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2022

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Articles 1 - 30 of 173

Full-Text Articles in Materials Science and Engineering

Elucidating The Synergic Effect In Nanoscale Mos2/Tio2 Heterointerface For Na-Ion Storage, Chunrong Ma, Dewen Hou, Jiali Jiang, Yanchen Fan, Xiang Li, Tianyi Li, Zifeng Ma, Haoxi Ben, Hui Xiong Dec 2022

Elucidating The Synergic Effect In Nanoscale Mos2/Tio2 Heterointerface For Na-Ion Storage, Chunrong Ma, Dewen Hou, Jiali Jiang, Yanchen Fan, Xiang Li, Tianyi Li, Zifeng Ma, Haoxi Ben, Hui Xiong

Materials Science and Engineering Faculty Publications and Presentations

Interface engineering in electrode materials is an attractive strategy for enhancing charge storage, enabling fast kinetics, and improving cycling stability for energy storage systems. Nevertheless, the performance improvement is usually ambiguously ascribed to the “synergetic effect”, the fundamental understanding toward the effect of the interface at molecular level in composite materials remains elusive. In this work, a well-defined nanoscale MoS2/TiO2 interface is rationally designed by immobilizing TiO2 nanocrystals on MoS2 nanosheets. The role of heterostructure interface between TiO2 and MoS2 by operando synchrotron X-ray diffraction (sXRD), solid-state nuclear magnetic resonance, and density functional …

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Clove Essential Oil And Nanoclays-Based Active Food Packaging, Kalpani Y. Perera, Shubham Sharma, Amit K. Jaiswal, Swarna Jaiswal Dec 2022

Clove Essential Oil And Nanoclays-Based Active Food Packaging, Kalpani Y. Perera, Shubham Sharma, Amit K. Jaiswal, Swarna Jaiswal

Articles

Active food packaging materials enhance the shelf-life of food products while reducing food waste. The current study aims to develop a biodegradable active food packaging material. The food packaging material was developed with the incorporation of clove essential oil, sodium alginate, gelatin, and nanoclay films were prepared. The influences of nanoclay and clove on the surface, optical, mechanical, chemical, barrier, and pH-indicating properties were studied. The lightness and yellowness increased by 1.06 folds and 3.34 folds when compared to clove (control), respectively. The UV barrier property 0.08±0.01nm in all films, while 8.37 folds reduction in transparency has been observed as …

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Nanoclays And Curcumin Based Food Packaging Material For Intelligent Food Packaging Applications, Kalpani Y. Perera, Swarna Jaiswal, Amit K. Jaiswal, Shubham Sharma Dec 2022

Nanoclays And Curcumin Based Food Packaging Material For Intelligent Food Packaging Applications, Kalpani Y. Perera, Swarna Jaiswal, Amit K. Jaiswal, Shubham Sharma

Articles

Bionanocomposite packaging eco-friendly alternatives with enhanced characteristics. This study aimed to develop a bionanocomposite intelligent packaging. Sodium alginate, gelatin, Curcumin (Cur), glycerol, and Nanoclay (NC) films were prepared. The influences of nanoclay and curcumin on the surface, optical, mechanical, chemical, barrier, and pH-indicating properties were studied. The results showed that the lightness of films was reduced by 1.28 folds compared to NC (control) film, while the yellowness of films increased by 5.82 folds. Film transparency was reduced by 9.3 folds and a 3.46 folds increase in UV barrier properties was observed compared to NC (control) film. The highest tensile strength …

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Cold Plasma Technology In Food Packaging, Kalpani Y. Perera, Jack Prendeville, Amit K. Jaiswal, Swarna Jaiswal Dec 2022

Cold Plasma Technology In Food Packaging, Kalpani Y. Perera, Jack Prendeville, Amit K. Jaiswal, Swarna Jaiswal

Articles

Cold plasma (CP) is an effective strategy to alter the limitations of biopolymer materials for food packaging applications. Biopolymers such as polysaccharides and proteins are known to be sustainable materials with excellent film-forming properties. Bio-based films can be used as an alternative to traditional plastic packaging. There are limitations to biopolymer packaging materials such as hydrophobicity, poor barrier, and thermos-mechanical properties. For this reason, biopolymers must be modified to create a packaging material with the desired applicability. CP is an effective method to enhance the functionality and interfacial features of biopolymers. It etches the film surface allowing for better adhesion …

