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Full-Text Articles in Chemical Engineering
Heats Of Transport From Diffusion Thermoeffect Measurements On Binary Liquid Mixtures Of Carbon Tetrachloride With Benzene, Toluene, 2-Propanone, N-Hexane, And N-Octane, Richard L. Rowley, S. C. Yi
Heats Of Transport From Diffusion Thermoeffect Measurements On Binary Liquid Mixtures Of Carbon Tetrachloride With Benzene, Toluene, 2-Propanone, N-Hexane, And N-Octane, Richard L. Rowley, S. C. Yi
Faculty Publications
Measurements of heats of transport are reported for binary liquid mixtures containing carbon tetrachloride and benzene, toluene, 2-propanone, n-hexane, or n-octane at 298 K and ambient pressure. Additionally, measurements were made at 308 K for carbon tetrachloride with benzene, toluene, and 2-propanone. The corresponding heat-mass Onsager coefficients are also reported, from which thermal diffusion ratios have been calculated based on Onsager reciprocity. These data will be used in a companion paper to report a modified Enskog method for correlation and prediction of heats of transport.
On The Use Of A Modified Square-Well Model For Prediction And Correlation Of Thermal Diffusion Factors In Binary Liquid Mixtures, Richard L. Rowley, S. C. Yi
On The Use Of A Modified Square-Well Model For Prediction And Correlation Of Thermal Diffusion Factors In Binary Liquid Mixtures, Richard L. Rowley, S. C. Yi
Faculty Publications
Recently reported thermal diffusion factors obtained from heats of transport have been used to test the ability of existing theories to predict thermal diffusivities using model parameters regressed from pure component transport data. None of the theories tested were able to provide even qualitative agreement with experiment. However, predictions using a square-well Enskog theory, modified here for consistency with normal experimental definitions, were found to be approximately correct using pure-component square-well parameters regressed from viscosity and thermal conductivity and an assumed mixing rule for cross terms. Predicted values are very sensitive to the energy mixing rule, and correlation of experimental …
Hard-Sphere Theory For Correlation Of Tracer Diffusion Of Gases And Liquids In Alkanes, Michael A. Matthews, Aydin Akgerman
Hard-Sphere Theory For Correlation Of Tracer Diffusion Of Gases And Liquids In Alkanes, Michael A. Matthews, Aydin Akgerman
Faculty Publications
No abstract provided.
Utility Of An Empirical Method Of Modeling Combined Zero Gap/Attached Electrode Membrane Chlor-Alkali Cells, Clifford W. Walton, Ralph E. White
Utility Of An Empirical Method Of Modeling Combined Zero Gap/Attached Electrode Membrane Chlor-Alkali Cells, Clifford W. Walton, Ralph E. White
Faculty Publications
An extensive survey of the Docktor-Ingenieur Dissertationen of Jakob Jörissen and Klaus-R. Menschig, both originally from the Universität Dortmund, is presented in regard to the empirical modeling of membrane chlor-alkali cells and how it can be applied to a combined zero gap/attached porous electrode layer membrane cell. Particular emphasis isplaced on Menschig's work on zero gap (ZG) and attached porous electrode layer (APEL) membrane chlor-alkali cells, the first such research to appear in the open literature. Menschig developed various computer programs to characterize these ZG and APEL membrane chlor-alkali cells. He characterized these cells by using the following parameters: the …