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Structure And Kinetics Of Internal Oxidation In Ag-Sn Alloys, Zeljko J. Kamberovic

Zeljko J Kamberovic

Internal oxidation in Ag-Sn-In-Te and Ag-Sn-Cu-Bi alloys was tested. Microstructures of casted and homogenized samples, as well as after internal oxidation were followed by optical microscopy. The structure of Ag-Sn-Cu-Bi alloy was found finer, and the oxidation rate is considerably higher compared to the Ag-Sn-In-Te type alloy sheets. It seems that the size and volume fraction of secondary phase particles (probably ζ type) can influence the process of internal oxidation. In the Ag-Sn-In-Te alloy type “wavy oxidation” was noticed with oxide free regions.