Materials Science and Engineering Commons^™

Direct Electrochemistry And Glucose Biosensing Of Glucose Oxidase-Gold Nanoparticles Composite Synthesized By Enzyme Method, Fang He, Xiao-Li Qin, Ying-Chun Fu, Chao Chen, Qing-Ji Xie, Shou-Zhuo Yao

Journal of Electrochemistry

Glucose oxidase (GOx)-gold nanoparticles (AuNPs) composite was synthesized by the one-pot enzyme reaction in the mixture solution of NaAuCl₄, GOx and glucose, and a Nafion/GOx-AuNPs/glassy carbon electrode was fabricated by the cast-coating method to examine the direct electrochemistry of GOx and the biosensing performance on this electrode. Such a GOx-AuNPs composite showed good direct-electrochemistry activity and bioactivity of GOx, probably because the enzyme-mediated AuNPs are close to the redox active centers of GOx. This enzyme electrode exhibited a linear amperometric response to glucose concentration (0.54 mmol·L^-1) at -0.4 V (vs. SCE), and a detection limit of …

Synthesis Of Namnpo4 By Spraying Drying-High Temperature Sintering And Its Electrochemical Performance, Xiao-Chen Lin, Xiao-Biao Wu, Xu Hou, Yong Yang

Journal of Electrochemistry

As a cathode material for sodium ion batteries, NaMnPO₄/C nanocomposite is successfully synthesized by the combination of spraying drying and high temperature sintering methods. The crystal structure of the as-synthesized phosphate material is confirmed as the natrophilite NaMnPO₄, which possesses orthorhombic symmetry and Pmnb space group. It is shown that the precursors are hollow spherical particles and the obtained product consists of micro-scaled secondary particles, which are composed of NaMnPO₄ nanocrystallites (tens of nanometres) and amorphous carbon networks. The ionic and electronic conductivities of NaMnPO₄ are both effectively enhanced with the help of this …

Electrochemical Applications Of Single-Walled Carbon Nanohorns, Su-Ping Li, Huai-Min Guan, Shu-Yun Zhu, Muhammad Rehan Hassan Shah Gilani, Saima Hanif, Guo-Bao Xu, Yue-Jin Tong

Journal of Electrochemistry

Single-wall carbon nanohorns (SWCNHs) have unique properties, such as a large specific surface area, good electrical conductivity and biocompatibility. It has been widely utilized in many fields. In the present review, the progress in electrochemistry study of SWCNHs has been summarized and the future research trends have been proposed.

Comparison In Factors Affecting Electrochemical Properties Of Thermal-Reduced Graphene Oxide For Supercapacitors, Peng Xiao, Da-Hui Wang, Jun-Wei Lang

Journal of Electrochemistry

In this paper, thermal-reduced graphene oxide (T-RGO) materials are synthesized by modified Hummer’s method, followed by thermal reduction under argon atmosphere at different temperatures. Electrochemical investigations show that, for T-RGO electrodes, good electrical conductivity is necessary and the surface functional groups play more significant role than the specific surface area in determining the electrochemical capacitance. The T-RGO obtained at 900 °C (T-RGO900) with a relatively high Brunauer-Emmett-Teller (BET) surface area (314 m²·g^-1) and a high electrical conductivity (2421 S·m^-1) shows a low specific capacitance of 56 F·g^-1. In comparison, the T-RGO obtained …

One-Step Synthesis Of Pani/Nihcf Hybrid Film Using Unipolar Pulse Electrodeposition And Its Electrocatalytic Reduction Performance For H2O2 Detection, Sen-Liang Liao, Xiu-Min Li, Xiao-Gang Hao, Yan-Hong Wang, Chun-Feng Xue, Yong-Hong Wang

Journal of Electrochemistry

Organic–inorganic hybrid films composed of polyaniline/nickel hexacyanoferrate (PANI/NiHCF) were fabricated on platinum substrates using unipolar pulse one-step electrodeposition. The deposition mechanism of hybrid film was proposed: Due to high potential of unipolar pulse electrodeposition, which avoided the reduction of Fe(CN)₆^3-, the films with high electrocatalytic property and “insoluble” form of NiHCF were achieved. The morphology and composition of PANI/NiHCF hybrid film were characterized by scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), and Fourier transform infrared spectroscopy (FT-IR). The effect of pulse potential on the electrochemical performance of hybrid film was investigated in detail. Results showed that …

