Engineering Science and Materials Commons^™

Feasibility Of The Use Of Ultrasound Measurements For Grade Verification Of The Performance Grade Asphalt Binders, Mehdi Khalili

UNLV Theses, Dissertations, Professional Papers, and Capstones

This research investigates the feasibility of application of high frequency immersion ultrasonic measurement (UM) to discriminate different performance grade (PG) asphalt binders. PG asphalt binder is one of the main components of hot mix asphalt used for roadway construction. UT may provide an inexpensive alternative to sophisticated tests currently used for quality control of PG asphalt binders. Nine different PG asphalt binders used were selected for this investigation. Velocity (V) and integrated response (IR) of the ultrasonic wave were measured. The IR is a measure of the ratio of ultrasonic energy transmitted into the material to the ultrasonic energy reflected …

An Automated Finite Element Analysis Framework For The Probabilistic Evaluation Of Composite Lamina Properties, Jonathan Phillips Weigand

Masters Theses

This thesis outlines the development of computational modeling tools used to predict the elastic properties of composite lamina from representative volume elements (RVE) using numerical methods. The homogenization approach involves the use of Gauss’s Theorem to simply the average volumetric strain integral into a surface integral containing which is defined by surface displacements and their direction. Simulations of RVEs under specific loading conditions (longitudinal tension or shear and transverse tension or shear) are then performed in the software package ABAQUS to obtain the surface displacements. It was found that obtaining quality meshes and applying periodic boundary conditions for each RVE …

Mode I Fracture Toughness Of Eight-Harness-Satin Carbon Cloth Weaves For Co-Cured And Post-Bonded Laminates, Josh E. Smith

Master's Theses

Mode I interlaminar fracture of 3k 8-Harness-Satin Carbon cloth, with identical fill and weft yarns, pre-impregnated with Newport 307 resin was investigated through the DCB test (ASTM D5528). Crack propagations along both the fill and weft yarns were considered for both post-bonded (co-bonded) and co-cured laminates. A patent-pending delamination insertion method was compared to the standard Teflon film option to assess its applicability to mode I fracture testing. The Modified Beam Theory, Compliance Calibration method, and Modified Compliance Calibration method were used for comparative purposes for these investigations and to evaluate the validity of the proposed Equivalent Stiffness (EQS) method. …

Numerical Modeling Of Solidification Process And Prediction Of Mechanical Properties In Magnesium Alloys, Mehdi Farrokhnejad

Electronic Thesis and Dissertation Repository

A formulation used to simulate the solidification process of magnesium alloys is developed based upon the volume averaged finite volume method on unstructured collocated grids. To derive equations, a non-zero volume fraction gradient has been considered and resulting additional terms are well reasoned. For discretization the most modern approximations for gradient and hessians are used and novelties outlined. Structure-properties correlations are incorporated into the in-house code and the proposed formulation is tested for a wedge-shaped magnesium alloy casting. While the results of this study show a good agreement with the experimental data, it was concluded that a better understanding of …

Structure And Morphology Of Sulfonated Polysulfone And Perfluorosulfonic Acid Ionomers, Chen Wang

Doctoral Dissertations

The limitations of conventional perfluorosulfonic acid (PFSA) based membrane materials have provoked the search for alternative materials which can function as the electrolyte in PEM fuel cells operated at higher temperatures (> 100 °C) and without humidification. A novel class of sulfonated poly(phenylene) sulfone (sPSO2) ionomers have shown much higher proton conductivity than typical PFSA membranes at elevated temperatures. In this dissertation, both computational and experimental methods were used to investigate proton transfer, morphological and structural properties of sPSO2 and PFSA ionomers. We have undertaken ab initio electronic structure calculations to understand the primary hydration and the transfer of protons …

3d Modeling And Design Optimization Of Rod Shaped Ionic Polymer Metal Composite Actuator, Siul A. Ruiz

UNLV Theses, Dissertations, Professional Papers, and Capstones

Ionic polymer-metal composites (IPMCs) are some of the most well-known electro-active polymers. This is due to their large deformation provided a relatively low voltage source. IPMCs have been acknowledged as a potential candidate for biomedical applications such as cardiac catheters and surgical probes; however, there is still no existing mass manufacturing of IPMCs. This study intends to provide a theoretical framework which could be used to design practical purpose IPMCs depending on the end users interest.

