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Full-Text Articles in Mechanical Engineering

Decomposition And Ionization Of Ionic Liquids, Forrest Grady Kidd Iii Aug 2018

Decomposition And Ionization Of Ionic Liquids, Forrest Grady Kidd Iii

Dissertations

The United States Air Force is interested in developing a situationally responsive space environment. In order to achieve this, dual-mode-propulsion will be utilized. A new class of propellants is being developed for this application based on energetic ionic liquids. Two ionic liquids of current interest are Hydroxylammonium Nitrate (HAN) and Hydroxyethylhydrazinium Nitrate (HEHN) due to their beneficial performance characteristics. The decomposition and ionization chemistry of these two species is investigated in this work. Using GAUSSIAN09 software, reactions with important radicals are explored through quantum chemistry. The energetics of reactions as well as the identity of key product complexes are given. …


Complex Multidisciplinary Systems Decomposition For Aerospace Vehicle Conceptual Design And Technology Acquisition, Amen Omoragbon Aug 2016

Complex Multidisciplinary Systems Decomposition For Aerospace Vehicle Conceptual Design And Technology Acquisition, Amen Omoragbon

Mechanical and Aerospace Engineering Dissertations

Although, the Aerospace and Defense (A&D) industry is a significant contributor to the United States’ economy, national prestige and national security, it experiences significant cost and schedule overruns. This problem is related to the differences between technology acquisition assessments and aerospace vehicle conceptual design. Acquisition assessments evaluate broad sets of alternatives with mostly qualitative techniques, while conceptual design tools evaluate narrow set of alternatives with multidisciplinary tools. In order for these two fields to communicate effectively, a common platform for both concerns is desired. This research is an original contribution to a three-part solution to this problem. It discusses the …


The Decomposition Of Hydroxylammonium Nitrate Under Vacuum Conditions, Gregory A. Neff Apr 2016

The Decomposition Of Hydroxylammonium Nitrate Under Vacuum Conditions, Gregory A. Neff

Masters Theses

This research investigates the decomposition of the ionic liquid: hydroxylammonium nitrate (HAN), under vacuum conditions. All research was conducted at the Aerospace Laboratory for Plasma Experiments (ALPE) at Western Michigan University. Hydroxylammonium nitrate solution 24% wt. in H2O was used consistently throughout this research. A variety of temperatures and pressures ranging from 23°C to 645°C and 6E-3 Torr to 4 Torr, respectively, were used to decompose HAN. The primary gaseous species resulting from these decomposition conditions are N2O, NO, and trace amounts of NO2. The formation of H2O, and N2 is conditional on the experimental conditions, and the formation of …


Development Of A Micro-Catbed For Miniature Thrusters, Chance Paul Garcia Jan 2010

Development Of A Micro-Catbed For Miniature Thrusters, Chance Paul Garcia

Open Access Theses & Dissertations

The goal of this work is to develop a micro catalytic bed for miniature thrusters. A test bed was constructed for experimental testing to characterize several parts of the micro catalytic bed. The reactant fluid studied is 90% Hydrogen Peroxide (H2O2) by weight. Three different cross sectional area designs were tested to determine decomposition efficiency, temperature reaction propensity, optimum flow rate, and temperature distribution across each bed. The products of decomposition were condensed to measure the oxygen released from decomposition. The results will be used to develop the basis for a micro catalytic bed design to implement into future miniature …