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Michigan Technological University

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Articles 1 - 30 of 127

Full-Text Articles in Materials Science and Engineering

Progress In Energy: Usa–Canada Special Issue On Energy, Yun Hang Hu Feb 2024

Progress In Energy: Usa–Canada Special Issue On Energy, Yun Hang Hu

Michigan Tech Publications, Part 2

No abstract provided.

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Thermo-Photo Catalytic Anode Process For Carbonate-Superstructured Solid Fuel Cells, Hanrui Su, Yun Hang Hu Jan 2024

Thermo-Photo Catalytic Anode Process For Carbonate-Superstructured Solid Fuel Cells, Hanrui Su, Yun Hang Hu

Michigan Tech Publications, Part 2

Converting hydrocarbons and greenhouse gases (i.e., carbon dioxide, CO2) directly into electricity through fuel cells at intermediate temperatures (450 to 550 °C) remains a significant challenge, primarily due to the sluggish activation of C-H and C=O bonds. Here, we demonstrated a unique strategy to address this issue, in which light illumination was introduced into the thermal catalytic CO2reforming of ethane in the anode as a unique thermo-photo anode process for carbonate-superstructured solid fuel cells. The light-enhanced fuel activation led to excellent cell performance with a record-high peak power density of 168 mW cm-2at an intermediate temperature of 550 °C. Furthermore, …

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Heating Capacity And Biocompatibility Of Hybrid Nanoparticles For Magnetic Hyperthermia Treatment, Aline Alexandrina Gomes, Thalita Marcolan Valverde, Vagner De Oliveira Machado, Emanueli Do Nascimento Da Silva, Daniele Alves Fagundes, Fernanda De Paula Oliveira, Erico Freitas, José Domingos Ardisson, José Maria Da Fonte Ferreira, Junnia Alvarenga De Carvalho Oliveira, Eliza Rocha Gomes, Caio Fabrini Rodrigues, Alfredo Miranda De Goes, Rosana Zacarias Domingues, Ângela Leão Andrade Jan 2024

Heating Capacity And Biocompatibility Of Hybrid Nanoparticles For Magnetic Hyperthermia Treatment, Aline Alexandrina Gomes, Thalita Marcolan Valverde, Vagner De Oliveira Machado, Emanueli Do Nascimento Da Silva, Daniele Alves Fagundes, Fernanda De Paula Oliveira, Erico Freitas, José Domingos Ardisson, José Maria Da Fonte Ferreira, Junnia Alvarenga De Carvalho Oliveira, Eliza Rocha Gomes, Caio Fabrini Rodrigues, Alfredo Miranda De Goes, Rosana Zacarias Domingues, Ângela Leão Andrade

Michigan Tech Publications, Part 2

Cancer is one of the deadliest diseases worldwide and has been responsible for millions of deaths. However, developing a satisfactory smart multifunctional material combining different strategies to kill cancer cells poses a challenge. This work aims at filling this gap by developing a composite material for cancer treatment through hyperthermia and drug release. With this purpose, magnetic nanoparticles were coated with a polymer matrix consisting of poly (L-co-D,L lactic acid-co-trimethylene carbonate) and a poly(ethylene oxide)–poly(propylene oxide)–poly(ethylene oxide) triblock copolymer. High-resolution transmission electron microscopy and selected area electron diffraction confirmed magnetite to be the only iron oxide in the sample. Cytotoxicity …

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The Influence Of Boron (B), Tin (Sn), Copper (Cu), And Manganese (Mn) On The Microstructure Of Spheroidal Graphite Irons, A. V. Bugten, P. Sanders, C. Hartung, R. Logan, M. Di Sabatino, L. Michels Dec 2023

The Influence Of Boron (B), Tin (Sn), Copper (Cu), And Manganese (Mn) On The Microstructure Of Spheroidal Graphite Irons, A. V. Bugten, P. Sanders, C. Hartung, R. Logan, M. Di Sabatino, L. Michels

Michigan Tech Publications, Part 2

Most spheroidal graphite irons (SGIs) have a matrix consisting of ferrite, pearlite, or a mix of the two. To achieve the desired matrix composition, pearlite promoters such as Mn, Cu, or Sn, are added to the molten metal. Among these elements, Sn is the most potent pearlite promoter. However, each has a different impact on the solidification, graphite precipitation, eutectoid transformation, and ultimately the final structure of the material. Research has shown that B promotes ferrite in fully pearlitic grades where Cu and Mn were used to promote pearlite. The present work investigates the effect of B in SGI with …