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Nucleation And Growth Of Molybdenum Disulfide Grown By Thermal Atomic Layer Deposition On Metal Oxides, Jake Soares, Steven Letourneau, Matthew Lawson, Anil U. Mane, Yu Lu, Yaqiao Wu, Steven M. Hues, Lan Li, Jeffrey W. Elam, Elton Graugnard Dec 2022

Nucleation And Growth Of Molybdenum Disulfide Grown By Thermal Atomic Layer Deposition On Metal Oxides, Jake Soares, Steven Letourneau, Matthew Lawson, Anil U. Mane, Yu Lu, Yaqiao Wu, Steven M. Hues, Lan Li, Jeffrey W. Elam, Elton Graugnard

Materials Science and Engineering Faculty Publications and Presentations

To enable greater control over thermal atomic layer deposition (ALD) of molybdenum disulfide (MoS2), here we report studies of the reactions of molybdenum hexafluoride (MoF6) and hydrogen sulfide (H2S) with metal oxide substrates from nucleation to few-layer films. In situ quartz crystal microbalance experiments performed at 150, 200, and 250 °C revealed temperature-dependent nucleation behavior of the MoF6 precursor, which is attributed to variations in surface hydroxyl concentration with temperature. In situ Fourier transform infrared spectroscopy coupled with ex situ x-ray photoelectron spectroscopy (XPS) indicated the presence of molybdenum oxide and molybdenum oxyfluoride …

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Thermal Atomic Layer Etching Of Mos2 Using Mof6 And H2O, Jake Soares, Anil U. Mane, Devika Choudhury, Steven Letourneau, Steven M. Hues, Jeffrey W. Elam, Elton Graugnard Dec 2022

Thermal Atomic Layer Etching Of Mos2 Using Mof6 And H2O, Jake Soares, Anil U. Mane, Devika Choudhury, Steven Letourneau, Steven M. Hues, Jeffrey W. Elam, Elton Graugnard

Materials Science and Engineering Faculty Publications and Presentations

Two-dimensional (2D) layered materials offer unique properties that make them attractive for continued scaling in electronic and optoelectronic device applications. Successful integration of 2D materials into semiconductor manufacturing requires high-volume and high-precision processes for deposition and etching. Several promising large-scale deposition approaches have been reported for a range of 2D materials, but fewer studies have reported removal processes. Thermal atomic layer etching (ALE) is a scalable processing technique that offers precise control over isotropic material removal. In this work, we report a thermal ALE process for molybdenum disulfide (MoS2). We show that MoF6 can be used as …

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Out Of The Wood: Sojurn Cyclery, Jay H. Kinsinger Dec 2022

Out Of The Wood: Sojurn Cyclery, Jay H. Kinsinger

Engineering and Computer Science Faculty Contributions to the Popular Press

No abstract provided.

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Prediction Of Meltpool Depth In Laser Powder Bed Fusion Using In-Process Sensor Data, Part-Level Thermal Simulations, And Machine Learning, Grant King Dec 2022

Prediction Of Meltpool Depth In Laser Powder Bed Fusion Using In-Process Sensor Data, Part-Level Thermal Simulations, And Machine Learning, Grant King

Department of Mechanical and Materials Engineering: Dissertations, Theses, and Student Research

The goal of this thesis is the prevention of flaw formation in laser powder bed fusion additive manufacturing process. As a step towards this goal, the objective of this work is to predict meltpool depth as a function of in-process sensor data, part-level thermal simulations, and machine learning. As motivated in NASA's Marshall Space Flight Center specification 3716, prediction of meltpool depth is important because: (1) it can serve as a surrogate to estimate process status without the need for expensive post-process characterization, and (2) the meltpool depth provides an avenue for rapid qualification of microstructure evolution. To achieve the …

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The Living Breakwaters Pdr Efforts Econcrete Resource Analysis, Guianina Ferrari, Shervon Stephens, Calvin O. Walters Jr. Dec 2022

The Living Breakwaters Pdr Efforts Econcrete Resource Analysis, Guianina Ferrari, Shervon Stephens, Calvin O. Walters Jr.

