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Full-Text Articles in Engineering Science and Materials

Applications Of Advanced Imaging Technologies For Critical Issues Of All-Solid-State Lithium Battery Studies, Yi-Bo Zhao, Hui-Hui Liu, Song-Liang Chen, Shou-Hang Bo Feb 2019

Applications Of Advanced Imaging Technologies For Critical Issues Of All-Solid-State Lithium Battery Studies, Yi-Bo Zhao, Hui-Hui Liu, Song-Liang Chen, Shou-Hang Bo

Journal of Electrochemistry

All-solid-state lithium batteries have attracted much attention for their high energy density and good safety. To increase their efficiency and prolong their service life, it is necessary to achieve high ion conductivity at the electrode/electrolyte interface and in the electrolyte, as well as to eliminate dendrites growth in the battery. Based on the critical requirements outlined above, this paper discusses the applications of advanced imaging technologies in relevant studies. Recent progresses in investigations of all-solid-state lithium batteries by imaging techniques including electron microscopy, scanning probe microscopy, X-ray tomography, magnetic resonance imaging and optical microscopy are summarized.


Computational Studies On Perovskite-Metallofullerene Interface And Magnetic Properties Of Mn-Based Mixed Olivines, Bethuel Omutiti Khamala Jan 2019

Computational Studies On Perovskite-Metallofullerene Interface And Magnetic Properties Of Mn-Based Mixed Olivines, Bethuel Omutiti Khamala

Open Access Theses & Dissertations

Methyl ammonium lead halide (MAPbX3) perovskite based solar cells have recently emerged as promising class of materials for photovoltaic applications with efficiencies reaching over 22%. Designing interfaces with strong binding is vital to developing efficient, high-performing solar cells. Fullerene-based materials are widely employed as efficient electron acceptors and can serve as electron transporting layer in perovskite based solar cells. We have studied interfaces of methyl ammonium lead iodide MAPbI3 with Sc3N@C80 fullerene and Sc3N@C80PCBM fullerene derivate within the density functional formalism. Different surface terminations and orientations of the methyl ammonium are examined for binding of the fullerene layer. Our calculated …


Resistance To Helium Bubble Formation In Amorphous Sioc/Crystalline Fe Nanocomposite, Qing Su, Tianyao Wang, Jonathan Gigax, Lin Shao, Michael Nastasi Jan 2019

Resistance To Helium Bubble Formation In Amorphous Sioc/Crystalline Fe Nanocomposite, Qing Su, Tianyao Wang, Jonathan Gigax, Lin Shao, Michael Nastasi

Department of Mechanical and Materials Engineering: Faculty Publications

The management of radiation defects and insoluble He atoms represent key challenges for structural materials in existing fission reactors and advanced reactor systems. To examine how crystalline/amorphous interface, together with the amorphous constituents affects radiation tolerance and He management, we studied helium bubble formation in helium ion implanted amorphous silicon oxycarbide (SiOC) and crystalline Fe composites by transmission electron microscopy (TEM). The SiOC/Fe composites were grown via magnetron sputtering with controlled length scale on a surface oxidized Si (100) substrate. These composites were subjected to 50 keV He+ implantation with ion doses chosen to produce a 5 at% peak He …