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Electrosynthesis Of A New Electroactive Poly(2,2'-Diaminophenyloxydisulfide), Yu Zhi Su, Yan Wen Rao, Ye Yang, Mei-Bing Chen, Yin Ling Qiu, Yong-Hua Zhang, Ke Cheng Gong
Electrosynthesis Of A New Electroactive Poly(2,2'-Diaminophenyloxydisulfide), Yu Zhi Su, Yan Wen Rao, Ye Yang, Mei-Bing Chen, Yin Ling Qiu, Yong-Hua Zhang, Ke Cheng Gong
Journal of Electrochemistry
A new electroactive poly(2,2' diaminophenyloxydisulfide) (PDAPD) was successfully synthesized from acetonitrile(AN)/tetrahydrofuran(THF)solutions containing the supporting electrolyte(LiClO 4)and the various kinds of acids(HCl,CF 3COOH,CCl 3COOH) on Pt electrode by consecutive cyclic voltammiry. The effects of the concentrations of supporting electrolyte(LiClO 4) and acid(HCl,CF 3COOH,CCl 3COOH) on electrodepositon of PDAPD film were investigated. The best experimental conditions for electrosynthesis of a highly electroactive conducting polymer film are that the concentrations are 0.1 mol/L and between 0.05 mol/L～0.5 mol/L,respectively for LiClO 4 and HCl.