Publications and Research

On October 29, 2012, Superstorm Sandy impacted 443,000 people and caused nearly $19 billion (about $58 per person in the US) worth of damage within New York City. As part of the New York City infrastructure reparation plan, the Living Breakwaters project in Tottenville addressed coastal resilience, allocating $100M of public funds to a series of artificial breakwaters by the southwest coast of Staten Island. Each breakwater is constructed and designed to mitigate water flow in storm events. ECOncrete, a primary element of the breakwater, is a specialty cast cementitious product that is marine organism-friendly that encourages biocalcification and photosynthesis. …

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Parametric Modeling Of Biomimetic Sharkskin For Wire Edm For Drag Reduction And Hydrophobicity, Joel Maxwell Dec 2022

Parametric Modeling Of Biomimetic Sharkskin For Wire Edm For Drag Reduction And Hydrophobicity, Joel Maxwell

Department of Mechanical and Materials Engineering: Dissertations, Theses, and Student Research

This research sets out to demonstrate the viability of parametric modeling for biomimetic sharkskin in the effort to reduce drag and create a self-cleaning surface. Multiple designs were created to be machined by Wire EDM on stainless steel and titanium and were comparatively tested. Limitations of current manufacturing processes to economically produce naturally occurring structures such as sharkskin, emphasize the need to be able to calculate the most accurate design for a given manufacturing process. By designing a simplified but parametrically consistent model compared to an accurately depicted 3D model of sharkskin, the textured samples produced can be further tested …

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A Fiber-Optic Sensor-Embedded And Machine Learning Assisted Smart Helmet For Multi-Variable Blunt Force Impact Sensing In Real Time, Yiyang Zhuang, Taihao Han, Qingbo Yang, Ryan O'Malley, Aditya Kumar, Rex E. Gerald, Jie Huang Dec 2022

A Fiber-Optic Sensor-Embedded And Machine Learning Assisted Smart Helmet For Multi-Variable Blunt Force Impact Sensing In Real Time, Yiyang Zhuang, Taihao Han, Qingbo Yang, Ryan O'Malley, Aditya Kumar, Rex E. Gerald, Jie Huang

Materials Science and Engineering Faculty Research & Creative Works

Early on-site diagnosis of mild traumatic brain injury (mTBI) will provide the best guidance for clinical practice. However, existing methods and sensors cannot provide sufficiently detailed physical information related to the blunt force impact. In the present work, a smart helmet with a single embedded fiber Bragg grating (FBG) sensor is developed, which can monitor complex blunt force impact events in real time under both wired and wireless modes. The transient oscillatory signal "fingerprint" can specifically reflect the impact-caused physical deformation of the local helmet structure. By combination with machine learning algorithms, the unknown transient impact can be recognized quickly …

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Recent Progress In Two Dimensional Mxenes For Photocatalysis: A Critical Review, Tahir Haneef, Kashif Rasool, Jibran Iqbal, Rab Nawaz, Muhammad Raza Ul Mustafa, Khaled A Mahmoud, Tapati Sarkar, Asif Shahzad Nov 2022

Recent Progress In Two Dimensional Mxenes For Photocatalysis: A Critical Review, Tahir Haneef, Kashif Rasool, Jibran Iqbal, Rab Nawaz, Muhammad Raza Ul Mustafa, Khaled A Mahmoud, Tapati Sarkar, Asif Shahzad

All Works

Transition metal carbides and nitrides, generally known as MXenes have emerged as an alternative to improve photocatalytic performance in renewable energy and environmental remediation applications because of their high surface area, tunable chemistry, and easily adjustable elemental compositions. MXenes have many interlayer groups, surface group operations, and a flexible layer spacing that makes them ideal catalysts. Over 30 different members of the MXenes family have been explored and successfully utilized as catalysts. Particularly, MXenes have achieved success as a photocatalyst for carbon dioxide reduction, nitrogen fixation, hydrogen evolution, and photochemical degradation. The structure of MXenes and the presence of hydrophilic …

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Fluid Droplet Spreading And Adhesion Studied With A Microbalance: A Review, Youhua Jiang, Jaroslaw Drelich Nov 2022