This study begins by investigating methodologies used to develop quantify the physical actuation of an IPMC in 3-dimensional space. This approach is taken in …

Influence Of Microstructure On The Propagation Of Fatigue Cracks In Inconel 617, Benjiman Michael Albiston

Boise State University Theses and Dissertations

Inconel 617 is a candidate material for use in the intermediate heat exchanger of the Next Generation Nuclear Plant. Because of the high temperatures and the fluctuations in stress and temperature, the fatigue behavior of the material is important to understand. The goal of this study was to determine the influences of the microstructure during fatigue crack propagation. For this investigation, Inconel 617 compact tension samples, fatigue tested by Julian Benz at the Idaho National Laboratory, were obtained. The testing conditions included two environments at 650 °C (lab air and impure-He) and varied testing parameters including: loading waveform (triangular, trapezoidal), …

Low Velocity Impact Tower Feasibility, Setup, And Impact Testing Of Carbon Fiber Reinforced Epoxy Thermoset And Peek Thermoplastic Matrix Composites, Brent Plehn

Materials Engineering

A low velocity impact tower was donated to Cal Poly's Materials Engineering Department along with four fiber reinforced polymer matrix composites. The tower was set up in building 192 in the Mechanical Testing Laboratory. Improvements were made to the tower including adding velocity detection capabilities, making loose hardware inclusive, adding an extra tower arm for better consistency, adding a double jawed clamp for faster testing, and rerouting the tower's compressed air system to improve performance. A standard operating procedure was drafted, tested, and redrafted for impact testing composite panels. The four composite panels consisted of two quasi-isotropic 16 ply AS-1 …

Fatigue Testing And Data Analysis Of Welded Steel Cruciform Joints, Alina Shrestha

University of New Orleans Theses and Dissertations

In this study, ABS Publication 115, “Guidance on Fatigue Assessment of Offshore Structures” is briefly reviewed. Emphasis is on the S-N curves based fatigue assessment approach of non-tubular joints, and both size and environment effects are also considered. Further, fatigue tests are performed to study the fatigue strength of load-carrying and non-load-carrying steel cruciform joints that represent typical joint types in marine structures. The experimental results are then compared against ABS fatigue assessment methods, based on nominal stress approach, which demonstrates a need for better fatigue evaluation parameter. A good fatigue parameter by definition should be consistent and should correlate …

Stress Analysis Of Ramberg-Osgood And Hollomon 1-D Axial Rods, Ronald J. Giardina Jr

University of New Orleans Theses and Dissertations

In this paper we present novel analytic and finite element solutions to 1-D straight rods made of Ramberg-Osgood and Hollomon type materials. These material models are studied because they are a more accurate representation of the material properties of certain metals used often in manufacturing than the simpler composite linear types of stress/strain models. Here, various types of loads are considered and solutions are compared against some linear models. It is shown that the nonlinear models do have manageable solutions, which produce important differences in the results - attributes which suggest that these models should take a more prominent place …

Creep, Fatigue And Creep-Fatigue Interactions In Modified 9% Cr - 1% Mo (P91) Steels, Valliappa Kalyanasundaram

Graduate Theses and Dissertations

Grade P91 steel, from the class of advanced high-chrome ferritic steels, is one of the preferred materials for many elevated temperature structural components. Creep-fatigue (C-F) interactions, along with oxidation, can accelerate the kinetics of damage accumulation and consequently reduce such components' life. Hence, reliable C-F test data is required for meticulous consideration of C-F interactions and oxidation, which in turn is vital for sound design practices. It is also imperative to develop analytical constitutive models that can simulate and predict material response under various long-term in-service conditions using experimental data from short-term laboratory experiments. Consequently, the major objectives of the …