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Modification Strategies For Development Of 2d Material-Based Electrocatalysts For Alcohol Oxidation Reaction, Haichang Fu, Zhangxin Chen, Xiaohe Chen, Fan Jing, Hua Yu, Dan Chen, Binbin Yu, Yun Hang Hu, Yanxian Jin Dec 2023

Modification Strategies For Development Of 2d Material-Based Electrocatalysts For Alcohol Oxidation Reaction, Haichang Fu, Zhangxin Chen, Xiaohe Chen, Fan Jing, Hua Yu, Dan Chen, Binbin Yu, Yun Hang Hu, Yanxian Jin

Michigan Tech Publications, Part 2

2D materials, such as graphene, MXenes (metal carbides and nitrides), graphdiyne (GDY), layered double hydroxides, and black phosphorus, are widely used as electrocatalyst supports for alcohol oxidation reactions (AORs) owing to their large surface area and unique 2D charge transport channels. Furthermore, the development of highly efficient electrocatalysts for AORs via tuning the structure of 2D support materials has recently become a hot area. This article provides a critical review on modification strategies to develop 2D material-based electrocatalysts for AOR. First, the principles and influencing factors of electrocatalytic oxidation of alcohols (such as methanol and ethanol) are introduced. Second, surface …

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Modification Strategies For Development Of 2d Material-Based Electrocatalysts For Alcohol Oxidation Reaction, Haichang Fu, Zhangxin Chen, Xiaohe Chen, Fan Jing, Hua Yu, Dan Chen, Binbin Yu, Yun Hang Hu, Yanxian Jin Dec 2023

Modification Strategies For Development Of 2d Material-Based Electrocatalysts For Alcohol Oxidation Reaction, Haichang Fu, Zhangxin Chen, Xiaohe Chen, Fan Jing, Hua Yu, Dan Chen, Binbin Yu, Yun Hang Hu, Yanxian Jin

Michigan Tech Publications, Part 2

2D materials, such as graphene, MXenes (metal carbides and nitrides), graphdiyne (GDY), layered double hydroxides, and black phosphorus, are widely used as electrocatalyst supports for alcohol oxidation reactions (AORs) owing to their large surface area and unique 2D charge transport channels. Furthermore, the development of highly efficient electrocatalysts for AORs via tuning the structure of 2D support materials has recently become a hot area. This article provides a critical review on modification strategies to develop 2D material-based electrocatalysts for AOR. First, the principles and influencing factors of electrocatalytic oxidation of alcohols (such as methanol and ethanol) are introduced. Second, surface …

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Acute Exposure To Two Biocides Causes Morphological And Molecular Changes In The Gill Ciliary Epithelium Of The Invasive Golden Mussel Limnoperna Fortunei (Dunker, 1857), Amanda Maria Siqueira Moreira, Erico Freitas, Mariana De Paula Reis, Júlia Meireles Nogueira, Newton Pimentel De Ulhôa Barbosa, André Luiz Martins Reis, Afonso Pelli, Paulo Ricardo Da Silva Camargo, Antonio Valadão Cardoso, Rayan Silva De Paula, Erika Cristina Jorge Oct 2023

Acute Exposure To Two Biocides Causes Morphological And Molecular Changes In The Gill Ciliary Epithelium Of The Invasive Golden Mussel Limnoperna Fortunei (Dunker, 1857), Amanda Maria Siqueira Moreira, Erico Freitas, Mariana De Paula Reis, Júlia Meireles Nogueira, Newton Pimentel De Ulhôa Barbosa, André Luiz Martins Reis, Afonso Pelli, Paulo Ricardo Da Silva Camargo, Antonio Valadão Cardoso, Rayan Silva De Paula, Erika Cristina Jorge

Michigan Tech Publications, Part 2

Limnoperna fortunei, the golden mussel, is a bivalve mollusk considered an invader in South America. This species is responsible for ecological and economic damages due to its voluminous fouling capability. Chemical biocides such as MXD-100™ and sodium dichloroisocyanurate (NaDCC) are often used to control L. fortunei infestations in hydraulic systems. Thus, we proposed to investigate the effects of different periods (24, 48 and 72 h) of exposure to MXD-100™ (0.56 mg L−1) and NaDCC (1.5 mg L−1) on the gills of L. fortunei through morphological and molecular analyses. NaDCC promoted progressive morphological changes during the analyzed periods and only an …