Fluid Droplet Spreading And Adhesion Studied With A Microbalance: A Review, Youhua Jiang, Jaroslaw Drelich

Michigan Tech Publications

A contact angle observed for a liquid–solid system is not necessarily a unique value, and a few contact angles need to be considered carefully in relation to liquid spreading, adhesion and phase separation. Understanding of the significance of different contact angles has improved in the last few years through direct measurements of interactive forces between droplets/bubbles and solids together with the simultaneous visualization of the changes in their shapes. A microelectronic balance system is employed to measure the force of spreading after either liquid droplet or gas bubble attachment to a substrate surface and the droplet/bubble–substrate adhesion forces after droplet/bubble …

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Transition-Metal Ions In Β-Ga2O3 Crystals: Identification Of Ni Acceptors, Timothy D. Gustafson, Nancy C. Giles, Brian C. Holloway, J. Jesenovec, B. L. Dutton, M. D. Mccluskey, Larry E. Halliburton Nov 2022

Transition-Metal Ions In Β-Ga2O3 Crystals: Identification Of Ni Acceptors, Timothy D. Gustafson, Nancy C. Giles, Brian C. Holloway, J. Jesenovec, B. L. Dutton, M. D. Mccluskey, Larry E. Halliburton

Faculty Publications

Excerpt: Transition-metal ions (Ni, Cu, and Zn) in β-Ga2O3 crystals form deep acceptor levels in the lower half of the bandgap. In the present study, we characterize the Ni acceptors in a Czochralski-grown crystal and find that their (0/−) level is approximately 1.40 eV above the maximum of the valence band.

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Biodegradable Active Bio-Nanocomposite Film For The Enhanced Shelf Life Of Tomatoes, Kalpani Y. Perera, Shubham Sharma, Brendan Duffy, Amit K. Jaiswal, Swarna Jaiswal Nov 2022

Biodegradable Active Bio-Nanocomposite Film For The Enhanced Shelf Life Of Tomatoes, Kalpani Y. Perera, Shubham Sharma, Brendan Duffy, Amit K. Jaiswal, Swarna Jaiswal

Articles

The increased environmental pollution has led to finding sustainable solutions for non-renewable plastic-based food packaging materials. Thus, the use of biomaterial-based packaging material has become an immense trend. This work aims at developing an antimicrobial biodegradable chitosanalginate bio-nano composite film with TiO2 nanoparticle (NPs) for food packaging applications. The film was developed by a solution casting method. The chemical, mechanical, thermal, barrier, antimicrobial, and biodegradable properties of the packaging films were evaluated. Packaging studies were performed for 15 days for cherry tomatoes. The designed packaging material had enhanced the mechanical properties with a significantly (p < 0.05) higher tensile strength of 15.76 folds and 2 fold higher elongation at break. The UV barrier properties increased by 88.6%, while the film transparency decreased by 87.23%. Molecular interaction of N-H covalent bonds was observed between alginate and chitosan together with TiO2 NPs. The developed bio-nano composite film showed antimicrobial activity against foodborne pathogens E. coli, S. aureus, S. typhi, and L. monocytogene with a log reduction of 7.08, 7.28, 6.04 & 6.02 log CFU/ml respectively at 24 hours incubation period. The film was completely biodegraded and a weight loss of 89.06% was observed in bio-nanocomposite film during the 3 months. Shelf-life estimation of cherry tomato using developed packaging films showed an increase in the shelf-life up to 8 days with stable pH, total soluble solids, and weight with no bacterial growth when packaged with prepared film. Owing to their improved mechanical, UV barrier, antibacterial, and biodegradability, the prepared active bio-nano composite packaging films could be considered a potential candidate for fruit packaging.

