Materials Science and Engineering Commons^™

Vacancy Clustering In Quenched Al-Li Solid Solution Alloys Studied By Doppler Broadening Spectroscopy, Hollis P. Leighly, P. G. Coleman

Materials Science and Engineering Faculty Research & Creative Works

The clustering of vacancies in severely quenched Al-Li solid solution alloys, with Li content between 230 and 2760 ppm, has been studied using Doppler broadening spectroscopy. The alloy samples were initially annealed at 873 K in dry air or dry, pure nitrogen. The onset temperature for vacancy clustering in samples initially annealed in air was found to be 150 ± 10 K, 40 ± 15 K lower than for the nitrogen-annealed samples. This result is consistent with the migration of divacancies, formed as a result of the significant increase in vacancy concentration caused by Li migration to, and oxidation at, …

Specific Heat And Transport “Anomalies” In Mixed Alkali Glasses, Peter F. Green, Richard K. Brow, James J. Hudgens

Materials Science and Engineering Faculty Research & Creative Works

We show that changes in the relative mole fractions of Li₂O and Na₂O in alkali metaphosphate glasses lead to “anomalies” in the specific heat and structural relaxations. The heat capacity change between the liquid and glassy states, Δc_p(T_g), at the calorimetric glass transition temperature, T_g, exhibits a minimum when the mole fractions of Li₂O and Na₂O are comparable. Moreover, systematic changes in the temperature dependence of the viscosity, η, i.e., changes in the “fragility” of the system, accompany these changes in mole fraction. This observed dependence …

Microstructures And Mechanical Properties Of Two-Phase Alloys Based On Nbcr2, Katherine C. Chen, Paul G . Kotula, Carl M. Cady, Michael E. Mauro, Dan J. Thoma

Materials Engineering

A two-phase, NbCrTi alloy (bcc + C15 Laves phase) has been developed using several alloy design methodologies. In efforts to understand processing-microstructure-property relationships, different processing routes were employed. The resulting microstructures and mechanical properties are discussed and compared. Plasma arc melted (PAM) samples served to establish baseline, as-cast properties. In addition, a novel processing technique, involving decomposition of a supersaturated and metastable precursor phase during hot isostatic pressing (HIP), was used to produce a refined, equilibrium two-phase microstructure. Quasi-static compression tests as a function of temperature were performed on both alloy types. Different deformation mechanisms were encountered based upon temperature …

Defects And Site Occupancies In Nb-Cr-Ti C15 Laves Phase Alloys, P. G. Kotula, C. B. Carter, Katherine C. Chen, Dan J. Thoma, F. Chu, T. E. Mitchell

Materials Engineering

No abstract provided.

Promoting Excellence In Education With An Outstanding Student Instructor Award Program, Jennifer Kadlowec, Justin Shriver, Trevor S. Harding, Charles Choi

Materials Engineering

The ASEE Student Chapter at the University of Michigan in conjunction with the College of Engineering has developed and organized an annual Outstanding Student Instructor Award in recognition of excellence in engineering education. The award not only acknowledges the outstanding contributions of the individuals selected for the award, but also coincides with the ASEE’s goals of promoting excellence in engineering education and attracting new members. The paper outlines the planning procedures developed since the inception of the award in 1994 and provides suggestions and insights for other ASEE Student Chapters to create and organize such an award.

Mixed Electron Emission From Doped Pb(Zr,Ti)O₃ Ceramics: Microstructural Aspects, Weiming Zhang, Wayne Huebner

Materials Science and Engineering Faculty Research & Creative Works

A mixed type electron emission, i.e., simultaneous ferroelectric and plasma emission, was observed with a negative driving pulse applied to doped Pb(Zr,Ti)O₃ ceramics in the absence of any external potential on the electron collector. During these emission studies, significant microstructural changes on the emission surface were observed, and corresponded to the different emission modes. Erosion craters at the edge of the electrode and small particles near these craters reflected the formation of a dense plasma there. Comparatively, cavities, i.e., grain pullouts, accumulated on the bare ferroelectric surface, the frequency of which depended upon its distance from the grid. This …

