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Articles 1 - 7 of 7
Full-Text Articles in Chemical Engineering
Modeling Of Gas Production From Shale Reservoirs Considering Multiple Transport Mechanisms, Chaohua Guo, Mingzhen Wei, Hong Liu
Modeling Of Gas Production From Shale Reservoirs Considering Multiple Transport Mechanisms, Chaohua Guo, Mingzhen Wei, Hong Liu
Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works
Gas transport in unconventional shale strata is a multi-mechanism-coupling process that is different from the process observed in conventional reservoirs. In micro fractures which are inborn or induced by hydraulic stimulation, viscous flow dominates. And gas surface diffusion and gas desorption should be further considered in organic nano pores. Also, the Klinkenberg effect should be considered when dealing with the gas transport problem. In addition, following two factors can play significant roles under certain circumstances but have not received enough attention in previous models. During pressure depletion, gas viscosity will change with Knudsen number; and pore radius will increase when …
2,2-Dimethylbutane Adsorption And Diffusion In Mfi Zeolite, Miao Yu, J. Wyss, R. Noble, J. Falconer
2,2-Dimethylbutane Adsorption And Diffusion In Mfi Zeolite, Miao Yu, J. Wyss, R. Noble, J. Falconer
Miao Yu
No abstract provided.
Transport Limitations In Zeolites And Biomass Pyrolysis, Andrew Robert Teixeira
Transport Limitations In Zeolites And Biomass Pyrolysis, Andrew Robert Teixeira
Doctoral Dissertations
Biomass pyrolysis has been widely explored for its potential to generate a sustainable chemical source capable of producing synthetic fuels and chemicals. Lignocellulosic biomass is the carbon rich, inedible fraction of wood that is comprised of long oxygenated biopolymers, primarily cellulose, hemicellulose and the highly aromatic lignin. High temperature thermal conversion of biomass to bio-oil (pyrolysis oil) occurs on the order of milliseconds and converts long chain biopolymers to a carbon-rich liquid crude. The chemistry of biomass pyrolysis is greatly complicated by significant heat and mass transport challenges. The complex fluid dynamics of the reactive liquid intermediate are examined in …
Parameter Estimates For A Pemfc Cathode, Qingzhi Guo, Vijay A. Sethuraman, Ralph E. White
Parameter Estimates For A Pemfc Cathode, Qingzhi Guo, Vijay A. Sethuraman, Ralph E. White
Ralph E. White
Five parameters of a model of a polymer electrolyte membrane fuel cell (PEMFC) cathode (the volume fraction of gas pores in the gas diffusion layer, the volume fraction of gas pores in the catalyst layer, the exchange current density of the oxygen reduction reaction, the effective ionic conductivity of the electrolyte, and the ratio of the effective diffusion coefficient of oxygen in a flooded spherical agglomerate particle to the square of that particle radius) were determined by least-squares fitting of experimental polarization curves. The values of parameters obtained in this work indicate that ionic conduction and gas-phase transport are two …
Using Parameter Estimation Techniques With A Simple Model Of A Diaphragm-Type Electrolyzer To Predict The Electrical Energy Cost For Naoh Production, John Van Zee, Ralph E. White
Using Parameter Estimation Techniques With A Simple Model Of A Diaphragm-Type Electrolyzer To Predict The Electrical Energy Cost For Naoh Production, John Van Zee, Ralph E. White
Ralph E. White
Predictions of the electrical energy cost for NaOH production are determined as a function of the independent operating variables and diaphragm characterizing properties. The predictions are based on data from a statistically designed experiment, a simple model of a diaphragm-type electrolyzer, a simple model of the cell voltage losses, and parameter estimation techniques. The data were obtained over a sufficiently large range of operating conditions so that the resulting design equation may be industrially useful. The simple model of the diaphragm is based on the mass transport of the hydroxyl ion, a linear potential gradient, and is presented in terms …
Determination Of Transport And Electrochemical Kinetic Parameters Of Bare And Copper-Coated Lani4.27Sn0.24 Electrodes In Alkaline Solution, G. Zheng, Branko N. Popov, Ralph E. White
Determination Of Transport And Electrochemical Kinetic Parameters Of Bare And Copper-Coated Lani4.27Sn0.24 Electrodes In Alkaline Solution, G. Zheng, Branko N. Popov, Ralph E. White
Ralph E. White
Electrochemical properties of bare and copper-coated LaNi4.27Sn0.24 electrodes were investigated in alkaline solution. The exchange current density, polarization resistance, and equilibrium potential were determined as functions of the state of charge in the electrodes. The symmetry factors for bare and copper-coated electrodes were estimated to be 0.53 and 0.52, respectively. By using a constant current discharge technique, the hydrogen diffusion coefficient in bare and coated LaNi4.27Sn0.24 was estimated to be 6.75 × 10–11 cm2/s.
Matrix Effects On Interdiffusion At The Polystyrene And Poly(Vinyl Methyl Ether) Interface, Esmaiel Jabbari, Nikolaos Peppas
Matrix Effects On Interdiffusion At The Polystyrene And Poly(Vinyl Methyl Ether) Interface, Esmaiel Jabbari, Nikolaos Peppas
Esmaiel Jabbari
No abstract provided.