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Sodium Alginate, Nanoclay And Curcumin Based Food Packaging Material For Intelligent Food Packaging Applications, Kalpani Y. Perera, Máille Hopkins, Shubham Sharma, Brendan Duffy, Amit K. Jaiswal, Swarna Jaiswal Nov 2022

Sodium Alginate, Nanoclay And Curcumin Based Food Packaging Material For Intelligent Food Packaging Applications, Kalpani Y. Perera, Máille Hopkins, Shubham Sharma, Brendan Duffy, Amit K. Jaiswal, Swarna Jaiswal

Articles

Bionanocomposite food packaging contains materials of biological origin which display high-performance activity when compared to biopolymers and are eco-friendly alternatives to conventional packaging materials. Intelligent packaging monitors the condition of the food or environment surrounding the food and communicates changes to the consumer. This study aimed to develop a bionanocomposite intelligent packaging material by utilising sodium alginate, nanoclay and curcumin. Sodium alginate (2 W/V% SA) film incorporated with 0.3 W/V% curcumin (Cur), glycerol, and nanoclay (NC) in various concentrations (0, 0.5, 1 and 2 W/V %) was prepared using the solvent casting method. The influences of nanoclay and curcumin on …

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Adiabatic Shear Banding In Nickel And Nickel-Based Superalloys: A Review, Russell A. Rowe, Paul G. Allison, Anthony N. Palazotto, Keivan Davami Nov 2022

Adiabatic Shear Banding In Nickel And Nickel-Based Superalloys: A Review, Russell A. Rowe, Paul G. Allison, Anthony N. Palazotto, Keivan Davami

Faculty Publications

This review paper discusses the formation and propagation of adiabatic shear bands in nickel-based superalloys. The formation of adiabatic shear bands (ASBs) is a unique dynamic phenomenon that typically precedes catastrophic, unpredicted failure in many metals under impact or ballistic loading. ASBs are thin regions that undergo substantial plastic shear strain and material softening due to the thermo-mechanical instability induced by the competitive work hardening and thermal softening processes. Dynamic recrystallization of the material’s microstructure in the shear region can occur and encourages shear localization and the formation of ASBs. Phase transformations are also often seen in ASBs of ferrous …

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Experimental Evidence That Shear Bands In Metallic Glasses Nucleate Like Cracks, Alan A. Long, Wendelin Wright, Xiaojun Gu, Anna Thackray, Mayisha Nakib, Jonathan T. Uhl, Karin A. Dahmen Nov 2022

Experimental Evidence That Shear Bands In Metallic Glasses Nucleate Like Cracks, Alan A. Long, Wendelin Wright, Xiaojun Gu, Anna Thackray, Mayisha Nakib, Jonathan T. Uhl, Karin A. Dahmen

Faculty Journal Articles

Highly time-resolved mechanical measurements, modeling, and simulations show that large shear bands in bulk metallic glasses nucleate in a manner similar to cracks. When small slips reach a nucleation size, the dynamics changes and the shear band rapidly grows to span the entire sample. Smaller nucleation sizes imply lower ductility. Ductility can be increased by increasing the nucleation size relative to the maximum (“cutoff”) shear band size at the upper edge of the power law scaling range of their size distribution. This can be achieved in three ways: (1) by increasing the nucleation size beyond this cutoff size of the …

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Synthesis Of A Phosphorus-Based Epoxy Reactive Flame Retardant Analog To Diglycidyl Ether Of Bisphenol A (Dgeba) And Its Behavior As A Matrix In A Carbon Fiber Composite, Mustafa Mukhtar Nov 2022

Synthesis Of A Phosphorus-Based Epoxy Reactive Flame Retardant Analog To Diglycidyl Ether Of Bisphenol A (Dgeba) And Its Behavior As A Matrix In A Carbon Fiber Composite, Mustafa Mukhtar

Chemical and Materials Engineering Faculty Publications

This paper describes the synthesis of a phosphorus-based flame retardant that is a chemical analog of diglycidyl ether of bisphenol A (DGEBA), as well as its incorporation as a matrix into carbon fiber laminates. Carbon fiber composites, if used for structural applications in mass transport vehicles (aircraft, trains), will require some aspects of improved fire performance to be used safely in those applications. The first phase of work involved the development of two separate synthesis routes to produce the flame retardant monomer, referred to as Phosphorus-DGEBA or simply P-DGEBA. The second step was to determine the viability of the compound's …

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Comparing Structure-Property Evolution For Pm-Hip And Forged Alloy 625 Irradiated With Neutrons To 1 Dpa, Caleb Clement, Sowmya Panuganti, Patrick H. Warren, Yangyang Zhao, Yu Lu, Katelyn Wheeler, David Frazer, Donna P. Guillen, David W. Gandy, Janelle P. Wharry Nov 2022

