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Full-Text Articles in Materials Science and Engineering

A Novel Approach To Predicting The Lifetime Of Elastomers Undergoing Stress Relaxation, Stephen Ronan Sep 2009

A Novel Approach To Predicting The Lifetime Of Elastomers Undergoing Stress Relaxation, Stephen Ronan

Doctoral

his work opens with a broad overview of several factors influencing the behaviour of elastomeric materials under constant deformation. Following this, an evaluation of the common difficulties surrounding industry-standard lifetime prediction methods is presented. Subsequently, a novel method for the lifetime prediction of stress relaxation in elastomeric materials under constant deformation is introduced. Experimental testing to determine the influence of filler type and content was conducted on several natural rubber materials. The effect of altering the vulcanising agent, crosslink density and mixing time was also examined. Chemiluminescence was used to determine the influence that oxidation has on the overall life …


Influence Of Magnesium Nitrate On The Corrosion Performance Of Sol-Gel Coated Aa2024-T3 Aluminium Alloy, Rajath Varma, Brendan Duffy, John Cassidy Jan 2009

Influence Of Magnesium Nitrate On The Corrosion Performance Of Sol-Gel Coated Aa2024-T3 Aluminium Alloy, Rajath Varma, Brendan Duffy, John Cassidy

Articles

Traditional anti-corrosion technology has relied heavily on using reducible metal species, predominantly hexavalent chromium (Cr(VI)), for protecting reactive metal alloys such as aluminium which is extensively used in the aerospace sector. However, the impending changes in the use of Cr(VI) in Europe and the United States have forced aerospace manufacturers to examine alternative materials for protecting aluminium. One of the most promising alternatives being investigated are organosilane based sol-gels containing anticorrosion additives. In this work the anti-corrosion properties of magnesium (II) nitrate (Mg(NO3)2) as a inhibitor was investigated at different concentrations (0.1% - 1.0 wt %) in a methyltriethoxysilane (MTEOS) …