Materials Science and Engineering Commons^™

Tunable Electronic And Optical Properties Of Low-Dimensional Materials, Shiyuan Gao

Arts & Sciences Electronic Theses and Dissertations

Two-dimensional (2D) materials with single or a few atomic layers, such as graphene, hexagonal boron nitride (h-BN) and transition metal dichalcogenides (TMDCs), and the heterostructures or one-dimensional (1D) nanostructures they form, have attracted much attention recently as unique platforms for studying many condensed-matter phenomena and holds great potentials for nanoelectronics and optoelectronic applications. Apart from their unique intrinsic properties which has been intensively studied for over a decade by now, they also allow external control of many degrees of freedom, such as electrical gating, doping and layer stacking. In this thesis, I present a theoretical study of the electronic and …

Multifunctional Nanocomposites Based On Bacterial Cellulose, Qisheng Jiang

McKelvey School of Engineering Theses & Dissertations

Cellulose is biodegradable, renewable, and abundant in nature thus cellulose (or paper)-based products can be inexpensively produced and recycled. Among cellulosic materials, bacterial nanocellulose (BNC) draws a special research attention due to the inherent three-dimensional nanofibrous structure, excellent mechanical flexibility, high purity and well-defined surface chemistry, and cost-efficient, scalable and environment-friendly synthesis. BNC can be biosynthesized by Gluconacetobacter xylinus, which is the most characterized BNC producer among various microorganisms. BNC is composed of highly pure cellulose nanofibrils, produced from well-defined dextrose through biochemical steps and subsequent self-assembling of the secreted cellulose fibrils which has the dimension ranges from 25 to …

Multifunctional Nanocomposites Based On Bacterial Cellulose, Qisheng Jiang

McKelvey School of Engineering Theses & Dissertations

Cellulose is biodegradable, renewable, and abundant in nature thus cellulose (or paper)-based products can be inexpensively produced and recycled. Among cellulosic materials, bacterial nanocellulose (BNC) draws a special research attention due to the inherent three-dimensional nanofibrous structure, excellent mechanical flexibility, high purity and well-defined surface chemistry, and cost-efficient, scalable and environment-friendly synthesis. BNC can be biosynthesized by Gluconacetobacter xylinus, which is the most characterized BNC producer among various microorganisms. BNC is composed of highly pure cellulose nanofibrils, produced from well-defined dextrose through biochemical steps and subsequent self-assembling of the secreted cellulose fibrils which has the dimension ranges from 25 to …

Linking Structure And Dynamics In Metallic Liquids: A Combined Experimental And Molecular Dynamics Approach, Robert Ashcraft

Arts & Sciences Electronic Theses and Dissertations

A major outstanding problem in condensed matter physics is the nature of the glass transition, in which a rapidly cooled liquid can bypass the transition into a crystalline state and the liquid structure is "frozen-in" due to kinetic arrest. To characterize the fundamental features behind this transition the liquid, both in the high temperature (equilibrium) and supercooled state, needs to be better understood. By examining the relationship between structure and dynamics a better characterization of the liquid state and a determination of the mechanisms that are ultimately important for the formation of the glass can be gained. In this dissertation, …

Measuring Characteristic Shrinkage Variability Due To Metal Loading Effects In Low Temperature Co-Fired Ceramic Using Image Processing, John Ezekiel Zumbro

Graduate Theses and Dissertations

Low temperature co-fired ceramic (LTCC) has many benefits when it comes to electronic packaging due to the low dielectric loss, reliability in extreme environments, and high breakdown voltage. Though the ceramic has a lot of benefits it is not widely used due to the high cost and complexities associated with manufacturing. One of these issues with manufacturing is compensating for the shrinkage of the ceramic, this is accomplished by using an expansion factor, creating the “green” or manufactured design. This expansion factor is approximated through knowledge of the ceramic factors such as the metal loading, layers of ceramic tape, firing …

Comparative Study Of Power Semiconductor Devices In A Multilevel Cascaded H-Bridge Inverter, Kenneth Mordi

Graduate Theses and Dissertations

This thesis compares the performance of a nine-level transformerless cascaded H-bridge (CHB) inverter with integrated battery energy storage system (BESS) using SiC power MOSFETs and Si IGBTs. Two crucial performance drivers for inverter applications are power loss and efficiency. Both of these are investigated in this thesis. Power devices with similar voltage and current ratings are used in the same inverter topology, and the performance of each device is analyzed with respect to switching frequency and operating temperature. The loss measurements and characteristics within the inverter are discussed. The Saber® simulation software was used for the comparisons. The power MOSFET …

