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Full-Text Articles in Engineering Science and Materials
Electrochemical Synthesis And Characterization Of The Nickel Electropolyurushiol Coordination Polymer, Feng Gao, Guo-Cai Shen, Jie-Yuan Tang, Wen-Gong Zhang
Electrochemical Synthesis And Characterization Of The Nickel Electropolyurushiol Coordination Polymer, Feng Gao, Guo-Cai Shen, Jie-Yuan Tang, Wen-Gong Zhang
Journal of Electrochemistry
The nickel electropolyurushiol coordination polymer(EPU Ni 2+ ) was obtained by the reaction between nickel chloride isopropyl alcohol solution with electropolyurushiol (EPU).The electrochemical polymerization of urushiol and the preparation of nickel electropolyurushiol coordination polymer were investigated.The coordination polymer was characterized by XPS,FT_IR,DMTA and AES methods,and its composition and structure were determined.The content of Ni 2+ reached up to 7.5%. It was shown that there was certain coordination between Ni 2+ and electropolyurushiol in the coordination polymer,thus cross_links were formed.Therefore the glass transition temperature of the coordination polymer increased and heat resistance was enhanced considerably.
Investigation Of A Complex Lithium Cobalt Nickel Oxide As Lithium Ion Battery Cathode Materials Prepared By A New Citrate Sol-Gel Method, Jing-Li Han, Qing Guo Liu
Investigation Of A Complex Lithium Cobalt Nickel Oxide As Lithium Ion Battery Cathode Materials Prepared By A New Citrate Sol-Gel Method, Jing-Li Han, Qing Guo Liu
Journal of Electrochemistry
The synthesis and electrochemical characteristics of lithium cobalt nickel oxide as cathode materials for rechargeable lithium batteries were investigated. It was clarified from these investigations that lithium cobalt nickel oxide has been produced from basic cobalt carbonate,basic nickel carbonate, lithium carbonate, and citrate. LiNi 0.8 Co 0.2 O 2 prepared under the stream of oxygen gas showed a higher cycling capacity of (~190 mAhg 1 ).