Mixed Electron Emission From Lead Zirconate-Titanate Ceramics, Weiming Zhang, Wayne Huebner, Stephen E. Sampayan, Mike L. Krogh

Materials Science and Engineering Faculty Research & Creative Works

Simultaneous ferroelectric and plasma emission from Pb(Zr,Ti)O₃ was observed with only a negative driving pulse applied to the sample, and without an extraction potential on the electron collector. Plasma emission was a strong, inconsistent, and self-destructive process. In addition, a positive ion current was detected. Comparatively, ferroelectric emission was a relatively stable self-emission process, exhibiting no apparent delay time, and no positive ion current. The relationship between the switching and emission current of ferroelectric samples measured simultaneously cannot only be used to determine the existence of ferroelectric emission, but can also give direction to choosing suitable ferroelectric materials for …

Iron Phosphate Compositions For Containment Of Hazardous Metal Waste, D. E. Day

Materials Science and Engineering Faculty Research & Creative Works

An improved iron phosphate waste form for the vitrification, containment and long-term disposition of hazardous metal waste such as radioactive nuclear waste is provided. The waste form comprises a rigid iron phosphate matrix resulting from the cooling of a melt formed by heating a batch mixture comprising the metal waste and a matrix-forming component. The waste form comprises from about 30 to about 70 weight percent P205 and from about 25 to about 50 weight percent iron oxide and has metals present in the metal waste chemically dissolved therein. The concentration of iron oxide in the waste form along with …

The Effects Of Beryllium Additions On The Oxidation Of Nickel Aluminide And Titanium Aluminide Based Intermetallics, R. H. Hanrahan Jr., Katherine C. Chen, M. P. Brady

Materials Engineering

The effects of Be additions on the oxidation behavior of β-NiAl in moist air at 1000°C and borderline alumina-forming y (TiAI) + Laves Ti-Al-Cr based alloys at 800°C and 1000°C in dry and moist air were investigated. The addition of Be to β-NiAl suppressed the formation of transient alumina, and resulted in the formation of a protective BeAl₂O₄ spinel phase. In dry air, the addition of Be to the Ti-AI-Cr alloys also resulted in the formation of a protective BeAl₂O₄ spinel phase. In moist air, only Ti-AlCr- Be alloys with a high Cr content …

Strength Degradation Of Sapphire Fibers During Pressure Casting Of A Sapphire-Reinforced Ni-Base Superalloy, R. Asthana, Surendra N. Tewari, S. L. Draper

Chemical & Biomedical Engineering Faculty Publications

Transient-liquid-phase (TLP) bonding was used to fabricate a Haynes 230 Ni-base superalloy/sapphire fiber composite for high-temperature applications. Boron was used as a melting-point depressant for the Ni, to aid superalloy infiltration of the fibers. Preliminary study of the composite indicated an incomplete TLP bonding cycle. Therefore, microstructural and microchemical analyses were carried out to determine the TLP bonding mechanism. It was found that the TLP process did not occur under local thermodynamic equilibrium conditions at the solid/liquid interfaces, contrary to the primary assumption of conventional models, so a modified model for TLP bonding is proposed. The main differences between the …

Regarding The Correlation Of Nuclear Spin Relaxation And Electrical Conductivity Relaxation In Ionic Glasses, David L. Sidebottom, Peter F. Green, Richard K. Brow

Materials Science and Engineering Faculty Research & Creative Works

Much attention has been focused recently on the apparent differences between ion dynamics in ion-containing glasses as probed by electrical conductivity relaxation (ECR) and by nuclear spin relaxation (NSR) techniques. In both relaxation processes, a power law frequency dependence is observed. Based upon fluctuation-dissipation arguments, the power law exponents should be equivalent. However, experimentally, it appears that the conductivity exponent is generally smaller than the NSR exponent. While an explanation for this discrepancy based upon fundamental differences in the correlation functions probed by the two techniques has been proffered, we show how this discrepancy may simply arise from differing analyses …

Two-Dimensional Ferroelectric Films, Alexander V. Bune, Vladimir M. Fridkin, Stephen Ducharme, Lev M. Blinov, Serguei P. Palto, Alexander V. Sorokin, S. G. Yudin, A. Zlatkin