Reinventing The Wheel, Esther K. Unti, Ahmed Z. Shorab, Patrick B. Kragen, Adam M. Menashe

Mechanical Engineering

Reinventing the Wheel selected tires and designed wheels for the 2018 Cal Poly, San Luis Obispo Formula SAE combustion vehicle. Available tire options were evaluated for steady-state and transient performance as well as vehicle integration. A single-piece composite wheel with hollow spokes was designed to meet stiffness, strength, and tolerance requirements. A detailed study of wheel loading and geometric structural efficiency was performed. Finite element analysis was used to iterate the geometry and laminate. A two-piece male mold was designed and machined to manufacture the wheel. Removable silicone inserts were used to create the hollow spokes.

A Study Of The Diffusion Characteristics Of Tungsten Bar Stock And Tungsten Produced Via Direct Metal Laser Sintering (Dmls), Jonathan Robert Bruss

Master's Theses (2009 -)

Using a vacuum hot extraction method diffusivity and concentration of hydrogen were measured in samples of tungsten bar stock and direct metal laser sintered (DMLS) tungsten. It was found that the tungsten bar stock closely adhered to the model established by Frauenfelder. The DMLS samples approximately follow a downward sloping trend over the 500K-1200K temperature range. The trend is opposite of what is expected suggesting processing has a major effect on diffusion behavior. A CFD model was created using ANSYS Fluent to simulate the diffusion behavior. The model functions by separating out diffusion mechanisms and solving Fick’s law with each …

Electrospun Collagen Fibers For Tissue Regeneration Applications, Ying Li

Electronic Thesis and Dissertation Repository

Tissue engineering aims to regenerate damaged and deceased tissue by combining cells with scaffold made from an appropriate biomaterial and providing a conducive environment to guide cell growth and the formation or regeneration of new tissue or organ. While collagen, an important material of the extracellular matrix (ECM), is a natural choice as a scaffold biomaterial, the conducive environment can only be created by having the ability to control the geometry, organization, structural and mechanical properties of the scaffold. Moreover, degradability and degradation rate control of the scaffold has to be taken into consideration too. In this work, we aim …

Synthesis Of Crumpled Graphene And Titanium Dioxide Based–Nanomaterials And The Application To Carbon Dioxide Photoreduction, Yao Nie

McKelvey School of Engineering Theses & Dissertations

With the rapid development of the economy, increasing combustion of fossils fuels has caused an increase in the atmospheric carbon dioxide (CO2) level, and has led to global climate change. As a mitigation approach, CO2 capture and conversion (CCC) can not only capture CO2, but also convert it to useable products, such as hydrocarbon fuels. Photocatalytic reduction is an attractive CCC option that directly harnesses inexpensive and abundant solar energy. Titanium dioxide (TiO2) is a widely used semiconductor for photocatalysis, and graphene nanosheets are a promising material for use in fabricating graphene-TiO2 hybridized photocatalysts. To realize the application of these …

Modeling And Validations Of Control Parameters For Material Extrusion-Based Additive Manufacturing Of Thixotropic Aluminum Alloys., Lars Herhold

Electronic Theses and Dissertations

Additive Manufacturing (AM) with metals has been accomplished mainly through powder bed fusion processes. Initial experiments and simulations using Material Extrusion Additive Manufacturing (MEAM) have been performed by various researchers especially using low melting alloys. Recently Stratasys Inc. submitted a patent application for the use of their Material Extrusion technology also called Fused Deposition Modeling (FDM) where they describe the process using thixotropic semi-solid alloys. Currently this process using semi-solid, engineering type alloys such as A356 or THIXALLOY 540 aluminum have not been researched to evaluate the control parameters. This research combines the in-depth knowledge of applying thixotropic semi-solid aluminum …

Engineering Next Generation Anisotropic Materials And Composites, Nihal Kanbargi

Doctoral Dissertations

Polymer-based composite systems have been developed for a wide variety of applications ranging from aerospace to electronics. My work has focused on the structure-process-property relationships of anisotropic polymeric materials and composites, aimed primarily for structural applications. Anisotropic materials such as fibers have superior mechanical properties along the axial direction and this property can be exploited to engineer exceptionally strong and light materials. In the first chapter, we discuss the physics of degradation of Poly(p-phenylene-2,6-benzobisoxazole) (PBO) fibers. PBO, a fiber of extraordinary tensile modulus and strength has been found to degrade rapidly under moderate conditions of humidity and heat. Solid-state NMR …