Comparing Structure-Property Evolution For Pm-Hip And Forged Alloy 625 Irradiated With Neutrons To 1 Dpa, Caleb Clement, Sowmya Panuganti, Patrick H. Warren, Yangyang Zhao, Yu Lu, Katelyn Wheeler, David Frazer, Donna P. Guillen, David W. Gandy, Janelle P. Wharry

Materials Science and Engineering Faculty Publications and Presentations

The nuclear power industry has growing interest in qualifying powder metallurgy with hot isostatic pressing (PM-HIP) to replace traditional alloy fabrication methods for reactor structural components. But there is little known about the response of PM-HIP alloys to reactor conditions. This study directly compares the response of PM-HIP to forged Ni-base Alloy 625 under neutron irradiation doses ∼0.5–1 displacements per atom (dpa) at temperatures ranging ∼321–385 °C. Post-irradiation examination involves microstructure characterization, ASTM E8 uniaxial tensile testing, and fractography. Up through 1 dpa, PM-HIP Alloy 625 appears more resistant to irradiation-induced cavity nucleation than its forged counterpart, and consequently experiences …

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Optimizing Switching Of Non-Linear Properties With Hyperbolic Metamaterials, James A. Ethridge, John G. Jones, Manuel R. Ferdinandus, Michael J. Havrilla, Michael A. Marciniak Nov 2022

Optimizing Switching Of Non-Linear Properties With Hyperbolic Metamaterials, James A. Ethridge, John G. Jones, Manuel R. Ferdinandus, Michael J. Havrilla, Michael A. Marciniak

Faculty Publications

Hyperbolic metamaterials have been demonstrated to have special potential in their linear response, but the extent of their non-linear response has not been extensively modeled or measured. In this work, novel non-linear behavior of an ITO/SiO2 layered hyperbolic metamaterial is modeled and experimentally confirmed, specifically a change in the sign of the non-linear absorption with intensity. This behavior is tunable and can be achieved with a simple one-dimensional layered design. Fabrication was performed with physical vapor deposition, and measurements were conducted using the Z-scan technique. Potential applications include tunable optical switches, optical limiters, and tunable components of laser sources.

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Perturbative Theoretical Model Of Electronic Transient Circular Dichroism Spectroscopy Of Molecular Aggregates, Paul C. Arpin, Daniel B. Turner Oct 2022

Perturbative Theoretical Model Of Electronic Transient Circular Dichroism Spectroscopy Of Molecular Aggregates, Paul C. Arpin, Daniel B. Turner

Materials Science and Engineering Faculty Publications and Presentations

A chiral analog of transient absorption spectroscopy, transient circular dichroism (TCD) spectroscopy is an emerging time-resolved method. Both spectroscopic methods can probe the electronic transitions of a sample, and TCD is additionally sensitive to the dynamic aspects of chirality, such as those induced by molecular excitons. Here, we develop a theoretical description of TCD for electronic multi-level models in which the pump pulse is linearly polarized and probe pulse is alternately left- and right-circularly polarized. We derive effective response functions analogous to those often used to describe other four-wave mixing methods and then simulate and analyze TCD spectra for three …

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Local Structure In High-Entropy Transition Metal Diborides, Mattia Gaboardi, Frederic Monteverde, Federico Saraga, Giuliana Aquilanti, Lun Feng, William Fahrenholtz, Gregory Hilmas Oct 2022

Local Structure In High-Entropy Transition Metal Diborides, Mattia Gaboardi, Frederic Monteverde, Federico Saraga, Giuliana Aquilanti, Lun Feng, William Fahrenholtz, Gregory Hilmas

Materials Science and Engineering Faculty Research & Creative Works

Studies on high-entropy materials often speculate about the effects of lattice distortion and disorder on characteristics such as hardness, thermal expansion, and electronic properties. Notwithstanding the ongoing race to discover new compositions, investigations of the local structure at the atomic level remain sparse at best. Additionally, assessments of the homogeneity of the distribution of metals within the lattice sites are often restricted to techniques such as energy dispersive spectroscopy which might lead to an inaccurate picture of the bulk material. Herein, we report an extensive and systematic study of a class of emerging high-entropy ceramics that uses a combination of …

