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Full-Text Articles in Chemical Engineering

Dynamic Contact Angles Under Evaporation, Robert M. Ybarra, Partho Neogi Mar 2004

Dynamic Contact Angles Under Evaporation, Robert M. Ybarra, Partho Neogi

Chemical and Biochemical Engineering Faculty Research & Creative Works

Wetting kinetics in the presence of heat transfer, evaporation, and Marangoni effect has been explored using a method used by Joanny and de Gennes [C. R. Acad. Sci. Ser. II 299, 279 (1984)]. The method solves for the dynamic contact angle alpha by equating the rate of surface work to the rate of dissipation. The result in the form of dynamic contact angle alpha as a function of capillary number Ca agrees well with existing experimental data. Qualitative comparisons have been made in cases where quantitative data do not exist. Finally, a form of contact line instability is predicted, for …


Series Solution To The Transient Convective Diffusion Equation For A Rotating Disk Electrode, Shiriram Santhanagopalan, Ralph E. White Jan 2004

Series Solution To The Transient Convective Diffusion Equation For A Rotating Disk Electrode, Shiriram Santhanagopalan, Ralph E. White

Faculty Publications

A series solution to the transient convective diffusion equation for the rotating disc electrode system is presented and compared to previously reported solutions. The solution presented here is for the entire time domain and agrees well with both the short and long time solutions presented earlier in the literature.