Stephen Ducharme Publications

Ultrathin crystalline films offer the possibility of exploring phase transitions in the crossover region between two and three dimensions. Second- order ferromagnetic phase transitions have been observed in monolayer magnetic films [1,2], where surface anisotropy energy stabilizes the two-dimensional ferromagnetic state at finite temperature [3]. Similarly, a number of magnetic materials have magnetic surface layers that show a second-order ferromagnetic–paramagnetic phase transition with an increased Curie temperature [4]. Ferroelectricity is in many ways analogous to ferromagnetism, and bulk-like ferroelectricity and finite-size modifications of it have been seen in nanocrystals as small as 250 Å in diameter [5], in perovskite films …

Factors Affecting The Room-Temperature Mechanical Properties Of Ticr2-Base Laves Phase Alloys, Katherine C. Chen, Samuel M. Allen, James D. Livingston

Materials Engineering

Various effects on the room-temperature mechanical properties of TiCr₂-base alloys have been assessed in efforts to improve the toughness of Laves phase intermetallics (AB₂). Systematic studies were performed on: (i) single-phase stoichiometric and nonstoichiometric TiCr₂, (ii) TiCr₂-base ternary Laves phases, and (iii) two-phase binary alloys containing TiCr₂. In order to make quantitative comparisons among the different alloys, Vickers indentation was used to obtain hardness and fracture toughness values. Within the single-phase field, constitutional defects accounted for the compositional dependencies of properties, and may aid the synchroshear deformation process. Ternary Laves …

Derivation Of An Analytical Model To Calculate Junction Depth In Hgcdte Photodiodes, Stacy H. Gleixner, H. G. Robinson, C. R. Helms

Faculty Publications

Presents an enhanced analytical model to calculate junction depth and Hg interstitial profile during n-on-p junction formation in HgCdTe photodiodes. Detailed information on the enhanced model; Function of the model; Information on HgCdTe; Detailed information on how the model was obtained.

Three-Dimensional Dynamic Analysis Of Wheelchair Propulsion, Mary M. Rodgers, Srinivas Tummarakota, Junghsen Lieh

Mechanical and Materials Engineering Faculty Publications

A three-dimensional (3-D) inverse dynamic model of wheelchair propulsion was developed using the Newton-Euler method based on body coordinate systems. With this model, the arm was assumed to be three rigid segments (hand, forearm, and upper arm) connected by the wrist, elbow, and shoulder joints. A symbolic method was adopted to generate the equations of motion. The model was used to compute the joint forces and moments based on the inputs obtained from a 3-D motion analysis system, which included an instrumented wheelchair, video cameras, and a data acquisition system. The linear displacements of markers placed on the joints were …

Incommensurate Magnetic Fluctuations In Yba₂Cu₃O₆.₆, Pengcheng Dai, Herbert A. Mook, Fatih Dogan

Materials Science and Engineering Faculty Research & Creative Works

We use inelastic neutron scattering to demonstrate that the low-frequency magnetic fluctuations in YBa₂Cu₃O_6.6 (T_c = 62.7 K) change from commensurate to incommensurate on cooling with the incommensurability first appearing at temperatures above T_c. For the energies studied, the susceptibility at incommensurate positions increases on cooling below T_c, accompanied by a suppression of the spin fluctuations at the commensurate points. These results suggest that incommensurate spin fluctuations may be a common feature for all cuprate superconductors.

White Light Interferometric Surface Profiler, Vincent Toal, Brian Bowe

Articles

We describe an optical system for 3-D profilometry based on the white light interferometer. We detail a simple way to construct a profiler that uses two simple algorithms which deal efficiently and quickly with the data. The system has a theoretically unlimited range and can deal with rough and smooth surfaces

Lateral Resistance Of Ring-Shank Nail Connections In Southern Pine Lumber, R D. Theilen, D A. Bender, David Pollock, S G. Winistorfer

Faculty Publications - Biomedical, Mechanical, and Civil Engineering

Ring-shank nails are used in engineered structures with lateral connection design values based on theoretically derived equations which were validated only for common nails. The goal of this study was to quantify the input parameters and lateral connection strength of several types of ring-shank nails in Southern Pine lumber and critically evaluate the applicability of the theoretical equations for ring-shank nails.