Nafion/Thionine/Platinum Nanowires-Modified Electrode For Electrocatalyzing Glucose, Yu-Ping Lin, You-Xiu Lin, Qian Zhou, Dian-Ping Tang

Journal of Electrochemistry

A new amperometric biosensor based on Nafion, thionine and latinum nanowires was developed for sensitive detection of glucose. Initially, positively charged thionine molecules were immobilized onto the surface of Nafion-modified glassy carbon electrode through the interaction between -SO₃^- and -NH₃⁺, and glucose oxidase was then assembled on the modified electrode by using platinum nanowires as the cross-linkage. The preparation process was characterized by using cyclic voltammetry. Two enzymatic biosensors modified with and without platinum nanowires were used for the detection of glucose, and the improved analytical properties were obtained with platinum nanowires. Experimental results indicated …

Platinum Hollow Nanospheres With Different Sizes: Controllable Synthesis And Electrocatalytic Oxidation Toward Methanol, Xuan Lin, Mei-Qin Cheng, Zhong-Jin Shang, Ting Xiong, Xian-Tu Zhang, Wei Tian, Jian-Yun Lin, Qi-Ling Zhong, Bin Ren

Journal of Electrochemistry

The selenium (Se) templates and hollow platinum (Pthollow) nanospheres with different sizes were controllably synthesized by adjusting the concentration of sodium dodecyl sulphonate (SDSN) (CSDSN, μmol·L-1) which was used as a surfactant. Accordingly, the Pthollow nanospheres modified glassy carbon (GC) electrode (Pthollow/GC) was prepared. The morphology and composition of Pthollow nanospheres were characterized by scanning electron microscopy (SEM), transmission electron microscope (TEM), energy dispersive X-ray spectroscopy (EDX), high resolution transmission electron microscopy (HRTEM), selected area electron diffraction (SAED) and X-ray diffraction (XRD) techniques. The electrocatalytic activities of Pthollow/GC and electrodeposited Pt nanoparticles modified glassy carbon electrode (Ptnano/GC) toward methanol oxidation …

Resolve Mono-Electronic Process In The Voltammetric Behaviors Of Multi-Redox Bis-Coenzyme Q0, Hao Zhou, Yi-Tao Long

Journal of Electrochemistry

A widely held concept in electrochemistry is that truly elementary electron-transfer reactions always involve the exchange of one electron, therefore, an overall process involving a change of n electrons must involve n distinct electron-transfer steps. It is highly desirable to resolve multiple-step electron transfer reactions into each electron transfer step. The electrochemical behaviors of coenzyme Q₀ and methylene-bridged Bis-coenzyme Q₀ were investigated by cyclic voltammetry and square wave voltammetry in nonaqueous dichloromethane containing 0.15 mol·L^-1 Bu₄NClO₄ as the supporting electrolyte. The redox reaction of coenzyme Q₀ is well described as two chemically reversible …

Density Functional Theory Study On The Structures Of Solvent-Ion In The Electrolyte Of Lithium Ion Battery, Li-Dan Xing, Ru Yang, Xian-Wen Tang, Wen-Na Huang, Qi-Feng Liu, Qi-Peng Yu, Wei-Shan Li

Journal of Electrochemistry

In this work, the possible structures of solvent-ion complex, resulting from the electrostatic interaction in the propylene carbonate (PC) base electrolyte of lithium ion battery, have been investigated using the density functional theory. The calculated results show that the structure of solvent-ion complex depends on the solvent number. In the PC base electrolyte, maximum number of PC solvents that coexist in the Li⁺-solvent sheath is four. Additionally, the salt anion exists in a complex with the positively charged alkyl group of PC rather than in a free state. The calculated results give a good explanation to the reported …

Production And Applications Of Formaldehyde-Free Phenolic Resins Using 5-Hydroxymethylfurfural Derived From Glucose In-Situ, Yongsheng Zhang

Electronic Thesis and Dissertation Repository

The phenol-formaldehyde (PF) resin manufacturing industry is facing a growing challenge with respect to concerns over human health, due to the use of carcinogenic formaldehyde and sustainability due to the use of petroleum-based phenol in PF resin manufacture. Glucose and its derivative, 5-hydroxymethylfurfural (5-HMF), have proven to be potential substitutes for formaldehyde in the synthesis of phenolic novolac resins.

