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Full-Text Articles in Chemical Engineering

Metal-Doped Rare Earth Oxide Catalysts For Condensations To Ketones, Arvind Karkal Bhat Jan 2004

Metal-Doped Rare Earth Oxide Catalysts For Condensations To Ketones, Arvind Karkal Bhat

LSU Master's Theses

Metal-doped supported rare earth oxide catalysts were examined to determine their suitability for the decarboxylative condensation of two carboxylic acids to produce ketones. The catalysts were characterized based on chemisorption tests, coke analysis using thermo-gravimetric analysis and X-ray absorption spectroscopy. Effect of catalyst particle size on rate of reaction was studied for various supported cerium oxide catalysts. Catalysts were tested for activity, selectivity, and stability using isothermal fixed bed reactors. Optimal operating conditions for the production of diisopropyl ketone and methyl nonyl ketone were determined. It was found that supported cerium oxide catalysts effectively catalyzed the condensation of isobutyric acid …


Development And Integration Of New Processes Consuming Carbon Dioxide In Multi-Plant Chemical Production Complexes, Sudheer Indala Jan 2004

Development And Integration Of New Processes Consuming Carbon Dioxide In Multi-Plant Chemical Production Complexes, Sudheer Indala

LSU Master's Theses

New, energy-efficient and environmentally acceptable, catalytic processes have been identified that can use excess high purity CO2 as a raw material from the sources available in a chemical production complex. The chemical complex in the lower Mississippi River Corridor has been used to show how these new plants can be integrated into this existing infrastructure using the Chemical Complex and Cogeneration Analysis System. Eighty six published articles of laboratory and pilot plant experiments were reviewed that describe new methods and catalysts to use CO2 for producing commercially important products. Reactions have been categorized as hydrogenation reactions; hydrocarbon synthesis …


Online Heat Transfer Measurement And Analysis For Sugar Mill Evaporators, David Timothy Solberg Jan 2004

Online Heat Transfer Measurement And Analysis For Sugar Mill Evaporators, David Timothy Solberg

LSU Master's Theses

Fouling and scaling in evaporators has been an area of great interest to raw sugar mills for a number of years and many of the mechanisms causing the scale and the rates of scaling are unknown. In an attempt to quantify the scaling rates and measure the scaling, an online model has been developed to model a system of evaporators. Monitoring the heat transfer coefficient as a function of time enabled measurement of the scaling rate by monitoring the heat transfer coefficient as it decreased with time. It is assumed that the scaling on the juice side of the evaporators …


Evaluation Of New Methods For Processing Drilling Data To Determine The Cause Of Changes In Bit Performance, Jaime Solano Jan 2004

Evaluation Of New Methods For Processing Drilling Data To Determine The Cause Of Changes In Bit Performance, Jaime Solano

LSU Master's Theses

Drilling operations represent the major cost in finding and developing new petroleum reserves. Poor drilling performance when drilling deep shale and strong rocks, as evidenced by slow rate of penetration (ROP), has a significant detrimental impact on drilling costs. Also, it has been concluded that bit balling is the main cause of low ROP when drilling deep, clay-rich shale with water-based mud. In addition, it is estimated that a potential saving in drilling cost of hundreds of millions of dollars a year can be obtained if bit balling is mitigated and ROP is improved. Several methods have been developed in …


Trajectory And Window Width Predictions For A Cased Hole Sidetrack Using A Whipstock, Harshad Prakash Patil Jan 2004

Trajectory And Window Width Predictions For A Cased Hole Sidetrack Using A Whipstock, Harshad Prakash Patil

LSU Master's Theses

The Trackmaster system manufactured by Smith Services consists of a multi-ramped whipstock and a trimill assembly used to perform a sidetrack from a cased well. Smith Services has observed evidence that the trimill assembly may prematurely leave the face of the whipstock and build excess inclination and dogleg severity or may fall into the original well immediately after leaving the end of the whipstock ramp thus creating a need to predict the borehole trajectory for sidetracking operations. The goal of this project was to predict the borehole trajectory and the window profile cut in the casing by the sidetracking equipment …


A Re-Evaluation Of Geopressured-Geothermal Aquifers As An Energy Resource, Jeremy Scott Griggs Jan 2004

A Re-Evaluation Of Geopressured-Geothermal Aquifers As An Energy Resource, Jeremy Scott Griggs

LSU Master's Theses

The search for more efficient and economical forms of energy generation is a continual process. Natural gas production and electricity generation from geopressured-geothermal aquifers is an unconventional hydrocarbon source that has long been unproductive due to its marginal economics and lack of technological certainty. This thesis demonstrates that, based on modern technological competencies and economic constraints, geopressured-geothermal energy now maintains a viable future as an alternative domestic energy source.


Modeling Of Cane Sugar Colorant Removal In Packed-Bed Ion Exchange Columns And An Investigation Into Pretreatment Methods, Bruce Malcolm Ellis Jan 2004

Modeling Of Cane Sugar Colorant Removal In Packed-Bed Ion Exchange Columns And An Investigation Into Pretreatment Methods, Bruce Malcolm Ellis

LSU Master's Theses

Cane sugar colorants have been extensively researched but still little is known about their exact compositions. Rather than distinct compounds, they are a mixture of many compounds. Some it is assumed can be classified into the pseudo components that have been defined using gel permeation chromatography, based on molecular weight. The defining of these components has allowed the colorants to be modeled independently, instead of as one lumped color parameter. The measured colored components were modeled using a linear driving force adsorption model, which could be applied in the design process for optimizing the decolorizing capacity of the resins. The …