High Strain Rate Dynamic Response Of Aluminum 6061 Micro Particles At Elevated Temperatures And Varying Oxide Thicknesses Of Substrate Surface, Carmine Taglienti

Masters Theses

Cold spray is a unique additive manufacturing process, where a large number of ductile metal micro particles are deposited to create new surface coatings or free-standing structures. Metallic particles are accelerated through a gas stream, reaching velocities of over 1 km/s. Accelerated particles experience a high-strain-rate microscopic ballistic collisions against a target substrate. Large amounts of kinetic energy results in extreme plastic deformation of the particles and substrate. Though the cold spray process has been in use for decades, the extreme material science behind the deformation of particles has not been well understood due to experimental difficulties arising from the …

Effect Of Material Viscoelasticity On Frequency Tuning Of Dielectric Elastomer Membrane Resonators, Liyang Tian

Electronic Thesis and Dissertation Repository

Dielectric elastomers (DEs) capable of large voltage-induced deformation show promise for applications such as resonators and oscillators. However, the dynamic performance of such vibrational devices is not only strongly affected by the nonlinear electromechanical coupling and material hyperelasticity, but also significantly by the material viscoelasticity. The material viscoelasticity of DEs originates from the highly mobile polymer chains that constitute the polymer networks of the DE. Moreover, due to the multiple viscous polymer subnetworks, DEs possess multiple relaxation processes. Therefore, in order to predict the dynamic performance of DE-based devices, a theoretical model that accounts for the multiple relaxation processes is …

Analysis Of The Low-Cycle Fatigue Behavior Of Silicone Rubber For Biomedical Balloons, Chase Cooper

Materials Engineering

The development of a medical drug delivery device that allows for the deployment drugs into the adventitial tissue of blood vessels requires the inflation of a silicone elastomer. The inflated silicone must be able to consistently endure multiple loading cycles without failing so that the device can operate reliably. There are multiple methods of processing the silicone for the device and the goal of this study is to examine the effect of the various processing methods on the characteristics of the silicone. The Dynamic Mechanical Analysis Machine (DMA) is used to model the conditions of the device’s application by performing …

Ultrasonic Nondestructive Evaluation Of Metal Additive Manufacturing., Venkata Karthik Nadimpalli

Electronic Theses and Dissertations

Metal Additive Manufacturing (AM) is increasingly being used to make functional components. One of the barriers for AM components to become mainstream is the difficulty to certify them. AM components can have widely different properties based on process parameters. Improving an AM processes requires an understanding of process-structure-property correlations, which can be gathered in-situ and post-process through nondestructive and destructive methods. In this study, two metal AM processes were studied, the first is Ultrasonic Additive Manufacturing (UAM) and the second is Laser Powder Bed Fusion (L-PBF). The typical problems with UAM components are inter-layer and inter-track defects. To improve the …

Mechanical Characterization And Shear Test Comparison For Continuous-Fiber Polymer Composites, Matthew Crossan

Electronic Thesis and Dissertation Repository

As fiber-reinforced composites continue to be used in a wide-range of high performance structures, more detailed understanding and accurate prediction of stress-strain behaviour is necessary to improving designs and reducing costs. This thesis compares the experimental behaviour of a continuous fiber polymer composite of carbon fiber and epoxy resin using Digital Image Correlation to analytical and theoretical predictions. Furthermore, an in-depth analysis of shear testing methods reveals the advantages and limitations of different testing standards. Finally, the limitations of the Iosipescu Shear test (ASTM 5379) fixture to break high-strain-to-failure composites in comparison to the V-notched Rail Shear Fixture (ASTM 7078) …

Modeling Deformation Behavior And Strength Characteristics Of Sand-Silt Mixtures: A Micromechanical Approach, Mehrashk Meidani

Doctoral Dissertations

This dissertation is comprised of six chapters. In the first chapter the motivation of this research, which was modeling the deformation behavior and strength characteristics of soils under internal erosion, is briefly explained. In the second chapter a micromechanis-based stress-strain model developed for prediction of sand-silt mixtures behavior is presented. The components of the micromechanics-based model are described and undrained behavior of six different types of sand-silt mixtures is predicted for several samples with different fines contents. The need for a more comprehensive compression model for sand-silt mixtures is identified at the end of this chapter. This desired compression model …