Experimental Study On The Fabrication Of Advanced Materials For Energy Applications Using High Energy Mechanical Milling, Ashvin Kumar Narayana Swamy

Open Access Theses & Dissertations

The reaction of aluminum (Al) powder with water has the potential for on demand hydrogen generation. Conventional Al powders, however, react with water slowly due to a highly protective oxide layer on the particle surface. Current methods for Al activation involve harmful and expensive materials. The nano-scale Al powders also remain very expensive and have problems such as a large amount of oxide on the surface. The use of aluminum in an energy generation cycle is also hindered by the fact that, although Al is the most abundant metal in the Earth's crust, its recovery from ore consumes a lot …

Thermal Barrier Coatings (Tbc's) For High Heat Flux Thrust Chambers, Christopher Michael Bradley

Open Access Theses & Dissertations

The last 30 years materials engineers have been under continual pressure to develop materials with a greater temperature potential or to produce configurations that can be effectively cooled or otherwise protected at elevated temperature conditions. Turbines and thrust chambers produce some of the harshest service conditions for materials which lead to the challenges engineers face in order to increase the efficiencies of current technologies due to the energy crisis that the world is facing. The key tasks for the future of gas turbines are to increase overall efficiencies to meet energy demands of a growing world population and reduce the …

Microstructure And Properties For Titanium Aluminide Superalloy Prototypes Fabricated By Electron Beam Melting And Thermally Processed, Jennifer Hernandez

Open Access Theses & Dissertations

Gamma TiAl has been considered to be an ideal replacement for Ni-base superalloy aerospace applications, particularly in weight-critical applications. While bulk, fully dense gamma-TiAl is 50% less dense than Ni-base superalloys, it also has excellent mechanical properties at high temperature (up to ~800°C). Pre alloyed (Ti-48Al-2Cr-2Nb) powder was used to fabricate solid, fully dense (3.85 g/cm3) components and foam components with densities ranging from 0.33 g/cm³ to 0.46 g/cm³ by electron beam melting (EBM). A 10:1 blend of 2-phase TiAl (Ti-48Al-2Cr-2Nb in ^a/_o) : Inconel 625 (Ni-22Cr-6Mo-2Nb in ^a/_o) pre-alloyed powders produced …

Structure And Electronic Properties Of Pure And Nitrogen Doped Nanocrystalline Tungsten Oxide Thin Films, Vemnkata Rama Sesha Ravi Kumar Vemuri

Open Access Theses & Dissertations

Tungsten oxide (WO₃) is a multifunctional material which has applications in electronics, sensors, optoelectronics, and energy-related technologies. Recently, electronic structure modification of WO₃ to design novel photocatalysts has garnered significant attention. However, a fundamental understanding of nitrogen induced changes in the structure, morphology, surface/interface chemistry, and electronic properties of WO₃ is a prerequisite to producing materials with the desired functionality and performance. Also, understanding the effect of thermodynamic and processing variables is highly desirable in order to derive the structure-property relationships in the W-O/W-O-N material system. The present work was, therefore, focused on studying the effects …

Microstructure And Mechanical Properties Of Titanium Nitride Optical Coatings Made By Dc Magnetron Sputtering, Gustavo Martinez

Open Access Theses & Dissertations

Titanium nitride (TiNx) thin films were grown by DC (Direct Current) magnetron sputtering method onto Si(100) substrates by varying time of deposition to produce films with variable thickness (dTiN) in the range of 20-120 nm. The grown TiNx films were characterized by studying their structure, composition, and mechanical properties. Nuclear reaction analysis (NRA) combined with Rutherford backscattering spectrometry (RBS) analyses indicate that the grown films were stoichiometric TiN. Grazing incidence X-ray diffraction (GIXRD) measurements indicate that the texturing of the TiN films changes as a function of dTiN. The (111) and (002) peaks appear initially; with increasing dTiN, (111) becomes …