This thesis investigated a number of glucose and 5-HMF resin systems including the curing of phenol-glucose novolac resin (PG) with a bis-phenol-A type epoxy. The curing process was modeled according to the Sestak-Berggren equation (S, B) using Málek methods. This was …

Engineering Surface Functionality Of Nanoparticles For Biological Applications, Yi-Cheun Yeh

Doctoral Dissertations

Engineering the surface functionality of nanomaterials is the key to investigate the interactions between nanomaterials and biomolecules for potent biological applications such as therapy, imaging and diagnostics. My research has been orientted to engineer both of the surface monolayers and core materials to fabricate surface-functionalized nanomaterials through the synergistic multidisciplinary approach that combine organic chemistry, materials science and biology. This thesis illustrates the design and synthesis of the surface-funcitonalized quantum dots (QDs) and gold nanoparticles (AuNPs) for the fundamental studies and practical applications. For QDs, A new class of cationic QDs with quaternary ammonium derivatives was synthesized to provide permanent …

Electrochemistry Of Glucose Oxidase Modified On Porin-Phospholipid Biomimic Membrane, Kun-Qi Wang, Zuo-Ming Zhang, Wei Xing, Chang-Peng Liu, Xing Zhou

Journal of Electrochemistry

Biomimic membrane with nano-channels, which is made up of porin MspA and 1,2-Dimyristoyl-sn-glycero-3-phosphocholine (DMPC) is constructed on glassy carbon substrate, and glucose oxidase (GOD) is modified on it. The direct electrochemical reaction and electrocatalytic behavior to oxygen and glucose of GOD on the GOD/MspA-DMPC/GC electreode are expounded by the cyclic voltammetric method. The study shows that GOD immobilized on porin MspA and DMPC biomimic membrane displays direct and surface-controlled electrochemical reaction nearby formal potential (E0′) of the flavoprotein active centre (FAD/FADH), and the electrochemical reaction contains two electrons and two protons exchange in 0.1 mmol?L^-1 phosphate buffer solution (PBS) …

Fabrication Of Pattern Of Graphene Oxide And Au Nanoparticles By Microcontanct Printing Technique, Wen-Hui Pang, Xiao-Jian Xiao, Meng-Wei Ye, Kai-Chao Deng, Jing Tang

Journal of Electrochemistry

Graphene oxide (GO) was prepared by modified Hummers method. Using the GO solution as "ink", Au nanoparticles (AuNPs) and GO were transferred to the surface of ITO substrate modified with (3-aminopropyl) triethoxysilane (APTES/ITO) in a sequence. The transferred AuNPs and GO could form a uniform and dense composite pattern which was characterized by FE-SEM and AFM. Moreover, using the APTES/ITO substrate surface potential as zero, the sequences of the surface potential were APTES>GO>Au.

Preparation Of Pt/Dna-Mwcnts/Gc Electrode And Its Electrocatalytic Activity Toward H2O2 Reduction, Li-Li Fan, Li-Na Wu, Zhi-Yu Qu, Dan-Feng Liu, Jun-Ming Zhang, Si-Ming Fan, You-Jun Fan

Journal of Electrochemistry

The DNA-multi-walled carbon nanotubes (MWCNTs)/glassy carbon (GC) electrode was prepared by modifying the DNA functionalized MWCNTs composite on a GC electrode. A novel non-enzymatic H₂O₂ sensing electrode was fabricated by electrodepositing Pt nanoparticles on the DNA-MWCNTs/GC electrode. The modified electrodes were characterized by scanning electron microscope (SEM). The response properties of the sensing electrode to H₂O₂ were investigated by cyclic voltammetry and chronoamperometry. The results indicated that the sensing electrode exhibited a good linear relationship between response current and H₂O₂ concentration in the range of 0.04 ~ 18.07 mmol·L^-1 with …

Electro-Catalytic Properties Of Β-Pbo2/Sb-Sno2/Ti Electrode On Phenol Oxidation, Peng Li, Yue-Min Zhao, Li-Zhang Wang, Yan-Le Zhang, Zhao-Qing Lu

Journal of Electrochemistry

The combination technology of brush pyrolysis and electroplating was employed in the preparation of β-PbO₂/Sb-SnO₂/Ti electrode. X-ray Diffraction (XRD) and Scanning Electron Microscope (SEM) results showed that the Sb-SnO₂ as an interlayer would restrain the formation of lead fluoride and the crystallization degree on the electrode surface could be as high as 100%. The grain size was calculated by Scherrer formula to be 25.2 nm and the agglomeration of lead dioxide was effectively eliminated. The potential span of diffusion control phase, oxygen evolution potential, Tafel slope for the β-PbO₂/Sb-SnO₂/Ti electrode during …