Creep Of Hafnium Diboride -20 Vol% Silicon Carbide At 1500°C In Air, Glen E. Pry

Theses and Dissertations

Refractory metal borides, commonly referred to as Ultra High Temperature Ceramics (UHTCs), exhibit a number of unique properties, such as extremely high melting temperature and hardness, chemical stability, high electrical and thermal conductivity and corrosion resistance. It has been demonstrated that the addition of SiC improves the oxidation resistance of ZrB2- and HfB2-based UHTCs above 1200°C by modifying the composition of the oxide scale. Addition of SiC retards the oxidation rate of ZrB2 and HfB2 by forming a protective layer of borosilicate glass. Creep deformation is one of the critical criterion for structural application of ceramics at elevated temperatures. Compression …

Tensile Properties And Fatigue Behavior Of Geopolymer Matrix Composites With Carbon Fiber Reinforcement At Elevated Temperature, Steffan M.L. Wilcox

Theses and Dissertations

The tensile stress-strain and tension-tension fatigue of geopolymer matrix composites reinforced with 0/90 carbon fibers was investigated at 23 and 300°C in laboratory air. Geopolymers are inorganic polymeric materials composed of alumina, silica, and alkali metal oxides. Because geopolymers are synthesized as a fluid mixture or particles and liquid, they can be cast into a desired shape, and cured at only slightly elevated temperatures. The relative ease of synthesis and low processing temperatures make geopolymers an attractive choice as a matrix material for composite materials. Geopolymers also offer resistance to heat and oxidizing environments. Currently, geopolymer matrix composites are being …

Structural And Optical Investigations Of Rbxcs1-Xh2po4, Alex D. Price

Open Access Theses & Dissertations

Proton conductor solid acid electrolytes RbxCs1-xH2PO4 (0≤x≤1) have been investigated using second harmonic generation and powder x-ray diffraction. Second harmonic generation is an optical technique which can be used to study the structural properties of materials. Microscopes of this nature have the ability to image objects with a variable penetration depth in a non-destructive manner, allowing for great potential to be used for in situ observations of the electrolyte’s structure when in a fuel cell under operating conditions.

X-ray powder diffraction was carried out on the series of samples and found for values of 0≤x≤0.5 the structure of the material …

Effects Of Air And Other Gases In The Stabilization Process Of The Superprotonic Phase Of Cesium Dihydrogen Phosphate Within A Hermetically Sealed Chamber, Israel Martinez

Open Access Theses & Dissertations

The solid acid CsH2PO4 (CDP), exhibits a sudden increase in its proton conductivity as it’s heated above a certain temperature (around T~235oC), which makes it a very attractive candidate to be used as an electrolyte in intermediate temperature fuel cells. Unfortunately, at these temperatures the sample is not stable, as starts to dehydrate; which causes a dramatic drop in the proton conductivity over a short period of time (less than one hour). In order to inhibit, or at least delay, the dehydration process, the solid acid it’s put under a saturated water vapor atmosphere. Another method to stabilize the highly …

Development And Characterization Of Novel Materials For The Advancement Of Additive Manufacturing By Material Extrusion 3d Printing, Jose Gilberto Siqueiros

Open Access Theses & Dissertations

The development of additive manufacturing technologies has been under the spotlight from the past decade due to its enormous potential to disrupt current manufacturing processes. Material extrusion 3D printing (ME3DP) is the most common type of additive manufacturing technology as it experienced an exponential growth after the expiration of the fused deposition modeling patent filed in 1989 by Scott Crump. The large interest behind this technology is generated from the capacity to create complex shapes, rapid prototyping, relatively ease of use, low cost, and high accessibility. The gradual evolution of material extrusion 3D printing calls to become a technology ordinarily …

A New Approach To Multiplanar, Real-Time Simulation Of Physiological Knee Loads And Synthetic Knee Components Augmented By Local Composition Control In Fused Filament Fabrication, Joshua Taylor Green

Open Access Theses & Dissertations

Despite numerous advances in biomedical engineering, few developments in surgical simulation have been made outside of computational models. Cadavers remain the primary media on which surgical research and simulation is conducted. Most attempts to quantify the effects of orthopedic surgical methods fail to achieve statistical significance due to limited quantities of cadaver specimen, large variations among the cadaver population, and a lack of repeatability among measurement techniques. The general purpose of the research covered in this dissertation is to develop repeatable simulation of physiological loads and develop techniques to fabricate a synthetic-based replacement of cadaver specimens. Future work applying this …

Titanium Incorporated Gallium Oxide (Ga-Ti-O): Structure Property Relationship And Performance Evaluation For Extreme Environment Applications, Sandeep Manandhar

