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Magnetic Ordering In The Rare Earth Intermetallic Compound Tb₂Ti₃Ge₄: Magnetization And Neutron Diffraction Studies, Satish K. Malik, Jagat Lamsal, R. L. De Almeida, S. Quezado, William B. Yelon, V. O. Garlea, A. V. Morozkin, R. Nirmala

Physics Faculty Research & Creative Works

Magnetization and neutron diffraction studies on a polycrystalline Tb2Ti3Ge4 sample (orthorhombic Sm5Ge4-type structure, space group Pnma, No. 62) have been carried out. This compound is found to order antiferromagnetically at ~18 K (TN). The magnetization (M) versus field (H) isotherms obtained at 2, 3, 5, and 10 K indicate a field-induced antiferromagnetic to ferromagnetic transition in fields of the order of 0.5 T. The saturation magnetization value at 2.5 K (M extrapolated to 1/H-->0) is only ~5.6µB/Tb3+, suggesting the possible presence of crystal field effects with or without a persisting antiferromagnetic component. Neutron powder diffraction data at 10 K …