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Evidence Of The Existence Of Cathodic And Anodic Zones During The Leaching Of Minerals And Metals, Fathi Habashi Jan 2014

Evidence Of The Existence Of Cathodic And Anodic Zones During The Leaching Of Minerals And Metals, Fathi Habashi

Fathi Habashi

It is accepted worldwide that the dissolution of minerals in some cases, is an electrochemical process where anodic and cathodic reactions take place. There are many parameters, such as agent concentration, that directly affect the dissolution process. The rate of leaching of minerals may differ depending on the oxygen concentration. In this paper, the existence of anodic and cathodic zones on themineral surface during the dissolution/leaching of minerals andmetals has been presentedwith some differentworks. It isworthmentioning that a good number of published papers have experimentally demonstrated the existence of anodic and cathodic areas on the mineral surface.


Leaching Mechanism Of Semiconducting Minerals, Fathi Habashi Dec 2010

Leaching Mechanism Of Semiconducting Minerals, Fathi Habashi

Fathi Habashi

The mechanism of leaching of semiconducting minerals such as PbS, ZnS, UO2, etc., has been the subject of intensive speculation by hydrometallurgists in the early 1950s. The electrochemical mechanism proposed in 1970 by the author in volume 2 of his Principles of Extractive Metallurgy avoids the assumption of forming intermediate complexes that cannot be isolated or identified.


Researches On Copper. History & Metallurgy, Fathi Habashi Feb 2009

Researches On Copper. History & Metallurgy, Fathi Habashi

Fathi Habashi

The present volume is a collection of selected papers dealing with the extractive metallurgy of copper published by the author and his coworkers. They are reproduced here in a facsimile edition in 240 pages. In addition ten new chapters were specially written in 150 pages. The book is fully illustrated by many colored pictures, flowsheets, and diagrams. It is hoped that it will be useful for students, engineers, chemists, geologists, and for research workers.


A Generalized Kinetic Model For Hydrometallurgical Processes, Fathi Habashi Jan 2007

A Generalized Kinetic Model For Hydrometallurgical Processes, Fathi Habashi

Fathi Habashi

In electrochemical leaching processes the solid must be an electric conductor, e.g., a metal, or a semiconductor, e.g., certain metal sulfides or oxides. Reaction takes place by the transfer of electrons at the solid surface and involves oxidation–reduction processes that take place simultaneously at two different locations not far from each other. At one location, electrons are picked up by a depolarizer, D, in solution, e.g., O2, H+, etc. (the cathodic zone) and at another location metal ions are released in solution (the anodic zone) where they react with reagent C. A single kinetic law derived theoretically is obeyed: Rate …