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Tunable Electronic Structure Via Dna-Templated Heteroaggregates Of Two Distinct Cyanine Dyes, Jonathan S. Huff, Matthew S. Barclay, Azhad U. Chowdhury, Lance K. Patten, Simon K. Roy, Aaron Sup, Austin Biaggne, Lan Li, Jeunghoon Lee, Paul H. Davis, Bernard Yurke, William B. Knowlton, Daniel B. Turner, Ryan D. Pensack Oct 2022

Tunable Electronic Structure Via Dna-Templated Heteroaggregates Of Two Distinct Cyanine Dyes, Jonathan S. Huff, Matthew S. Barclay, Azhad U. Chowdhury, Lance K. Patten, Simon K. Roy, Aaron Sup, Austin Biaggne, Lan Li, Jeunghoon Lee, Paul H. Davis, Bernard Yurke, William B. Knowlton, Daniel B. Turner, Ryan D. Pensack

Materials Science and Engineering Faculty Publications and Presentations

Molecular excitons are useful for applications in light harvesting, organic optoelectronics, and nanoscale computing. Electronic energy transfer (EET) is a process central to the function of devices based on molecular excitons. Achieving EET with a high quantum efficiency is a common obstacle to excitonic devices, often owing to the lack of donor and acceptor molecules that exhibit favorable spectral overlap. EET quantum efficiencies may be substantially improved through the use of heteroaggregates─aggregates of chemically distinct dyes─rather than individual dyes as energy relay units. However, controlling the assembly of heteroaggregates remains a significant challenge. Here, we use DNA Holliday junctions to …

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Molecular Dynamics Simulations Of Cyanine Dimers Attached To Dna Holliday Junctions, Austin Biaggne, Young C. Kim, Joseph S. Melinger, William B. Knowlton, Bernard Yurke, Lan Li Oct 2022

Molecular Dynamics Simulations Of Cyanine Dimers Attached To Dna Holliday Junctions, Austin Biaggne, Young C. Kim, Joseph S. Melinger, William B. Knowlton, Bernard Yurke, Lan Li

Materials Science and Engineering Faculty Publications and Presentations

Dye aggregates and their excitonic properties are of interest for their applications to organic photovoltaics, non-linear optics, and quantum information systems. DNA scaffolding has been shown to be effective at promoting the aggregation of dyes in a controllable manner. Specifically, isolated DNA Holliday junctions have been used to achieve strongly coupled cyanine dye dimers. However, the structural properties of the dimers and the DNA, as well as the role of Holliday junction isomerization are not fully understood. To study the dynamics of cyanine dimers in DNA, molecular dynamics simulations were carried out for adjacent and transverse dimers attached to Holliday …

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Carbonate-Superstructured Solid Fuel Cells With Hydrocarbon Fuels, Hanrui Su, Wei Zhang, Yun Hang Hu Oct 2022

Carbonate-Superstructured Solid Fuel Cells With Hydrocarbon Fuels, Hanrui Su, Wei Zhang, Yun Hang Hu

Michigan Tech Publications

A basic requirement for solid oxide fuel cells (SOFCs) is the sintering of electrolyte into a dense impermeable membrane to prevent the mixing of fuel and oxygen for a sufficiently high open-circuit voltage (OCV). However, herein, we demonstrate a different type of fuel cell, a carbonate-superstructured solid fuel cell (CSSFC), in which in situ generation of superstructured carbonate in the porous samarium-doped ceria layer creates a unique electrolyte with ultrahigh ionic conductivity of 0.17 S.cm21 at 550 °C. The CSSFC achieves unprecedented high OCVs (1.051 V at 500 °C and 1.041 V at 550 °C) with methane fuel. Furthermore, the …

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Design And Development Of A Multi-Material, Cost-Competitive, Lightweight Mid-Size Sports Utility Vehicle’S Body-In-White, Amit M. Deshpande, Rushabh Rajesh Sadiwala, Nathan Brown, Sai Aditya Pradeep, Leon M. Headings, Ningxiner Zhao, Brad Losey, Ryan Hahnlen, Marcelo J. Dapino, Gang Li, Srikanth Pilla Oct 2022