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Evolution Of Glassy Carbon Derived From Pyrolysis Of Furan Resin, Josh Kemppainen, Ivan Gallegos, Aaron Krieg, Jacob R. Gissinger, Kristopher E. Wise, Margaret Kowalik, Julia A. King, S. Gowtham, Adri Van Duin, Gregory Odegard Oct 2023

Evolution Of Glassy Carbon Derived From Pyrolysis Of Furan Resin, Josh Kemppainen, Ivan Gallegos, Aaron Krieg, Jacob R. Gissinger, Kristopher E. Wise, Margaret Kowalik, Julia A. King, S. Gowtham, Adri Van Duin, Gregory Odegard

Michigan Tech Publications, Part 2

Glassy carbon (GC) material derived from pyrolyzed furan resin was modeled by using reactive molecular dynamics (MD) simulations. The MD polymerization simulation protocols to cure the furan resin precursor material are validated via comparison of the predicted density and Young's modulus with experimental values. The MD pyrolysis simulations protocols to pyrolyze the furan resin precursor is validated by comparison of calculated density, Young's modulus, carbon content, sp carbon content, the in-plane crystallite size, out-of-plane crystallite stacking height, and interplanar crystallite spacing with experimental results from the literature for furan resin derived GC. The modeling methodology established in this work can …

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Establishing Physical And Chemical Mechanisms Of Polymerization And Pyrolysis Of Phenolic Resins For Carbon-Carbon Composites, Ivan Gallegos, Josh Kemppainen, Jacob R. Gissinger, Malgorzata Kowalik, Adri Van Duin, Kristopher E. Wise, S. Gowtham, Gregory Odegard Sep 2023

Establishing Physical And Chemical Mechanisms Of Polymerization And Pyrolysis Of Phenolic Resins For Carbon-Carbon Composites, Ivan Gallegos, Josh Kemppainen, Jacob R. Gissinger, Malgorzata Kowalik, Adri Van Duin, Kristopher E. Wise, S. Gowtham, Gregory Odegard

Michigan Tech Publications, Part 2

The complex structural and chemical changes that occur during polymerization and pyrolysis critically affect material properties but are difficult to characterize in situ. This work presents a novel, experimentally validated methodology for modeling the complete polymerization and pyrolysis processes for phenolic resin using reactive molecular dynamics. The polymerization simulations produced polymerized structures with mass densities of 1.24 ± 0.01 g/cm3 and Young's moduli of 3.50 ± 0.64 GPa, which are in good agreement with experimental values. The structural properties of the subsequently pyrolyzed structures were also found to be in good agreement with experimental X-ray data for the phenolic-derived carbon …

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Carbohydrates Generated Via Hot Water As Catalyst For Co2 Reduction Reaction, Yang Yang, Heng Zhong, Jiong Cheng, Yun Hang Hu, Richard Lee Smith Jr, Fangming Jin Sep 2023

Carbohydrates Generated Via Hot Water As Catalyst For Co2 Reduction Reaction, Yang Yang, Heng Zhong, Jiong Cheng, Yun Hang Hu, Richard Lee Smith Jr, Fangming Jin

Michigan Tech Publications, Part 2

Combining terrestrial biomass with submarine-type hydrothermal environments for CO2 reduction is a possible approach for realizing new energies while achieving sustainable circulation of carbon. Herein, carbohydrateenabled CO2 reduction based on NaHCO3 conversion to formate revealed that hydrothermal environments facilitated direct hydrogen transfer from carbohydrates (glucose, cellulose) to CO2/NaHCO3 with hot water (250–300 °C, 5–20 MPa) acting as homogeneous catalyst in absence of any conventional catalysts giving CO2/ NaHCO3 reduction efficiencies as high as 76% for cellulose. Time-resolved operando hydrothermal DRIFTS spectra of glycolaldehyde in hot water (250 °C, autogenous pressure) verified that water catalyzed NaHCO3 reduction by converting the -CHO …