Fabrication And Characterization Of The Ni-Scsz Composite Anodes With A Cu-Lscm-Ceo2 Catalyst Layer In The Thin Film Sofc, Yao Lv, Bo Huang, Xi-Zhi Gu, Chun-Yi Hou, Yi-Xing Hu, Xiao-Yin Wang, Xin-Jian Zhu

Journal of Electrochemistry

Solid oxide fuel cell (SOFC) directly operating on hydrocarbon without external reforming has the potential of greatly speeding up the application of SOFCs for transportation. In this paper, a three-layer structure anode was fabricated by tape casting and screen printing method. The addition of Cu-LSCM-CeO₂ to the supported anode surface presented better performance running on H₂ and ethanol. The maximum power densities were 511 and 390 mW?cm^-2, respectively, running on H₂ and ethanol at 750 °C. No significant degradation was observed on the anode. Consequently, the Cu-LSCM-CeO₂ catalyst layer on the surface of the …

Review Of Carbon Materials Energy Storage Mechanism In Lead-Carbon Battery, Le-Ying Wang, Hao Zhang, Chen Hu, Shu-Kai Zhang, Hai-Lei Zhao, Gao-Ping Cao, Wen-Feng Zhang, Yu-Sheng Yang, Xiao-Kang Lai

Journal of Electrochemistry

The traditional lead-acid batteries are mainly used for automobile and various internal combustion engine starting, wireless communication base stations and renewable energy storage; however, their negative plates are easily sulfated under partial-state-of-charge duty, then their charging capacity and cycle life are greatly reduced. Lead-carbon battery is a new type of lead-acid battery, in which a carbon material with high specific surface area and conductivity is added into a negative plate, and has excellent rate discharge performance and higher PSoC cycle life. Lead-carbon battery has a good application prospect in energy storage and hybrid electric vehicle, so these years the study …

On The Origin Of The Errors Of IK As Estimated From K-L Equation In Rotating Disk Electrode System, Wei Chen, Ling-Wen Liao, Zheng-Da He, Yan-Xia Chen

Journal of Electrochemistry

Rotating disk electrode system is mainly used to study the kinetics of reactions whose reactants have very low solubility in the electrolyte. For an irreversible reaction, Koutecky-Levich equation (K-L Eq.) is frequently used to deduce the kinetic current i_k). Since K-L Eq. is derived based on the assumption that a system should conform the steady-state diffusion conditions, the data recoded from the actual system which deviates from such a condition, great error may be induced for the i_k estimated. In this work, polarization curves for oxygen reduction reaction at polycrystalline Pt electrode recorded in solutions with various …

Electrochemical Deposition Of Copt Alloy Thin Film And Its Abnormal Infrared Effects, Qing-Song Chen, Guo-Cong Guo, Shi-Gang Sun

Journal of Electrochemistry

Nanostructured CoPt alloy thin film was deposited on glassy carbon substrate (denoted as CoPt/GC) under cyclic voltammetric conditions. SEM studies demonstrated that the CoPt/GC was composed of nonuniform nanoparticles with an average size of 139 nm. The composition of the CoPt/GC was analyzed by energy dispersive X-ray spectroscopy (EDS), which depicts a Co:Pt ratio of ca. 3:5. In situ FTIR spectroscopy employing CO adsorption as a probe reaction revealed that the CoPt/GC exhibits abnormal infrared effects (AIREs). The unique anomalous IR features of CO adsorbed (CO_ad) on CoPt/GC consist in the complete inversion of the CO_ad IR …

Influence Of Pt:Ru Ratio In Nanotubes Array Structures On The Electrocatalytic Activity Of Methanol Oxidation, Jin-Hua Yuan, Feng-Bin Wang, Xing-Hua Xia

Journal of Electrochemistry

Bimetallic PtRu nanotubes array electrodes (NTAEs) with varied Pt to Ru atomic ratios have been prepared by electrochemical codeposition in 3-aminopropyltri-methoxysilane modified porous anodic alumina (PAA) membranes. The structure and morphology of the catalysts were characterized using X-ray diffraction (XRD) and scanning electron microscopy (SEM), respectively. Electrochemical results showed that the NTAEs with varied atomic ratios could be achieved by controlling the precursor concentration for deposition. The prepared nanoarrays composed of Pt or PtRu alloy promoted the mass-normalized activity toward the sluggish electrooxidation reaction of methanol due to the increased catalytic activity and real surface area, as well as the …