Two sizes of galvanized and ungalvanized, hardened steel ring-shank nails from two manufacturers were studied. The hardened, ring-shank nails carried significantly higher loads than the common wire nails studied. Because the current method of determining yield load does not …

Deuterium Nmr Of Adsorbed Poly(Methyl Acrylate)-D₃, Frank D. Blum, Wuu-Yung Lin

Chemistry Faculty Research & Creative Works

The dynamics of polymers at interfaces are important in a variety of applications, especially where those applications depend on the mechanical or surface properties. Unfortunately, the surface properties of interfacial species like polymers used in composites are not easily measured macroscopically. Microscopic techniques, especially spectroscopic ones, have been successful. In our laboratory we have been successful in applying NMPR to determine the behavior of absorbed polymers. NMR has several advantages for this kind of study, the principal ones being that it can be used on opaque materials, different nuclei can be used as probes, and interfacial material can sometimes be …

Dynamic Analysis Of Unidirectional Pressure Infiltration Of Porous Preforms By Pure Metals, Dhiman K. Biswas, Jorge E. Gatica, Surendra N. Tewari

Chemical & Biomedical Engineering Faculty Publications

Unidirectional pressure infiltration of porous preforms by molten metals is investigated numerically. A phenomenological model to describe fluid flow and transport phenomena during infiltration of fibrous preforms by a metal is formulated. The model describes the dynamics of the infiltration process, the temperature distribution, and solid fraction distribution. The numerical results are compared against classical asymptotic analyses and experimental results. This comparison shows that end effects may become important and render asymptotic results unreliable for realistic samples. Fiber volume fraction and initial temperature appear as the factors most strongly influencing infiltration. Metal superheating affects not only the length of the …

Metal-Organic Chemical Vapor Deposition Of Sr-Co-Fe-O Films On Porous Substrates, C.-F. Xia, P. Atanasova, Robert W. Schwartz, T. L. Ward

Mechanical and Aerospace Engineering Faculty Research & Creative Works

Aerosol-assisted chemical vapor deposition using the b-diketonate precursors Sr(tmhd)2•2H2O, Fe(tmhd)3 and Co(tmhd)3 was investigated for depositing thin films of the mixed-conducting ceramic SrCoyFe1-yO3-d onto porous a-Al2O3 substrates. Single-phase SrCoyFe1-yO3-d perovskite films were obtained at a deposition temperature of 550°C and pressure of 15 mm Hg, whereas deposition at atmospheric pressure produced mixed-phase films. The Co/Fe elemental ratios in the films reflected those in the precursor solution, but the films were depleted in Sr. Reduced-pressure deposition provided a more uniform film morphology than atmospheric-pressure, and led to a supported film which was leak-tight to N2 flow.

Magnetoresistance Of Magnetic Tunnel Junctions In The Presence Of A Nonmagnetic Layer, Shi C. Zhang, P. M. Levy

Materials Science and Engineering Faculty Research & Creative Works

We find that electron propagation across a uniform nonmagnetic metallic layer di in a magnetically layered structure is coherent up to a critical length dc. This provides a possible explanation for the slow decay of the magnetoresistance of magnetic tunnel junctions when a layer of Cu or Ag is inserted between the magnetic electrode and the barrier. However, for many (most) structures the roughness of the interfaces breaks the coherence for di ≪ dc. While the loss of coherence is not fatal for the magnetoresistance of metallic multilayers, it is for tunnel junctions. The quantum well states arising from the …

Organically Deposited Metallic Films For Device Fabrication, Thomas J. O'Keefe, M. Stroder, Matthew O'Keefe