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Magnesium-Based Nanocomposites: A Review From Mechanical, Creep And Fatigue Properties, S. Abazari, A. Shamsipur, H. R. Bakhsheshi-Rad, J. W. Drelich, J. Goldman, S. Sharif, A. F. Ismail, M. Razzaghi Aug 2023

Magnesium-Based Nanocomposites: A Review From Mechanical, Creep And Fatigue Properties, S. Abazari, A. Shamsipur, H. R. Bakhsheshi-Rad, J. W. Drelich, J. Goldman, S. Sharif, A. F. Ismail, M. Razzaghi

Michigan Tech Publications, Part 2

The addition of nanoscale additions to magnesium (Mg) based alloys can boost mechanical characteristics without noticeably decreasing ductility. Since Mg is the lightest structural material, the Mg-based nanocomposites (NCs) with improved mechanical properties are appealing materials for lightweight structural applications. In contrast to conventional Mg-based composites, the incorporation of nano-sized reinforcing particles noticeably boosts the strength of Mg-based nanocomposites without significantly reducing the formability. The present article reviews Mg-based metal matrix nanocomposites (MMNCs) with metallic and ceramic additions, fabricated via both solid-based (sintering and powder metallurgy) and liquid-based (disintegrated melt deposition) technologies. It also reviews strengthening models and mechanisms that …

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Conventional Platinum Metal Implants Provoke Restenosis Responses In Atherogenic But Not Healthy Arteries, Lea M. Morath, Roger J. Guillory Ii, Alexander A. Oliver, Shu Q. Liu, Martin L. Bocks, Galit Katarivas Levy, Jaroslaw Drelich, Jeremy Goldman Jun 2023

Conventional Platinum Metal Implants Provoke Restenosis Responses In Atherogenic But Not Healthy Arteries, Lea M. Morath, Roger J. Guillory Ii, Alexander A. Oliver, Shu Q. Liu, Martin L. Bocks, Galit Katarivas Levy, Jaroslaw Drelich, Jeremy Goldman

Michigan Tech Publications

Platinum-containing stents are commonly used in humans with hypercholesterolemia, whereas preclinical stent evaluation has commonly been performed in healthy animal models, providing inadequate information about stent performance under hypercholesterolemic conditions. In this investigation, we used an ApoE−/− mouse model to test the impact of hypercholesterolemia on neointima formation on platinum-containing implants. We implanted 125 μm diameter platinum wires into the abdominal aortas of ApoE−/− and ApoE+/+ mice for 6 months, followed by histological and immunofluorescence examination of neointimal size and composition. It was found that ApoE−/− mice developed neointimas with four times larger area and ten times greater thickness than …

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Material Design And Performance Of Carbon Monoxide-Fueled Solid Oxide Fuel Cells: A Review, Wei Zhang, Yun Hang Hu Jun 2023

Material Design And Performance Of Carbon Monoxide-Fueled Solid Oxide Fuel Cells: A Review, Wei Zhang, Yun Hang Hu

Michigan Tech Publications

Solid oxide fuel cells (SOFCs) are electrochemical energy conversion devices with fuel flexibility. Since carbon monoxide (CO) is a major product of SOFC anodes operating with hydrocarbon fuels, direct utilization of CO as a fuel is expected for more efficient operation of SOFCs. A review on CO-fueled SOFC technologies is imperative to promote research activities in this important field, but it has not been published. In this review, we summarize and comment on literatures in this field, with respect to (1) materials developed for three fundamental components (anode, cathode, and electrolyte), (2) power output and stabilization strategies, and (3) critical …

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Turning Dead Leaves Into An Active Multifunctional Material As Evaporator, Photocatalyst, And Bioplastic, Siyuan Fang, Xingyi Lyu, Tian Tong, Aniqa Ibnat Lim, Tao Li, Jiming Bao, Yun Hang Hu Mar 2023

Turning Dead Leaves Into An Active Multifunctional Material As Evaporator, Photocatalyst, And Bioplastic, Siyuan Fang, Xingyi Lyu, Tian Tong, Aniqa Ibnat Lim, Tao Li, Jiming Bao, Yun Hang Hu

Michigan Tech Publications

Large numbers of leaves fall on the earth each autumn. The current treatments of dead leaves mainly involve completely destroying the biocomponents, which causes considerable energy consumption and environmental issues. It remains a challenge to convert waste leaves into useful materials without breaking down their biocomponents. Here, we turn red maple dead leaves into an active three-component multifunctional material by exploiting the role of whewellite biomineral for binding lignin and cellulose. Owing to its intense optical absorption spanning the full solar spectrum and the heterogeneous architecture for effective charge separation, films of this material show high performance in solar water …