Design And Development Of A Multi-Material, Cost-Competitive, Lightweight Mid-Size Sports Utility Vehicle’S Body-In-White, Amit M. Deshpande, Rushabh Rajesh Sadiwala, Nathan Brown, Sai Aditya Pradeep, Leon M. Headings, Ningxiner Zhao, Brad Losey, Ryan Hahnlen, Marcelo J. Dapino, Gang Li, Srikanth Pilla

Publications

Vehicle light-weighting has allowed automotive original equipment manufacturers (OEMs) to improve fuel efficiency, incorporate value-adding features without a weight penalty, and extract better performance. The typical body-in-white (BiW) accounts for up to 40% of the total vehicle mass, making it the focus of light-weighting efforts through a) conceptual redesign b) design optimization using state-of-the-art computer-aided engineering (CAE) tools, and c) use of advanced high strength steels (AHSS), aluminum, magnesium, and/or fiber-reinforced plastic (FRP) composites. However, most of these light-weighting efforts have been focused on luxury/sports vehicles, with a relatively high price range and an average production of 100,000 units/year or …

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Zinc–Acetate–Amine Complexes As Precursors To Zno And The Effect Of The Amine On Nanoparticle Morphology, Size, And Photocatalytic Activity, Josh Eixenberger, David Estrada Oct 2022

Zinc–Acetate–Amine Complexes As Precursors To Zno And The Effect Of The Amine On Nanoparticle Morphology, Size, And Photocatalytic Activity, Josh Eixenberger, David Estrada

Materials Science and Engineering Faculty Publications and Presentations

Zinc oxide is an environmentally friendly and readily synthesized semiconductor with many industrial applications. ZnO powders were prepared by alkali precipitation using different [Zn(acetate)2(amine)x] compounds to alter the particle size and aspect ratio. Slow precipitations from 95 °C solutions produced micron-scale particles with morphologies of hexagonal plates, rods, and needles, depending on the precursor used. Powders prepared at 65 °C with rapid precipitation yielded particles with minimal morphology differences, but particle size was dependent on the precursor used. The smallest particles were produced using precursors that yielded crystals with low aspect ratios during high-temperature synthesis. Particles …

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Effect Of Cu Additions On Scale Structure And Descaling Efficiency Of Low C Steel Reheated In A Combustion Gas Atmosphere, Richard Osei, Simon Lekakh, Ronald J. O'Malley Oct 2022

Effect Of Cu Additions On Scale Structure And Descaling Efficiency Of Low C Steel Reheated In A Combustion Gas Atmosphere, Richard Osei, Simon Lekakh, Ronald J. O'Malley

Materials Science and Engineering Faculty Research & Creative Works

Modern EAF steelmaking employs scrap as its primary source of raw material. Different sources of scrap have varying levels of residuals, which can negatively influence product properties, performance, and surface quality. The presence of some residuals, such as Cu and Ni in controlled quantities, can also positively impact steel performance for some applications. It is also well known that interactions between residuals and alloying elements in steel can modify the structure of scale formed during slab reheating prior to hot rolling. These changes in the scale structure can influence scale removability. In this study, the effect of varying Cu concentrations …

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Fusion Welding Of Refractory Metals And Zrb2-Sic-Zrc Ceramics, Jecee D. Jarman, William Fahrenholtz, Greg Hilmas, Jeremy Lee Watts, Tieshu Huang Oct 2022

Fusion Welding Of Refractory Metals And Zrb2-Sic-Zrc Ceramics, Jecee D. Jarman, William Fahrenholtz, Greg Hilmas, Jeremy Lee Watts, Tieshu Huang

Materials Science and Engineering Faculty Research & Creative Works

Molybdenum and a molybdenum alloy were fusion welded to ZrB2-based ceramics to determine if the electrical and thermal properties of the metals and ceramics affected their weldability. Commercial ceramic powders were hot pressed, machined into coupons, and preheated to 1600 °C before joining the ceramics to commercial metals using plasma arc welding. Weldability varied as indicated by the range of porosity observed within the fusion zones. Measured thermal and electrical properties appeared to have little to no effect on the weldability of metal-ceramic welds despite the large range of values measured across each property. Differences in melting temperatures between metal …

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