Materials Science and Engineering Commons^™

Electrical Properties Of Phosphate Glasses, Andrea Mogus-Milankovic, Ana Santic, Signo Tadeu Dos Reis, D. E. Day

Materials Science and Engineering Faculty Research & Creative Works

Investigation of the electrical properties of phosphate glasses where transition metal oxide such as iron oxide is the network former and network modifier is presented. Phosphate glasses containing iron are electronically conducting glasses where the polaronic conduction is due to the electron hopping from low to high iron valence state. The identification of structural defects caused by ion/polaron migration, the analysis of dipolar states and electrical conductivity in iron phosphate glasses containing various alkali and mixed alkali ions was performed on the basis of the impedance spectroscopy (IS). The changes in electrical conductivity from as-quenched phosphate glass to fully crystallized …