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Full-Text Articles in Mechanical Engineering

Carbon Dioxide Gasification Of Biochar: A Study On Utilizing Captured Co2 To Mitigate Greenhouse Gas Emission And Improving Carbon Conversion Efficiency, Nnamdi Ofuani Jan 2024

Carbon Dioxide Gasification Of Biochar: A Study On Utilizing Captured Co2 To Mitigate Greenhouse Gas Emission And Improving Carbon Conversion Efficiency, Nnamdi Ofuani

Electronic Theses and Dissertations

With rapidly growing global economies and world population, fossil fuel continues to play a major role in meeting current energy demands. Carbon capture and storage (CCS) technologies have, hence, been implemented to reduce CO2 emissions in the atmosphere. With the implementation of CCS technologies comes the need to utilize the captured CO2. This research, therefore, proposes CO2 gasification of biochar as a viable carbon utilization pathway. With captured CO2 coming at various concentrations, there is a need to understand how CO2 concentration affects biochar conversion to useful products. This study, therefore, evaluates the effects …


Dry Reforming Of Methane Using Microwave Irradiated Metal Oxide/Coal Char Catalysts, Anthony Carter Jan 2021

Dry Reforming Of Methane Using Microwave Irradiated Metal Oxide/Coal Char Catalysts, Anthony Carter

Graduate Theses, Dissertations, and Problem Reports

This research focuses on the synthesis of both shaped and amorphous powder materials, the combination of these materials with dried Powder River Basin (PRB) coal char, and their reactionary properties with methane and carbon dioxide gasses with conventional and microwave (MW) heating. The first goal of this project was to synthesize shaped micro and nano sized particles with ideal dielectric properties for converting electromagnetic energy into heat and proven capabilities of activating methane. These particles were synthesized via solvothermal, hydrothermal, and co-preceptory treatments alone and onto the surface of dried PRB coal char. PRB is a sub-bituminous, low-ranking coal (LRC) …


A Study On The Hydrodynamics Of A Bench-Scale Top-Fed Bubbling Fluidized Bed Gasifier Using Biomass And Coal As Feedstocks, Ali Can Sivri Jan 2020

A Study On The Hydrodynamics Of A Bench-Scale Top-Fed Bubbling Fluidized Bed Gasifier Using Biomass And Coal As Feedstocks, Ali Can Sivri

Graduate Theses, Dissertations, and Problem Reports

The production of synthetic gas (syngas) from renewable or carbon-neutral sources can significantly reduce greenhouse and other emissions associated with conventional fuels. One of the most promising technologies to efficiently convert carbonaceous feedstocks such as biomass, coal, or municipal waste into syngas for transportation, power, heat, electricity generation, and or production of added-value chemicals is the bubbling fluidized-bed gasifier (BFBG). However, the gasification process inside a BFBG is a very complex high-temperature multiphase flow phenomena still not well understood, particularly when binary mixtures are investigated. As a result, despite the numerous correlations in the literature developed to predict the hydrodynamics …


Co-Gasification Of Coal And Biomass Wastes In An Entrained Flow Gasifier: Modelling, Simulation And Integration Opportunities, Dalia A. Ali Eng, Mamdouh A. Gadalla Prof., Omar Y. Abdelaziz, Christian P. Hulteberg, Fatma H. Ashour Prof. Jan 2017

Co-Gasification Of Coal And Biomass Wastes In An Entrained Flow Gasifier: Modelling, Simulation And Integration Opportunities, Dalia A. Ali Eng, Mamdouh A. Gadalla Prof., Omar Y. Abdelaziz, Christian P. Hulteberg, Fatma H. Ashour Prof.

Chemical Engineering

Gasification processes convert carbon-containing material into syngas through chemical reactions in the presence of gasifying agents such as air, oxygen, and steam. Syngas mixtures produced from such processes consist mainly of carbon monoxide (CO), hydrogen (H2), carbon dioxide (CO2), and methane (CH4); this gas can be directly utilised as a fuel to produce electricity or steam. Besides, it is regarded as a basic feedstock within the petrochemical and conventional refining industries, producing various useful products like methanol, hydrogen, ammonia, and acetic acid. In this work, a rigorous process model is developed to simulate the co-gasification of coal-biomass blends through an …


Modelling Of Coal-Biomass Blends Gasification And Power Plant Revamp Alternatives In Egypt’S Natural Gas Sector, Dalia A. Ali Eng, Mamdouh A. Gadalla Prof., Omar Y. Abdelaziz, Fatma H. Ashour Prof. Oct 2016

Modelling Of Coal-Biomass Blends Gasification And Power Plant Revamp Alternatives In Egypt’S Natural Gas Sector, Dalia A. Ali Eng, Mamdouh A. Gadalla Prof., Omar Y. Abdelaziz, Fatma H. Ashour Prof.