Determination Of Folic Acid By Composite Film Electrode Modified With Poly-Alizarin Red And Multi-Walled Carbon Nanotubes, Xue-Ping Du, Tong-Fang Lou, Ying Dong, Jian-Ying Qu

Journal of Electrochemistry

The novel modified electrode was fabricated by electropolymerizing alizarin red onto the surface of multi-walled carbon nanotubes on glassy carbon electrode surface, which exhibited good electrocatalytic activity for folic acid. The experimental results showed that the reduction peak current of folic acid at -0.63 V was linear to its concentration over the range of 1.25×10^-6 ~ 4.00×10^-5 mol·L^-1 in the optimized experimental conditions (R = 0.9985). Test for recovery was carried out by standard addition method, and the recovery ratios were in the range of 92.0% ~ 102.0%. The modified electrode was prepared simply with excellent …

Preparation And Electrochemical Behavior Of Pbo/Gn/Ac, Yun-Fang Gao, Yan-Ping Wang, Qiu-Shi Yao, Fu-Hua Wang, Dong-Lei Ren, Xin Xu

Journal of Electrochemistry

The lead oxide/graphene/activated carbon (PbO/GN/AC) composite materials were prepared by impregnating commercial activated carbon and graphene in saturated lead nitrate solution followed by calcination. The structures and morphologies of the composite were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). The results show that PbO crystals (about 200 nm) were dispersed uniformly on the surface of activated carbon and graphene. Electrochemical data indicate that the composite exhibited good electrochemical performances. The PbO/GN/AC composite possessed the higher over-potential of hydrogen evolution and the high specific capacitance of 312.6 F·g^-1, while the internal resistance …

Electrochemical And Spectroscopic Studies Of Ethanol Oxidation On Nano-Cubic Pt Modified By Tin Adatoms, Lu Rao, Bin-Wei Zhang, Yan-Yan Li, Yan-Xia Jiang, Shi-Gang Sun

Journal of Electrochemistry

The nano-cubic Pt modified by tin (Sn) was synthesized and used to investigate the role of this adatom played in the ethanol oxidation. The onset potential of ethanol oxidation was significantly shifted negatively which can be forward about 300 mV when the coverage of Sn (θSn)was 0.9. The electrtochemical in situ FTIR result demonstrated that the amount of CO2 increased first, and then decreased with θSn increased, and reached the maximun when θSn was 0.38. Furthermore, the formation of acetic acid could be observed at very low potential (-0.05 V) after modifying Sn adatom, and the amount of acetic acid …

Boosting Electrocatalytic Activity Of Nitrogen-Doped Graphene/Carbon Nanotube Composite For Oxygen Reduction Reaction, Yu Zhang, Jin-Song Hu, Wen-Jie Jiang, Lin Guo, Zi-Dong Wei, Li-Jun Wan

Journal of Electrochemistry

Developing low-cost catalysts with high electrocatalytic activity for oxygen reduction reaction (ORR) has recently attracted much attention because the sluggish ORR currently limits the performance and commercialization of fuel cells and metal-air batteries as well. Nitrogen doped carbon materials have been considered as a promising candidate for the replacement of high-cost and scarce Pt-based catalysts although their electrocatalytic activity still needs to be much improved. In this work, an improved nitrogen-doped graphene/carbon nanotubes composite (N-rGO/CNT) was developed as an efficient ORR electrocatalyst. It was found that the ORR activity of N-rGO/CNT composite could be significantly enhanced by introducing iron in …

Recent Progress In Heteroatoms Doped Carbon Materials As A Catalyst For Oxygen Reduction Reaction, Wei Ding, Xue Zhang, Li Li, Zi-Dong Wei

Journal of Electrochemistry

Developing catalytic materials for oxygen reduction reactions (ORR) with high performance and low cost has been one of the major challenges for large-scale applications of fuel cells. In this review, we summarize the recent progress in the heteroatoms doped carbon materials as a catalyst for the catalysis of ORR, with an emphasis on the universal origin of their catalytic mechanisms. The future prospects of the metal-free catalyst were to find precisely controlled doping methods, to explore the role of heteroatoms in the catalysis, and to generate more active catalysts with suitable nanostructure.