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Austenite Formation And Manganese Partitioning During Double Soaking Of An Ultralow Carbon Medium-Manganese Steel, Josh J. Mueller, Alexandra G. Glover, David K. Matlock, John G. Speer, Emmanuel De Moor Mar 2023

Austenite Formation And Manganese Partitioning During Double Soaking Of An Ultralow Carbon Medium-Manganese Steel, Josh J. Mueller, Alexandra G. Glover, David K. Matlock, John G. Speer, Emmanuel De Moor

Michigan Tech Publications

Double soaking (DS) is a thermal processing route intended to produce austenite–martensite microstructures in steels containing austenite-stabilizing additions and consists of intercritical annealing (primary soaking), followed by heating and brief isothermal holding at an increased temperature (secondary soaking), and quenching. Herein, experimental dilatometry during DS of a medium-manganese (Mn) steel with nominally 7 wt% Mn and an ultralow residual carbon concentration, in combination with phase-field simulations of austenite formation during secondary soaking, is presented. The feasibility of maintaining heterogeneous Mn distributions during DS is demonstrated and insight is provided on the effects of the secondary soaking temperature and prior Mn …

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Can Grid-Tied Solar Photovoltaics Lead To Residential Heating Electrification? A Techno-Economic Case Study In The Midwestern U.S., Nelson Sommerfeldt, Joshua M. Pearce Feb 2023

Can Grid-Tied Solar Photovoltaics Lead To Residential Heating Electrification? A Techno-Economic Case Study In The Midwestern U.S., Nelson Sommerfeldt, Joshua M. Pearce

Michigan Tech Publications

This study aims to quantify the techno-economic potential of using solar photovoltaics (PV) to support heat pumps (HP) towards the replacement of natural gas heating in a representative North American residence from a house owner's point of view. For this purpose, simulations are performed on: (1) a residential natural gas-based heating system and grid electricity, (2) a residential natural gas-based heating system with PV to serve the electric load, (3) a residential HP system with grid electricity, and (4) a residential HP+PV system. Detailed descriptions are provided along with a comprehensive sensitivity analysis for identifying specific boundary conditions that enable …

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Temperature, Pressure, And Adsorption Dependent Redox Potentials: Iii. Processes Of Co Conversion To Value-Added Compounds, Siyuan Fang, Yun Hang Hu Jan 2023

Temperature, Pressure, And Adsorption Dependent Redox Potentials: Iii. Processes Of Co Conversion To Value-Added Compounds, Siyuan Fang, Yun Hang Hu

Michigan Tech Publications

Carbon monoxide (CO) is a primary air pollutant and a poisonous species for human beings, animals, and some catalytic reactions. Meanwhile, CO is also a versatile feedstock in the chemical industry to produce high‐value chemicals and clean fuels, which has stimulated extensive research interests in exploiting efficient CO conversion processes. Redox potential is a key thermodynamic quantity in these processes whereas only standard reduction potentials at 25°Cand 1 atm are currently available. Herein, it is the first time to report the effects of temperature (0–1000°C), pressure (1–100 atm), and adsorption on the redox potentials of 18 CO conversion reactions to …

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Conductive 3d Nano-Biohybrid Systems Based On Densified Carbon Nanotube Forests And Living Cells, Roya Bagheri, Alicia K. Ball, Masoud Kasraie, Aparna Chandra, Xinqian Chen, Ibrahim Miskioglu, Zhiying Shan, Parisa Pour Shahid Saeed Abadi Jan 2023

Conductive 3d Nano-Biohybrid Systems Based On Densified Carbon Nanotube Forests And Living Cells, Roya Bagheri, Alicia K. Ball, Masoud Kasraie, Aparna Chandra, Xinqian Chen, Ibrahim Miskioglu, Zhiying Shan, Parisa Pour Shahid Saeed Abadi

