time machining data to perform remote monitoring, prognostics and health management, and predictive maintenance. However, these CPS-integrated and network ready machines were not directly connected to the elements of Cloud Manufacturing and required human-in-the-loop. Addressing this gap, we introduced a new paradigm of Cyber-Physical Manufacturing Cloud (CPMC) that bridges a gap between physical machines and virtual space in 2017. CPMC virtualizes machine tools in cloud through web services …

Exploring Convergence Of Snake Skin-Inspired Texture Designs And Additive Manufacturing For Mechanical Traction, Catherine Sue Tiner

Graduate Theses and Dissertations

This research focuses on the understanding, development, and additive manufacture of a 3D printed snake skin-inspired texture pattern. The design functionalities of snake skin were determined through the study of the snake species Python Regius otherwise known as the ball python. Each scale of a snake has hierarchical texture with hexagonal macro-patterns aligned on the ventral surface of the skin with overriding anisotropic micro textured patterns such as denticulations and fibrils. Using a laser-powder bed fusion (L-PBF) process, 420 stainless steel samples were 3D printed which closely resemble the above described directional texture of natural snake skin. This printed surface …

Microextrusion 3d Printing Of Optical Waveguides And Microheaters, Edidiong Nseowo Udofia

Graduate Theses and Dissertations

The drive for smaller and more compact devices presents several challenges in materials and fabrication strategies. Although photolithography is a well-developed method for creating microdevices, the disparate requirements in fabrication strategies, material choices, equipment and process complexities have limited its applications. Microextrusion printing (μEP) provides a promising alternative for microfabrication. Compared to the traditional techniques, the attractions lie in the wide range of printable material choice, greater design freedom, fewer processing steps, lower cost for customized production, and the plurality of compatible substrates. However, while extrusion-based 3D printing processes have been successfully applied at the macroscale, this seeming simplicity belies …

The Role Of Inter-Particle Behavior In Iron Oxide Nanoparticle Induction Heating, Hayden Seth Carlton

Graduate Theses and Dissertations

Due to their multi-functional nature, iron oxide nanoparticles present themselves in a myriad of scientific disciplines, but perhaps the most interesting property of these nanomaterials can be seen in their immense thermal response under the influence of alternating magnetic fields. Currently popularized as an alternative cancer treatment through localized hyperthermia, iron oxide nanoparticle induction heating presents an interesting physical phenomenon that distinguishes itself from macroscopic induction heating. Understanding how a single spherical particle behaves is relatively simple and remains well documented; however, magnetic interactions of a single particle often extend over many length scales, affecting numerous neighboring particles in the …

Interfacial Tailoring Of Lithium-Ion Batteries By Atomic/Molecular Layer Deposition, Qian Sun

Graduate Theses and Dissertations

Lithium-ion batteries (LIBs) are promising energy storage devices, which play significant roles in addressing problems related to fossil fuels depletion and environmental pollution. Since the 1990s, LIBs have attracted great attention for many applications. Nowadays, LIBs are dominating portable electronics, having several advantages over their forerunners, such as high voltage (3.3~4.2 V) [1,2], low self-discharge (< 5~10 %/month) [3,4], wide operation temperature (-20~60 °C) [5,6], and fast charge/discharge rate [7,8]. However, LIBs deliver an energy density of 100-220 Wh/kg in practice to date, which is far from their theoretical ones, thus hindering their further applications in electric vehicles. Additionally, LIBs have been plagued by other problems, such as intolerance to overcharge/overdischarge, low heat resistance, lithium dendrites growth, large volume change of the silicon anode, large polarization and even safety problems.

Atomic layer deposition (ALD) and molecular layer deposition (MLD) are two important techniques, both proceeding in self-limiting gas-solid reactions and exhibiting excellent capabilities for ultra-thin films, conformal coatings, and controllable growth. They can be employed to address the problems of LIBs mentioned above by …

Development Of A Rapid Fatigue Life Testing Method For Reliability Assessment Of Flip-Chip Solder Interconnects, Cody Jackson Marbut

Graduate Theses and Dissertations

The underlying physics of failure are critical in assessing the long term reliability of power packages in their intended field applications, yet traditional reliability determination methods are largely inadequate when considering thermomechanical failures. With current reliability determination methods, long test durations, high costs, and a conglomerate of concurrent reliability degrading threat factors make effective understanding of device reliability difficult and expensive. In this work, an alternative reliability testing apparatus and associated protocol was developed to address these concerns; targeting rapid testing times with minimal cost while preserving fatigue life prediction accuracy. Two test stands were fabricated to evaluate device reliability …

Comparative Study Of Power Semiconductor Devices In A Multilevel Cascaded H-Bridge Inverter, Kenneth Mordi

