Open Access. Powered by Scholars. Published by Universities.®

Engineering Science and Materials Commons

Open Access. Powered by Scholars. Published by Universities.®

Electrical and Computer Engineering

1996

Electrocrystallization

Articles 1 - 1 of 1

Full-Text Articles in Engineering Science and Materials

Study On The Growth Process Of Lead Dioxide On Lead-Antimony Electrodes By Impedance Tracing Method, Guolin Wei, Hongxin Yang, Jiarong Wang Aug 1996

Study On The Growth Process Of Lead Dioxide On Lead-Antimony Electrodes By Impedance Tracing Method, Guolin Wei, Hongxin Yang, Jiarong Wang

Journal of Electrochemistry

The growth process of PbO2 formed by the oxidation of PbSO4 in the anodic film on lead-(1,3,5,7)wt%antimony electrodes was investigated with impedance tracing method of single frequency and the current-time transient method. The influence of antimony on this process was studied.The simulation curves obtained for capacity-time transients fit the experimental results very well.It has been shown that the mentioned growth process is a two-dimentional instantaneous nucleation and growth process,Antimony will inhibit the growth of PbO2 nucleus but enhance its nucleation.