Michigan Tech Publications, Part 2

Conductive biohybrid cell-material systems have applications in bioelectronics and biorobotics. To date, conductive scaffolds are limited to those with low electrical conductivity or 2D sheets. Here, 3D biohybrid conductive systems are developed using fibroblasts or cardiomyocytes integrated with carbon nanotube (CNT) forests that are densified due to interactions with a gelatin coating. CNT forest scaffolds with a height range of 120–240 µm and an average electrical conductivity of 0.6 S/cm are developed and shown to be cytocompatible as evidenced from greater than 89% viability measured by live-dead assay on both cells on day 1. The cells spread on top and …

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Size Distribution, Elemental Composition And Morphology Of Nanoparticles Separated From Respirable Coal Mine Dust, Shoeleh Assemi, Lei Pan, Xuming Wang, Titilayo Akinseye, Jan D. Miller Jan 2023

Size Distribution, Elemental Composition And Morphology Of Nanoparticles Separated From Respirable Coal Mine Dust, Shoeleh Assemi, Lei Pan, Xuming Wang, Titilayo Akinseye, Jan D. Miller

Michigan Tech Publications

Nanoparticles, defined as particles with one dimension below 100 nm, contribute little to the total mass concentration in respirable coal mine dust (RCMD) toxicological studies, but they could have a considerable part in the adverse health effects by RCMD inhalation. It has been shown that inhaled nanoparticles can penetrate deep into the lung and could plausibly contribute to acute and chronic pulmonary diseases by triggering oxidative stress formation and inducing inflammation. RCMD nanoparticles from samples collected in an underground mine in the United States were analyzed by a particle separation technique, field-flow fractionation (FFF), for size, morphology, and elemental composition. …

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Fluid Droplet Spreading And Adhesion Studied With A Microbalance: A Review, Youhua Jiang, Jaroslaw Drelich Nov 2022

Fluid Droplet Spreading And Adhesion Studied With A Microbalance: A Review, Youhua Jiang, Jaroslaw Drelich

Michigan Tech Publications

A contact angle observed for a liquid–solid system is not necessarily a unique value, and a few contact angles need to be considered carefully in relation to liquid spreading, adhesion and phase separation. Understanding of the significance of different contact angles has improved in the last few years through direct measurements of interactive forces between droplets/bubbles and solids together with the simultaneous visualization of the changes in their shapes. A microelectronic balance system is employed to measure the force of spreading after either liquid droplet or gas bubble attachment to a substrate surface and the droplet/bubble–substrate adhesion forces after droplet/bubble …

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Carbonate-Superstructured Solid Fuel Cells With Hydrocarbon Fuels, Hanrui Su, Wei Zhang, Yun Hang Hu Oct 2022

Carbonate-Superstructured Solid Fuel Cells With Hydrocarbon Fuels, Hanrui Su, Wei Zhang, Yun Hang Hu

Michigan Tech Publications

A basic requirement for solid oxide fuel cells (SOFCs) is the sintering of electrolyte into a dense impermeable membrane to prevent the mixing of fuel and oxygen for a sufficiently high open-circuit voltage (OCV). However, herein, we demonstrate a different type of fuel cell, a carbonate-superstructured solid fuel cell (CSSFC), in which in situ generation of superstructured carbonate in the porous samarium-doped ceria layer creates a unique electrolyte with ultrahigh ionic conductivity of 0.17 S.cm21 at 550 °C. The CSSFC achieves unprecedented high OCVs (1.051 V at 500 °C and 1.041 V at 550 °C) with methane fuel. Furthermore, the …

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Development Of High-Performance Fiber Cement: A Case Study In The Integration Of Circular Economy In Product Design, Parinya Chakartnarodom, Sarunya Wanpen, Wichit Prakaypan, Edward A. Laitila, Nuntaporn Kongkajun Sep 2022

Development Of High-Performance Fiber Cement: A Case Study In The Integration Of Circular Economy In Product Design, Parinya Chakartnarodom, Sarunya Wanpen, Wichit Prakaypan, Edward A. Laitila, Nuntaporn Kongkajun

Michigan Tech Publications

A new fiber cement (FC) is designed with the integration of circular economy (CE) concepts, in particular a product that is recyclable yet maintains performance. The FC samples were prepared from the mixtures of ordinary Portland cement (OPC), sand, and cellulose fibers, and required an inclusion compound (IC) and water. From the heat of hydration tests, the most effective IC, IC1, was prepared from lithium silicate, sodium thiocyanate, alkylbenzene sulfonate, and hydrochloric acid. The FC samples were recycled by crushing and grinding, then used as sand replacement in varying amounts to produce new FC samples. The results from the mechanical …