Chemical Engineering

Recently, there has been a growing research interest in the co-gasification of biomass with coal to produce syngas and electricity in a sustainable manner. Co-gasification technology do not only decrease potentially the exploitation of a significant amount of conventional coal resources, and thus lower greenhouse gases (GHG) emissions, but also boost the overall gasification process efficiency. In the present work, a rigorous simulation model of an entrained flow gasifier is developed using the Aspen Plus® software environment. The proposed simulation model is tested for an American coal and the model validation is performed in good agreement with practical data. The …


Gasification Of Coal And Heat Integration Modification For Igcc - Integrated Gasification Combined Cycle, Dalia A. Ali Eng, Mamdouh A. Gadalla Prof., Fatma H. Ashour Prof. Oct 2015

Gasification Of Coal And Heat Integration Modification For Igcc - Integrated Gasification Combined Cycle, Dalia A. Ali Eng, Mamdouh A. Gadalla Prof., Fatma H. Ashour Prof.

Chemical Engineering

Use of energy is closely related to the development of an economy. The most useful form of energy in the modern world is electricity. IGCC has higher fuel flexibility (biomass, refinery residues, petroleum coke, etc.) and generates multiple products (electricity, hydrogen and chemicals like methanol and higher alcohols) and by-products - sulphur, sulphuric acid, slag, etc. IGCC plants include coal preparation unit, air separation unit (ASU) to separate oxygen from air to use it in the gasification process, gasification unit where an incomplete combustion for coal is made to produce Syngas, cleaning unit to remove acid gases and CO2 from …


Aspen Plus Simulation Of Biomass Gasification In A Steam Blown Dual Fluidised Bed, Wayne Doherty, Anthony Reynolds, David Kennedy Aug 2013

Aspen Plus Simulation Of Biomass Gasification In A Steam Blown Dual Fluidised Bed, Wayne Doherty, Anthony Reynolds, David Kennedy

Book/Book Chapters

The efficient utilisation of biomass resources is of utmost importance. Biomass gasification offers much higher efficiencies than combustion. Gasification is a process in which a fuel is converted to a combustible gas (syngas). A dual fluidised bed gasifier known as the fast internally circulating fluidised bed (FICFB) was selected. It has been demonstrated at industrial scale and data is readily available for model validation. An Aspen Plus model was developed to simulate the FICFB gasifier. The model is based on Gibbs free energy minimisation and the restricted equilibrium method was used to calibrate it. The model has been validated and …


Simulation Of A Tubular Solid Oxide Fuel Cell Stack Operating On Biomass Syngas Using Aspen Plus, Wayne Doherty, Anthony Reynolds, David Kennedy May 2010

Simulation Of A Tubular Solid Oxide Fuel Cell Stack Operating On Biomass Syngas Using Aspen Plus, Wayne Doherty, Anthony Reynolds, David Kennedy

Articles

A tubular solid oxide fuel cell (SOFC) stack was modelled and its operation on biomass syn-gas was investigated. The objective of this work was to develop a computer simulation model of a biomass gasification-SOFC (BG-SOFC) system capable of predicting performance under various operating conditions and using diverse fuels. The stack was modelled using Aspen Plus and considers ohmic, activation and concentration losses. It was validated against published data for operation on natural gas. Operating parameters such as fuel and air utilisation factor Uf and Ua, current density j and steam to carbon ratio STCR were varied and …


Simulation Of A Tubular Solid Oxide Fuel Cell Stack Operating On Biomass Syn-Gas Using Aspen Plus, Wayne Doherty, Anthony Reynolds, David Kennedy Jan 2009

Simulation Of A Tubular Solid Oxide Fuel Cell Stack Operating On Biomass Syn-Gas Using Aspen Plus, Wayne Doherty, Anthony Reynolds, David Kennedy

Articles

A tubular solid oxide fuel cell (SOFC) stack is modelled and its operation on biomass syn-gas is investigated. The objective of this work is to develop a computer simulation model of a biomass gasification-SOFC (BG-SOFC) system capable of predicting performance under various operating conditions and using diverse fuels. The stack is modelled using Aspen Plus and considers ohmic, activation and concentration losses. It is validated against published data for operation on natural gas. Operating parameters such as fuel and air utilisation factor (Uf and Ua), current density (j) and steam to carbon ratio ( …