Engineering Science and Materials Commons^™

Adhesion And Deformation Mechanisms Of Polydopamine And Polytetrafluoroethylene: A Multiscale Computational Study, Matthew Brownell

Graduate Theses and Dissertations

Polydopamine (PDA) has been shown to bond via covalent bonding, van der Waals forces, and hydrogen bonding and is known to adhere strongly to almost any material. The application of PDA between a substrate and a PTFE surface coating has resulted in low friction and a greatly reduced wear rate. Previous research probing the capabilities and limitations of PDA/PTFE films have studied the wear and mechanical properties of the film, but the overall adhesive and deformation mechanisms remain unclear.

In this research, we investigate the tribological properties of PDA and PTFE molecules and composites from the atomic to the microscale …

Friction And Wear Behaviors Of Mos2-Multi-Walled-Carbon-Nanotube Hybrid Reinforced Polyurethane Composite Coating, Zhaozhu Zhang, Mingming Yang, Junya Yuan, Fang Guo, Xuehu Men

Friction

MoS2-multi-walled-carbon-nanotube (MWCNT) hybrids containing two-dimensional MoS2 and one-dimensional MWCNTs were synthesized through a one-step hydrothermal reaction. X-ray-diffraction and transmission-electron-microscopy results demonstrated that MoS2 nanosheets were successfully synthesized, and uniformly anchored on the MWCNTs' surfaces. Furthermore, the effects of the MoS2-MWCNT hybrids on the tribological performances of polyurethane composite coatings were investigated using a UMT-2MT tribo-tester. Friction and wear test results revealed that the friction coefficient and wear rate of a 3 wt% MoS2-MWCNT-1 filled polyurethane composite coating were reduced by 25.6% and 65.5%, respectively. The outstanding tribological performance of the MoS2-MWCNT-1 reinforced polyurethane composite coating was attributed to the excellent …