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Thermal Post-Processing Of 3d Printed Polypropylene Parts For Vacuum Systems, Pierce Mayville, Aliaksei L. Petsiuk, Joshua M. Pearce Sep 2022

Thermal Post-Processing Of 3d Printed Polypropylene Parts For Vacuum Systems, Pierce Mayville, Aliaksei L. Petsiuk, Joshua M. Pearce

Michigan Tech Publications

Access to vacuum systems is limited because of economic costs. A rapidly growing approach to reduce the costs of scientific equipment is to combine open-source hardware methods with digital distributed manufacturing with 3D printers. Although high-end 3D printers can manufacture vacuum components, again, the cost of access to tooling is economically prohibitive. Low-cost material extrusion 3D printing with plastic overcomes the cost issue, but two problems arise when attempting to use plastic in or as part of vacuum systems: the outgassing of polymers and their sealing. To overcome these challenges, this study explores the potential of using post-processing heat treatments …

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Do Agrivoltaics Improve Public Support For Solar? A Survey On Perceptions, Preferences, And Priorities, Alexis Pascaris, Chelsea Schelly, Mark Rouleau, Joshua Pearce Aug 2022

Do Agrivoltaics Improve Public Support For Solar? A Survey On Perceptions, Preferences, And Priorities, Alexis Pascaris, Chelsea Schelly, Mark Rouleau, Joshua Pearce

Michigan Tech Publications

Agrivoltaic systems integrate agricultural production with solar photovoltaic electricity generation. Given the proven technical, economic, and environmental co-benefits provided by agrivoltaic systems, increased proliferation is anticipated, which necessitates accounting for the nuances of community resistance to solar development on farmland and identifying pathways for mitigation. Minimizing siting conflict and addressing agricultural communities’ concerns will be key in continued deployment of agrivoltaics, as localized acceptance of solar is a critical determinant of project success. This survey study assessed if public support for solar development increases when energy and agricultural production are combined in an agrivoltaic system. Results show that 81.8% of …

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Utilization Of Bayesian Optimization And Kwn Modeling For Increased Efficiency Of Al‐Sc Precipitation Strengthening, Kyle Deane, Yang Yang, Joseph Licavoli, Vu Nguyen, Santu Rana, Sunil Gupta, Svetha Venkatesh, Paul G. Sanders Jun 2022

Utilization Of Bayesian Optimization And Kwn Modeling For Increased Efficiency Of Al‐Sc Precipitation Strengthening, Kyle Deane, Yang Yang, Joseph Licavoli, Vu Nguyen, Santu Rana, Sunil Gupta, Svetha Venkatesh, Paul G. Sanders

Michigan Tech Publications

The Kampmann and Wagner numerical model was adapted in MATLAB to predict the precipitation and growth of Al3Sc precipitates as a function of starting concentration and heat‐treatment steps. This model was then expanded to predict the strengthening in alloys using calculated average precipitate number density, radius, etc. The calibration of this model was achieved with Bayesian optimization, and the model was verified against experimentally gathered hardness data. An analysis of the outputs from this code allowed the development of optimal heat treatments, which were validated experimentally and proven to result in higher final strengths than were previously observed. Bayesian optimization …

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Energy Science & Engineering: 10 Years Of Excellence, Yun Hang Hu May 2022

Energy Science & Engineering: 10 Years Of Excellence, Yun Hang Hu

Michigan Tech Publications

No abstract provided.

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Ultrahigh Piezoelectric Performance Through Synergistic Compositional And Microstructural Engineering, Yongke Yan, L. D. Geng, Li Feng Zhu, Haoyang Leng, Xiaotian Li, Hairui Liu, Dabin Lin, Ke Wang, Yu Wang, Shashank Priya Mar 2022

Ultrahigh Piezoelectric Performance Through Synergistic Compositional And Microstructural Engineering, Yongke Yan, L. D. Geng, Li Feng Zhu, Haoyang Leng, Xiaotian Li, Hairui Liu, Dabin Lin, Ke Wang, Yu Wang, Shashank Priya

