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Full-Text Articles in Chemical Engineering

Fluidization Of Nanoparticles, Caroline Hijung Nam Aug 2004

Fluidization Of Nanoparticles, Caroline Hijung Nam

Dissertations

During the past decade, nanoparticles (1-100 nm) and nanocomposites have become the focus of many studies due to the unique properties of nanostructured materials that make them attractive for various applications. Due to their atomic and molecular interactions, nanoparticles and nanocomposites have unique and often favorable catalytic, mechanical, optical, electronic and / or other properties. For instance, nanocrystalline copper is up to 5 times harder than conventional micron sized copper particles. Nanocomposites, such as a homogenous mixture of different nanoparticles, can also exhibit improved properties. Other examples include coating and reacting nanoparticles with a second nanostructured phase. These processes are …


Fluidization Of Agglomerates Of Nanoparticles Under Different Force Fields, Jose A. Quevedo Aug 2004

Fluidization Of Agglomerates Of Nanoparticles Under Different Force Fields, Jose A. Quevedo

Theses

Nanoparticles are the focus of many research activities, and in the near future they will be handled in large amounts by industry. Fluidization is a very important unit operation which is applied in several industrial processes.

In the present work, fluidization experiments with agglomerates of nanoparticles were done under different force fields: (1) gravity force or conventional fluidization; (2) a magnetic force field, which uses magnetic particles under the influence of a magnetic field; and (3) a centrifugal force, generated by a rotating frame that simulates higher gravity conditions.

Among the significant results with agglomerates of nanoparticles, conventional fluidization was …


Burning Sewage Sludge From A Municipal Waste Water Treatment Plant – The Migreation Of Metals, Witold Zukowski, Jerzy Baron, Sylwia Chrupek, Malgorzata Pilawska Dec 2003

Burning Sewage Sludge From A Municipal Waste Water Treatment Plant – The Migreation Of Metals, Witold Zukowski, Jerzy Baron, Sylwia Chrupek, Malgorzata Pilawska

Witold Zukowski

The migration of selected heavy metals has been analysed when sewage sludge from a municipal waste water treatment plant was burned in a bubbling fluidised bed. It has been shown that manganese, lead, arsenic, mercury and cadmium, as opposed to chromium, nickel and copper, leave the reactor mainly via the gas phase. To reduce the emissions of heavy metals to the atmosphere associated with the thermal utilization of sewage sludge requires more effective flue gases cleaning than is possible with filters.


Utilisation Of Waste Fuels In A Fluidised Bed, Jerzy Baron, Malgorzata Pilawska, Malgorzata Olek, Witold Zukowski Dec 2003

Utilisation Of Waste Fuels In A Fluidised Bed, Jerzy Baron, Malgorzata Pilawska, Malgorzata Olek, Witold Zukowski

Witold Zukowski

A 100 kW atmospheric, bubbling fluidised bed reactor was used to study the combustion of wood waste, sewage sludge and a mixture of sewage sludge and meat-and-bone meal. Steady operation of the combustor was possible, even if the fuel was abruptly changed. With sewage sludge, the flue gas concentrations of SO2 and NOx were relatively high, as the sludge fuel contained much higher concentrations of combined S and N than e.g. wood waste. Co-combustion of sewage sludge and meat-and-bone meal presented no problems and the composition of the flue gases was similar to obtained the combustion of sewage sludge from …