Materials Science and Engineering Faculty Research & Creative Works

Advances in integrated circuit density, speed and complexity are dependent on lower resistance, finer line width on-chip interconnections. Methods for incorporating copper interconnects into IC fabrication processes have been developed which accomplish this objective but most of these methods use some form of blanket metal deposition that requires mechanical and/or chemical removal of excess material. To date, investigations into the selective deposition of conductor materials for device fabrication have met with limited success. A new process for selectively depositing metallic conductors using inexpensive, organic-based chemical solutions could potentially force a paradigm shift in the deposition of metals for microelectronic applications. …

Electrodeposition Of Copper On Thermally Oxidized 316 L Stainless Steel Substrates, Z. Zhou, Thomas J. O'Keefe

Materials Science and Engineering Faculty Research & Creative Works

The effect of thermal oxidation of 316 L stainless steel cathode blanks used in copper electrodeposition was studied. Current and potential step experiments were performed to evaluate electrochemical changes caused by the oxidation treatments. SEM and AES were used to characterize the stainless-steel substrates and the deposited copper films. Particular emphasis was given to the initial stages of copper nucleation and growth. The copper electro crystallization process was strongly influenced by the temperature employed in oxidizing the stainless steel. Dense, uniform and fine copper nuclei were obtained on the stainless-steel substrate oxidized in air at 200°C and 300°C for 3 …

Maskless, Direct Deposition Of Copper Onto Aluminum Bond Pads For Flip Chip Applications, M. Fang, Thomas J. O'Keefe, M. Stroder, W. Shih, Matthew O'Keefe, R. Strawser, D. Via

Materials Science and Engineering Faculty Research & Creative Works

Flip chip interconnection of integrated circuits (IC) for packaging applications such as direct chip attachment use Pb-Sn solders as the connection between the die and the substrate. Under bump metallization is typically used to transition from the non-solderable Al bond pad on the IC to a solderable surface such as copper using traditional blanket metal deposition, photolithography and etching procedures. In this study, we report for the first time the use of a novel process for selectively depositing adherent copper directly onto aluminum thin films, eliminating the need for adhesion promoting transition layers and additional patterning steps. Utilizing copper bearing …

Analysis Of The Value Of The Fe Examination For The Assessment Of Student Learning In Engineering And Science Topics, John L. Watson

Materials Science and Engineering Faculty Research & Creative Works

This paper presents the results of a project, which investigated the potential of fully using previously unreleased data from the nationally normed Fundamentals of Engineering (FE) examination to assess learning in key engineering and science topics. In the past, very limited information was released by the National Council of Examiners for Engineers and Surveyors (NCEES) for the eight hour FE examination, which is composed of 150-200 questions in ten morning and five afternoon topics. For the purposes of this project the NCEES agreed to release information to the University of Missouri-Rolla (UMR) to permit the value of the FE data …

Electrochemical Characterization Of Copper Deposited On Plasma And Thermally Modified Titanium Surfaces, K. S. Teng, J. L. Delplancke, Jiangfan Zhang, T. J. O'Keefe

Electrical and Computer Engineering Faculty Research & Creative Works

Thin oxide films were grown at temperatures from 373 to 1073 K in plasma and in air on commercially pure titanium substrates. It was determined that the color, thickness, composition, phase, and polarization behavior in a copper electrolyte varied with operating conditions: temperature, oxygen partial pressure, and plasma composition. High-temperature and high oxygen partial pressure plasma produced a thick oxide film. The surface film structure transformed from TiO2 (anatase) to TiO2 (rutile) at a temperature of 600 °C. A lower oxide of the form TinO2n-1, such as Ti2O3 (which may be porous) or possibly Ti3O5, was formed on a thermally …

Evolution Of In Situ Refractories In The 20th Century, William E. Lee, Robert E. Moore

Materials Science and Engineering Faculty Research & Creative Works

A common theme over the past 100 years in refractories science and technology has been to generate a protective refractories layer in a high-temperature container, often by reaction of the refractory materials with the contents (glass, slag, or atmosphere). The history of refractories during the 20th century is used in this review to illustrate how techniques - such as slag splashing, in situ spinel generation in castables, magnesia dense layer formation in magnesia-carbon brick in steelmaking, clinker adhesion in cement kilns, and viscous boundary layer generation in glass tanks - have evolved to their present status.