Graduate Theses and Dissertations

This thesis compares the performance of a nine-level transformerless cascaded H-bridge (CHB) inverter with integrated battery energy storage system (BESS) using SiC power MOSFETs and Si IGBTs. Two crucial performance drivers for inverter applications are power loss and efficiency. Both of these are investigated in this thesis. Power devices with similar voltage and current ratings are used in the same inverter topology, and the performance of each device is analyzed with respect to switching frequency and operating temperature. The loss measurements and characteristics within the inverter are discussed. The Saber® simulation software was used for the comparisons. The power MOSFET …

Microheater Array Powder Sintering (Maps) For Printing Flexible Electronics, Nicholas Holt

Graduate Theses and Dissertations

Microheater array powder sintering (MAPS) is a novel additive manufacturing process that uses an array of microheaters to selectively sinter powder particles. MAPS shows great promise as a new method of printing flexible electronics by enabling digital curing of conductive inks on a variety of substrates. MAPS operation relies on establishing a precision air gap of a few microns between an array of microheaters, which can reach temperatures of 600°C, and a layer of conductive ink which can be deposited onto a flexible substrate. This system presents challenges, being: the fabrication of a microheater that can reach suitable temperatures in …

Fluid Phase Separation Via Nanochannel Array, John Lee

Graduate Theses and Dissertations

Microelectromechanical systems (MEMS) and nanoelectromechanical systems (NEMS) generate ideas and techniques for creating new devices at the micro/nano scale. This dissertation study designed a gas generator system utilizing nanochannels for phase separation that is useful for micro-pneumatic actuators, micro-valves, and micro-pumps. The new gas generator has the potential to be an integral part of a propulsion system for small-scale satellites. Nano/picosatellites have limited orientation capability partly due to the current limitations of microthruster devices. Development of a self-contained micro propulsion system enables dynamic orbital maneuvering of pico- and nano-class satellites.

Additionally, the new gas generator utilizes a high efficiency, green …

Modeling Radiation Heat Transfer For Building’S Cooling And Heating Loads: Considering The Role Of Clear, Cloudy, And Dusty Conditions In Hot And Dry Climates, Salem Ahmed Algarni

Graduate Theses and Dissertations

The influence of transient factors such as sky long wave radiation exchange and atmospheric aerosols (i.e., smog, and dust – made up of sand, clay, and silt) are not carefully considered in current building design and simulation models. Therefore, the research objective was to better understand and account for such variables, resulting in improved radiative predictive capabilities, especially important for hot and dry climates under different sky conditions including clean, cloudy, and dusty. Overall, results of this dissertation provided a better prediction method for sky long wave radiation exchange with a building’s roof and the impact of dust accumulation on …

Swelling-Etching Characterization Of Copper (I) Oxide - Pdms For The Development Of Micro/Nano - Particles Composite Mems Corrosion Sensor, Abdoul Kader Maiga

Graduate Theses and Dissertations

The primary objective for this thesis is to contribute to the understanding of the oxide removal process for a corrosion sensing device. The goal for designing such a device is for monitoring corrosion on metallic structures. The sensing material (6.35mm x 1mm discs) of the device is composed of copper (I) oxide particles mixed in some polydimethylsiloxane (PDMS). The PDMS, “housing,” is meant for controlling the oxidation rate through the sensing material. A solvent was used to facilitate the etchant diffusion through the PDMS matrix. Toluene and acetic acid were the ideal solvent and etchant, respectively, for carrying out the …

Crack Growth Behavior Under Creep-Fatigue Conditions Using Compact And Double Edge Notch Tension-Compression Specimens, Santosh B. Narasimha Chary

Graduate Theses and Dissertations

The American Society for Testing and Materials (ASTM) has recently developed a new standard for creep-fatigue crack growth testing, E 2760-10, that supports testing compact specimens, C(T), under load controlled conditions. C(T) specimens are commonly used for fatigue and creep-fatigue crack growth testing under constant-load-amplitude conditions. The use of these specimens is limited to positive load ratios. They are also limited in the amount of crack growth data that can be developed at high stress intensity values due to accumulation of plastic and/or creep strains leading to ratcheting in the specimen. Testing under displacement control can potentially address these shortcomings …

Development Of A Pdms Based Micro Total Analysis System For Rapid Biomolecule Detection, Balaji Srinivasan Venkatesh

Graduate Theses and Dissertations

The emerging field of micro total analysis system powered by microfluidics is expected to revolutionize miniaturization and automation for point-of-care-testing systems which require quick, efficient and reproducible results. In the present study, a PDMS based micro total analysis system has been developed for rapid, multi-purpose, impedance based detection of biomolecules. The major components of the micro total analysis system include a micropump, micromixer, magnetic separator and interdigitated electrodes for impedance detection. Three designs of pneumatically actuated PDMS based micropumps were fabricated and tested. Based on the performance test results, one of the micropumps was selected for integration. The experimental results …

