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Materials Science and Engineering Commons

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Missouri University of Science and Technology

Theses/Dissertations

2014

Ceramics -- Thermal properties<br />Zirconium -- Thermal properties<br />Borides -- Thermal properties<br />Transition metals

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Full-Text Articles in Materials Science and Engineering

Thermal Properties Of Zirconium Diboride - Transition Metal Boride Solid Solutions, Devon Lee Mcclane Jan 2014

Thermal Properties Of Zirconium Diboride - Transition Metal Boride Solid Solutions, Devon Lee Mcclane

Masters Theses

"This research focuses on the thermal properties of zirconium diboride (ZrB₂) based ceramics. The overall goal was to improve the understanding of how different transition metal (TM) additives influence thermal transport in ZrB₂. To achieve this, ZrB₂ with 0.5 wt% carbon, and 3 mol% of individual transition metal borides, was densified by hot-press sintering. The transition metals that were investigated were: Y, Ti, Hf, V, Nb, Ta, Cr, Mo, W, and Re. The room temperature thermal diffusivities of the compositions ranged from 0.331 cm²/s for nominally pure ZrB₂ to 0.105 cm²/s for (Zr,Cr)B₂ and converged around 0.155cm²/s at higher temperatures …