Michigan Tech Publications

Piezoelectric materials enable the conversion of mechanical energy into electrical energy and vice-versa. Ultrahigh piezoelectricity has been only observed in single crystals. Realization of piezoelectric ceramics with longitudinal piezoelectric constant (d33) close to 2000 pC N–1, which combines single crystal-like high properties and ceramic-like cost effectiveness, large-scale manufacturing, and machinability will be a milestone in advancement of piezoelectric ceramic materials. Here, guided by phenomenological models and phase-field simulations that provide conditions for flattening the energy landscape of polarization, a synergistic design strategy is demonstrated that exploits compositionally driven local structural heterogeneity and microstructural grain orientation/texturing to provide record piezoelectricity in …

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The Influence Of Different Crystal Modifiers On Ultra-Low Embodied Energy Curing Fiber-Reinforced Cement Composites, Passakorn Sonprasarn, Wichit Prakaypan, Sureerat Polsilapa, Nuntaporn Kongkajun, Edward A. Laitila, Nutthita Chuankrerkkul, Parinya Chakartnarodom Jan 2022

The Influence Of Different Crystal Modifiers On Ultra-Low Embodied Energy Curing Fiber-Reinforced Cement Composites, Passakorn Sonprasarn, Wichit Prakaypan, Sureerat Polsilapa, Nuntaporn Kongkajun, Edward A. Laitila, Nutthita Chuankrerkkul, Parinya Chakartnarodom

Michigan Tech Publications

Fiber-reinforced cement composites (FRCC) are widely used in the construction of houses and commercial buildings in many countries such as the United States, the United Kingdom, the European countries, and the Asian countries such as China, India, and Thailand. Conventionally, the FRCC is manufactured from Portland cement, silica sand, and cellulose fiber using the so-called autoclaved curing under a designate hydrothermal condition to accelerate the hydration reaction resulting in superior properties. However, the autoclave-curing process needs a huge investment and generates highly environmental impact specially greenhouse gases due to its heavy energy consumption. Hence, this research aims to develop the …

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Bioabsorbable Metal Zinc Differentially Affects Mitochondria In Vascular Endothelial And Smooth Muscle Cells, Olivia R. M. Bagshaw, Fereshteh Moradi, Christopher S. Moffatt, Hillary A. Hettwer, Ping Liang, Jeremy Goldman, Jaroslaw Drelich, Jeffrey A. Stuart Dec 2021

Bioabsorbable Metal Zinc Differentially Affects Mitochondria In Vascular Endothelial And Smooth Muscle Cells, Olivia R. M. Bagshaw, Fereshteh Moradi, Christopher S. Moffatt, Hillary A. Hettwer, Ping Liang, Jeremy Goldman, Jaroslaw Drelich, Jeffrey A. Stuart

Michigan Tech Publications

Zinc is an essential trace element having various structural, catalytic and regulatory interactions with an estimated 3000 proteins. Zinc has drawn recent attention for its use, both as pure metal and alloyed, in arterial stents due to its biodegradability, biocompatibility, and low corrosion rates. Previous studies have demonstrated that zinc metal implants prevent the development of neointimal hyperplasia, which is a common cause of restenosis following coronary intervention. This suppression appears to be smooth muscle cell-specific, as reendothelization of the neointima is not inhibited. To better understand the basis of zinc's differential effects on rat aortic smooth muscle (RASMC) versus …

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Life Cycle Assessment Of Pasture-Based Agrivoltaic Systems: Emissions And Energy Use Of Integrated Rabbit Production, Alexis Pascaris, Robert Handler, Chelsea Schelly, Joshua Pearce Dec 2021

Life Cycle Assessment Of Pasture-Based Agrivoltaic Systems: Emissions And Energy Use Of Integrated Rabbit Production, Alexis Pascaris, Robert Handler, Chelsea Schelly, Joshua Pearce

Michigan Tech Publications

Agrivoltaic systems, which deliberately maximize the utility of a single parcel of land for both solar photovoltaic (PV) electricity production and agriculture, have been demonstrated as a viable technology that can ameliorate competing land uses and meet growing energy and food demands efficiently. The goal of this study is to assess the environmental impacts of a novel pasture-based agrivoltaic concept: co-farming rabbits and solar PV. A life cycle assessment (LCA) quantified the impacts of 1) the integrated agrivoltaic concept in comparison to conventional practices including 2) separate rabbit farming and PV production and 3) separate rabbit farming and conventional electricity …

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