Rbd2po4: Room Temprature Synthesis, Chemical And Structural Stablity Upon Heating, Masoud Mollaee

Open Access Theses & Dissertations

Monoclinic RbD2PO4 polycrystals were synthesized via the room temperature crystallization of RbH2PO4 dissolved in D2O. Powder x-ray diffraction (XRD) data collected at T=25 ºC indicate that this deuterated compound crystallizes in space group P21/m with unit cell parameters a=7.688í?, b=6.192í?, c=4.781í? and β=109.02°, and is isomorphic with the intermediate-temperature phase of its hydrogenated counterpart rubidium dihydrogen phosphate (RDP). We found no evidence of previously reported [Phase Transitions 80, 17 (2007)] polymorphic phase transition in rubidium dideuterium phosphate (DRDP) upon heating from room temperature to 210 ºC. All lattice parameters vary smoothly within this temperature range, demonstrating that the P21/m phase …

Structural, Optical And Electrical Properties Of Yttrium-Doped Hafnium Oxide Nanocrystalline Thin Films, Abhilash Kongu

Open Access Theses & Dissertations

Hafnium oxide (HfO2) has emerged as the most promising high-k dielectric for Metal-Oxide-Semiconductor (MOS) devices and has been highlighted as the most suitable dielectric materials to replace silicon oxide because of its comprehensive performance. In the present research, yttrium-doped HfO2 (YDH) thin films were fabricated using RF magnetron sputter deposition onto Si (100) and quartz with a variable thickness. Cross-sectional scanning electron microscopy coupled with Filmetrics revealed that film thickness values range from 700 A° to 7500 A°. Electrical properties such as AC Resistivity and current-voltage (I-V) characteristics of YDH films were studied. YDH films that were relatively thin (<1500 A°) crystallized in monoclinic phase while thicker films crystallized in cubic phase. The band gap (Eg) of the films was calculated from the optical measurements. The band gap was found to be ∼5.60 eV for monoclinic while it is ∼6.05 eV for cubic phase of YDH films. Frequency dependence of the electrical resistivity (ρac) and the total conductivity of the films were measured. Resistivity decreased (by three orders of magnitude) with increasing frequency from 100 Hz to 1 MHz, attributed due to the hopping mechanism in YDH films. Whereas, while ρac∼1Ω-m at low frequencies (100 Hz), it decreased to ∼ 104 Ω-cm at higher frequencies (1 MHz). Aluminum (Al) metal electrodes were deposited to fabricate a thin film capacitor with YDH layer as dielectric film thereby employing Al-YDH-Si capacitor structure. The results indicate that the capacitance of the films decrease with increasing film thickness. A detailed analysis of the electrical characteristics of YDH films is presented.

Process Study And Control Of Electron Beam Melting Technology Using Infrared Thermography, Jorge Mireles

Open Access Theses & Dissertations

An IR camera was installed in an Arcam A2 system (Arcam AB, Mölndal, Sweeden) and layer-by-layer image acquisition was achieved. The camera's capability to detect manufacturing defects was evaluated by implementing computer vision techniques using LabVIEW measurement and programming software (National Instruments, Austin, TX). Thermal maps acquired by the IR camera allowed layer-by-layer part temperature to be recorded. A core objective of this research was to study the impact of processing temperature on EBM-fabricated Ti-6Al-4V parts and achieve controlled mechanical properties. In this research, build variations were achieved by modifying parameters that change processing temperature from the standard processing temperature. …

Crystal Structure, Phase, And Optical Properties Of Yttrium-Doped Hafnium Oxide Nanocrystalline Thin Films, Alejandro Ortega