Development Of Mems-Based Corrosion Sensor, Feng Pan

Graduate Theses and Dissertations

This research is to develop a MEMS-based corrosion sensor, which is used for monitoring uniform, galvanic corrosion occurring in infrastructures such as buildings, bridges. The corrosion sensor is made up of the composite of micro/nano metal particles with elastomers. The mechanism of corrosion sensor is based on the mass transport of corrosive species through the sensor matrix. When the metal particles in the matrix corrode, the electrical resistivity of the material increases due to increasing particle resistances or reduction of conducting pathways. The corrosion rate can be monitored by detecting the resistivity change in sensing elements. The life span of …

Silica Nanoparticle-Based Coatings With Superhydrophilic And Superhydrophobic Properties, Robert Andrew Fleming

Graduate Theses and Dissertations

Superhydrophilic and superhydrophobic surfaces have potential for implementation into a variety of fields, including self-cleaning surfaces, anti-fogging transparent materials, and biomedical applications. In this study, sandblasting, oxygen plasma treatments, silica nanoparticle films, and a low surface energy fluorocarbon film were employed to change the natural surface wettability of titanium, glass, and polyethylene terephthalate (PET) substrates, with an aim to produce superhydrophilic and superhydrophobic behavior. The effects of these surface modifications are characterized by water contact angles (WCAs), surface wetting stability, surface morphology and roughness, surface elemental composition, and optical transmittance measurements. The results show that stable superhydrophilic and superhydrophobic surfaces …

Design, Fabrication, Testing Of Cnt Based Isfet And Characterization Of Nano/Bio Materials Using Afm, Zhuxin Dong

Graduate Theses and Dissertations

A combination of Carbon Nanotubes (CNTs) and Ion Selective Field Effect Transistor (ISFET) is designed and experimentally verified in order to develop the next generation ion concentration sensing system. Micro Electro-Mechanical System (MEMS) fabrication techniques, such as photolithography, diffusion, evaporation, lift-off, packaging, etc., are required in the fabrication of the CNT-ISFET structure on p-type silicon wafers. In addition, Atomic Force Microscopy (AFM) based surface nanomachining is investigated and used for creating nanochannels on silicon surfaces. Since AFM based nanomanipulation and nanomachining is highly controllable, nanochannels are precisely scratched in the area between the source and drain of the FET where …

Computational Design Of The Electrical And Mechanical Performance Of Steerable Mems Antennas, Morgan Andrew Roddy

Graduate Theses and Dissertations

This thesis describes the origins, improvements, and variations of a broadband microwave antenna that can be beam-steered by a micro-electromechanical system (MEMS). The steerable MEMS antenna of this work was comprised of a planar antenna on top of a Silicon membrane. The membrane is etched to create a gimbal hinge structure and a platform which supported the antenna and gave it one or two degrees of freedom of rotation. The antennas presented were broadband and fed by a coplanar waveguide (CPW) transmission line which traversed the hinge structure. The antenna's orientation in space was designed to be changed through electrostatic …

Design And Implementation Of A Small Electric Motor Dynamometer For Mechanical Engineering Undergraduate Laboratory, Aaron Farley

Graduate Theses and Dissertations

This thesis set out to design and implement a new experiment for use in the second lab of the laboratory curriculum in the Mechanical Engineering Department at the University of Arkansas in Fayetteville, AR. The second of three labs typically consists of data acquisition and the real world measurements of concepts learned in the classes at the freshman and sophomore level. This small electric motor dynamometer was designed to be a table top lab setup allowing students to familiarize themselves with forces, torques, angular velocity and the sensors used to measure those quantities, i.e. load cells and optical encoders. The …

Understanding The Role Of A Bio-Inspired Surface Modification For Delayed Icing, Clayton Schenk

Graduate Theses and Dissertations

Atmospheric icing event is problematic for outdoor structures because it can damage, slow, impede, and danger general routine. For a wind turbine blade, it can damage, disrupt movement, and cause potentially dangerous ice throw. Anti-icing based on a surface texture is advantageous due to the low cost of maintenance and there is no additional requirement of energy output for preventing the icing problem. This work is based on the biomimicry of the superhydrophobic nature of the lotus leaf, whereas the limited wettability supports the water to flow freely from the surface structure. The phenomenon is based on a morphology and …

A Solid State Nitrogen Gas Generating Chip And Applications For Picosatellites, Kyle Godin

Graduate Theses and Dissertations

A microscale gas generating chip has many applications; in this study, applications relating to picosatellites have been considered. Cube satellites, a type of picosatellite, are of mass around one kilogram and side length 10cm x 10cm x 10cm. Their launches are becoming more numerous since their debut ten years ago. Their low cost and deployment system makes space accessible to agencies hitherto barred from it, such as universities and small governments. However, their power, mass, and volume budget is extremely tight. A microscale gas chip could compete with other designs for attitude control devices, most not flown yet as cube …