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Full-Text Articles in Materials Science and Engineering

Hybrid Polymer Electrolyte For Lithium-Oxygen Battery Application, Amir Chamaani Oct 2017

Hybrid Polymer Electrolyte For Lithium-Oxygen Battery Application, Amir Chamaani

FIU Electronic Theses and Dissertations

The transition from fossil fuels to renewable resources has created more demand for energy storage devices. Lithium-oxygen (Li-O2) batteries have attracted much attention due to their high theoretical energy densities. They, however, are still in their infancy and several fundamental challenges remain to be addressed. Advanced analytical techniques have revealed that all components of a Li-O2 battery undergo undesirable degradation during discharge/charge cycling, contributing to reduced cyclability. Despite many attempts to minimize the anode and cathode degradation, the electrolyte remains as the leading cause for rapid capacity fading and poor cyclability in Li-O2 batteries. In this …


Three-Dimensional Graphene Foam Reinforced Epoxy Composites, Leslie Embrey Mar 2017

Three-Dimensional Graphene Foam Reinforced Epoxy Composites, Leslie Embrey

FIU Electronic Theses and Dissertations

Three-dimensional graphene foam (3D GrF) is an interconnected, porous structure of graphene sheets with excellent mechanical, electrical and thermal properties, making it a candidate reinforcement for polymer matrices. GrF’s 3D structure eliminates nanoparticle agglomeration and provides seamless pathways for electron travel. The objective of this work is to fabricate low density GrF reinforced epoxy composites with superior mechanical and electrical properties and study the underlying deformation mechanisms. Dip coating and mold casting fabrication methods are employed in order to tailor the microstructure and properties. The composite’s microstructure revealed good interfacial interaction. By adding mere 0.63 wt.% GrF, flexural strength was …