Open Access Theses & Dissertations

Yttrium-doped hafnium oxide (YDH) nanocrystalline films were produced by sputter-deposition at various substrate times and temperatures, to produce YDH films in a wide range of thicknesses, dYDH∼25 to 1100 nm. The deposition was made onto optical grade quartz and sapphire substrates. Samples deposited on sapphire were subject to post-deposition annealing (PDA) at various times (3-24 hr) and temperatures (1100 - 1500 °C). The effect of d[special characters omitted]YDH on the crystal structure, surface/interface morphology and optical properties of YDH films was investigated. X-ray diffraction analyses revealed the formation of monoclinic phase for relatively thin films (<150nm). The evolution towards stabilized cubic phase with increasing dYDH [special characters omitted]is observed. The scanning electron microscopy results indicate the dense, columnar structure of YDH films as a function of dYDH. Spectrophotometry analyses indicate that the grown YDH films are transparent and exhibit interference fringes. The band gap was found to be ∼ 5.60 eV for monoclinic YDH films while distinct separation and an increase in band gap to 6.03 eV is evident with increasing dYDH and formation cubic YDH films. The PDA films band gaps were found to be between 5.31 and 5.72 eV, all of which exhibit secondary gaps. A correlation between growth conditions, annealing, phase evolution, and optical properties of the YDH nanocrystalline thin films is established.

Comparative Characterization Of Ni-Base Superalloys Fabricated By Laser And Electron Beam Melting Technologies, Krista Amato

Open Access Theses & Dissertations

Nickel-base superalloys have been used in cast and wrought, and powder metallurgy forms for nearly four decades for industrial and automotive applications. One drawback of cast alloys is that upon solidification, there is minimal microstructural control. Another issue to be improved is to eliminate the limitations of shapes and forms of fabricated alloys.

Rapid prototyping is a new technology of additive manufacturing that shows to be promising for the freeform fabrication of novel superalloys, including nickel-base alloys. New rapid manufacturing technologies allow us to produce parts in any shape that can be designed by computer-aided design (CAD) software. Additionally, the …

Effect Of Hafnium-Incorporation On The Microstructure And Dielectric Properties Of Cobalt Ferrite Ceramics, Stephen Josiah Wells

Open Access Theses & Dissertations

The effect of hafnium ion (Hf⁴⁺) incorporation in cobalt ferrite (CFO) was studied. Samples of Hf substituted CFO ceramic (CoFe_2-xHf_xO₄), were synthesized in the laboratory with hafnium concentrations ranging from x=0.000 to x=0.200. X-ray diffraction scans show that the Hafnium CFO crystalizes in the inverse spinel phase. Inclusion of hafnium causes lattice expansion, increasing the lattice parameter from 8.374 í? for pure CoFe2O4 to 8.391 í? for the highest concentration of hafnium tested (x=0.020). The dielectric properties of CFO are greatly enhanced by inclusion of hafnium. The enhancement is due to the …

New Topics On Nanoindentation Of Polymers And Composite Materials, Ricardo Martinez-Hernandez

Open Access Theses & Dissertations

In this study, nanoindentation was used to determine Young's modulus of homogeneous plastic materials as well as inhomogeneous epoxy woven fabric composites using various indenters. In the first part, homogeneous PMMA and polycarbonate were characterized using conical and spherical indenters. The conventional approach of the inverse analysis was modified in order to account for effects obtained during spherical nanoindentation. The experimental results were verified using FEA analysis in ABAQUS. It was found that viscous effects were present in conical nanoindentations which led to an overestimation of contact stiffness. The second part, the response of carbon and glass fiber woven fabric …

Reducing Metal Alloy Powder Costs For Use In Powder Bed Fusion Additive Manufacturing: Improving The Economics For Production, Fransisco Medina

Open Access Theses & Dissertations

Titanium and its associated alloys have been used in industry for over 50 years and have become more popular in the recent decades. Titanium has been most successful in areas where the high strength to weight ratio provides an advantage over aluminum and steels. Other advantages of titanium include biocompatibility and corrosion resistance. Electron Beam Melting (EBM) is an additive manufacturing (AM) technology that has been successfully applied in the manufacturing of titanium components for the aerospace and medical industry with equivalent or better mechanical properties as parts fabricated via more traditional casting and machining methods. As the demand for …