Effect Of Imidazole Ionic Liquids On The Electro-Oxidation Of P-Methoxy Toluene, Qiong Chen, Ying-Hong Zhu, Ying Zhu, Yan-Fang Li, Chun-An Ma

Journal of Electrochemistry

The interactions between four Imidazole ionic liquids (EMIMBF₄, BMIMBF₄, BMIMHSO₄, BMIMAc) and p-methoxy toluene were investigated by ultraviolet spectroscopy. The red shifts of absorption peak were obviously observed, and the fine structures of the spectroscopy were disappeared on the long wave district. p-MT producing stable excited state was benefit from the interaction with solvent molecules. The electro-oxidation behavious of p-MT were studied in the four ILs on platinum electrode by cyclic voltammetry (CV) and chronoamperometry (CP), and the diffusion coefficients (D) and activation energies (ED) were calculated. The results indicated that the electro-oxidation process …

Molecular Engineering Strategies For The Design And Synthesis Of New Organic Photovoltaic Materials, Paul J. Homnick

Doctoral Dissertations

Dramatic improvements in organic photovoltaic device efficiency can be obtained by optimizing spectral absorbance and frontier molecular orbital (FMO) energies, increasing solid state exciton/charge mobility, and utilizing p-/n-type nanoarchitecture. Combining all of these properties into a new material presents a considerable synthetic challenge because potential commercial applications require materials that are high-performance and inexpensive. Thus, it is advantageous to design new materials using a versatile, modular synthetic approach that allows each design criterion to be engineered individually, in a synthetically efficient manner. Several strategies were successfully pursued using simple interchangeable electron donor and acceptor components as functional modules, which …

Preparation Of Pt-Tio2/Graphene Composites With High Catalytic Activity Towards Methanol Oxidation And Oxygen Reduction Reaction, Li Qi, Ying Yin, Wen-Guang Tu, Bing-Bing Wu, Zhao-Sheng Wang, Jian-Guo Liu, Jun Gu, Zhi-Gang Zou

Journal of Electrochemistry

A series of graphene-supported TiO₂ nanoparticles (TiO₂/G) with different TiO₂ contents were prepared by a facile hydrothermal method, and then the Pt-TiO₂/G catalysts were successfully prepared by reducing Pt-precursor with microwave technique. Compared with Pt-G catalysts, the catalytic performance toward oxygen reduction reaction (ORR) and methanol oxidation reaction (MOR) of Pt-TiO₂/G catalysts was improved due to the addition of TiO₂. However, the excessive TiO₂ would lead to a poor catalytic performance of Pt-TiO₂/G catalysts because of the low electrical conductivity of TiO₂.

High Sensitive Detection Of Cd(Ii) And Pb(Ii) Based On Antimony-Film Covered Pencil Core Electrodes, Shan Chen, Zhao-Yan Zheng, Yi-Min Fang, Li-Qing Zheng, Jian-Jun Sun

Journal of Electrochemistry

In this paper, a pencil core was used as the substrate for an antimony-film electrode for simultaneous detection of Cd(II) and Pb(II) by square-wave anodic stripping voltammetry (SWASV). With the deposition time of 180 s, the low limit of detection (LOD) for the electrode was determined to be 0.075 ?g?L-1 for Cd(II), while 0.13 ?g?L-1 for Pb(II) with good reproducibility in low pH solutions (pH = 2). The results show a much lower LOD than that of bismuth-film pencil core electrode. Finally, this antimony-film electrode was successfully applied to determine Cd(II) and Pb(II) in tap water.

A Sensitive And Label-Free Electrochemical Aptasensor Based On Signal Amplification Of Carbon Nanotubes, Chun-Yan Deng, Hui-Min Fan, Juan Xiang, Yuan-Jian Li

Journal of Electrochemistry

A label-free electrochemical sensing electrode for highly sensitive detection of adenosine was constructed based on the signal amplification of carbon nanotubes (CNTs). The change in the interfacial feature of the modified electrode was characterized by electrochemical impedance spectroscopy. Using [Ru(NH₃)₆]³⁺ as the signaling moiety, adenosine with concentrations as low as 0.027 nmol·L^-1 can be selectively detected. Additionally, the fabrication of this present aptasensor was simple, time-saving and cost-effective. Compared with other reported aptasensors, the proposed aptasensor had advantages of excellent sensitivity, selectivity and simplicity, which plays a potential role in development of aptasensor.