Open Access Theses & Dissertations

The existing power generation systems, which utilize fossil fuels, are in dire need of efficient, reliable chemical sensors that can operate safely at higher temperatures. These sensors control the combustion environment and the emissions during combustion. Several sensing materials such as SnO2, ZnO, TiO2, WO3, and Ga2O3 exhibit high sensitivity to certain type of chemical molecules and in a certain range of temperatures. Among these candidate materials, β-Ga2O3 is stable at very high temperatures and has shown functionality for oxygen sensing at higher temperatures (>700°C). However, the response time and sensitivity must be significantly improved in order to derive …

Evaluation Of Large Area Additively Manufactured Fiber Reinforced Acrylonitrile Butadiene Styrene (Abs), Kevin Schnittker

Open Access Theses & Dissertations

To enable the advancement of large-scale additive manufacturing processes, it is necessary to establish and standardize methodologies to characterize the mechanical properties of printed test coupons. Due to the large size of the print beads, conventional test standards are inadequate. The focus of this study was to determine the feasibility of using Digital image correlation (DIC) technology as a key enabler for robust data collection of strain measurements of large 3D printed parts. To incorporate the DIC measurements, a novel method was developed to prepare large 20 wt.% glass filled ABS test coupons for adequate contrast. Through this technique, Poisson's …

Heterogeneous Integration Of Metallic, Semiconducting And Dielectric Two-Dimensional Layered Material Inks For Electronics And Sensing Device Platforms, Jay Amrish Desai

Open Access Theses & Dissertations

In monolayers of two-dimensional (2-D) layered materials, the motion of electrons is confined to a 2-D plane yielding a "zero" effective thickness with regard to the electrons. These monolayers are commonly obtained by exfoliating membranes from the bulk crystal to overcome the weak interplanar Van der Waals bonding using the so-called top-down approach. The bottom-up approach is another avenue to realize these materials, where atoms and molecules coalesce together into increasingly larger assemblies for the realization of the bulk three-dimensional (3-D) crystal. The unique properties of many of these 2-D materials make them highly sought out candidates for advancing conventional …

Streamlining Alloy Design And Thermo-Mechanical Processing Parameters For High Strength Line Pipe Steels And Hot Rolled Microalloyed Steels: Process - Structure - Property Paradigm, Venkata Vignesh Natarajan

Open Access Theses & Dissertations

The process parameters related to thermo-mechanical controlled processing (TMCP) of steels play a vital role in affecting the ultimate mechanical properties. We illustrate here the impact of coiling temperature, the impact of finish cooling temperature on interrupted cooling and compare with continuous cooling, and the impact of carbon and niobium on the microstructure and precipitation behavior and corresponding changes in mechanical properties, in an ultrahigh strength titanium-niobium microalloyed steel. The microstructural advancement was contemplated via transmission electron microscopy and electron backscattered diffraction (EBSD). The goal was to underscore the impact of coiling temperature on the nature and distribution of microstructural …

Characterization Of 3d Printed Polylactic Acid/ Polycaprolactone/Titanium Dioxide Composites For Bone Replacement And Grafting, Sandra Elena Najera Beltran

Open Access Theses & Dissertations

A material that mimics the properties of bones was developed by optimizing the ratio of polymer composites of polylactic acid (PLA) and poly-ε-caprolactone (PCL), containing small amounts of titanium oxide (TiO2). Although titanium-based alloys have commonly been used for bone replacement procedures due to their biocompatibility with the human body and their mechanical properties, stress shielding continues to be a problem. The structure of a bone has a porosity which permits the flow of nutrients, blood, oxygen and minerals, and is an issue at the time of creating bone replacements using conventional methods. PLA and PCL have been used in …

Solvent And Concentration Effects Governing The Hierarchical Organization Of Asphaltenes: A Small-Angle X-Ray Scattering Study, Hasan Rejoanur Rahman

Open Access Theses & Dissertations

Asphaltenes are a group of planar molecules found in crude oil and are prone to aggregation which often causes blockage of pipes along the oil production stream resulting a huge economic downside. In an effort to understand the hierarchical organization of asphaltene in different solvents and concentrations, the solution structure of various asphaltene solutions were studied using small-angle x-ray scattering (SAXS). Solvents were chosen based on miscibility maps. Such maps are generated on the critical value of the solubility parameter difference between asphaltenes or asphaltene components, and a range of solvents. The critical factors that affect asphaltene and asphaltene component …