Chemical Engineering Commons^™

Influence Of Connection Placement To The Behavior Of Precast Concrete Exterior Beam-Column Joint, Elly Tjahjono, Heru Purnomo

Makara Journal of Technology

Influence of Connection Placement to the Behavior of Precast Concrete Exterior Beam-Column Joint. This paper presents an experimental study on the influence of connection placement to the behaviour of exterior beamcolumn joint of precast concrete structure under semi cyclic loading. Four half-scale beam-column specimens were investigated. Three beam-columns were jointed through connection that are placed in beam-column joint region and the forth is connected at the plastic hinge potensial region of the beam. Crack patterns, strength, stiffness and ductility of the test specimens have been evaluated. The test result indicated that all beam-column specimens show good ductility behavior.

The Effects Of Influent Debit On Hydrodynamic Characteristic Of Bojongsoang Facultative Pond: Without Wind Effects, Rositayanti Hadisoebroto, Suprihanto Notodarmojo

Makara Journal of Technology

The Effects of Influent Debit on Hydrodynamic Characteristic of Bojongsoang Facultative Pond: Without Wind Effects. The performance of facultative pond in Bojongsoang WWTP have reported to be unstable. One of the cause of the unstable performance is the hydrodynamic characteristics that not met the criterion. The improper hydrodynamic characteristics are included the existence of dead-zone, the short-circuiting, and the turbulence due to eddy current. The study was to analyze the effect of the influent debit variation on the hydrodynamic characteristics of the pond using mathematical model. The two-dimensional hydrodynamic model was built from two hydrodynamic equations which are continuity and …

Optic Properties On Aggase2 Polycristal Fabrication, A. Harsono Soepardjo, I Dewa Made Janusetiawan

Makara Journal of Technology

Optic Properties on AgGaSe2 Polycristal Fabrication. Polycristal AgGaSe2, is compound (I-III-VI2) a semiconductor as basic material for thin film for solar cell. Polycristal was succesfully grown using Bridgmann Method, heated on sequential temperature treatment until 850°C and cooled down slowly until room temperature. Results observed were in the form of ingot (bars) with more or less 3 cm length and 13 mm in diameter. By using X-Ray Fefraction, composition obtained of each element (weight %) was Ag = 29,3996 %, Ga = 36,8123 % and Se = 30,29 % while using X-Ray Difraction lattice parameter obtained/calculated a = 4,4112 Å, …

Modelling And Simulation Of Packed Bed Catalytic Converter For Oxidation Of Soot In Diesel Powered Vehicles Flue Gas, Mohammad Nasikin, Praswasti P.D.K. Wulan, Vita Andrianty

Makara Journal of Technology

Modelling and Simulation of Packed Bed Catalytic Converter for Oxidation of Soot in Diesel Powered Vehicles Flue Gas. Diesel vehicle is used in Indonesia in very big number. This vehicle exhausts pollutants especially diesel soot that can be reduces by using a catalytic converter to convert the soot to CO2. To obtain the optimal dimension of catalytic converter it is needed a model that can represent the profile of soot weight, temperature and pressure along the catalytic converter. In this study, a model is developed for packed bed catalytic converter in an adiabatic condition based on a kinetic study that …

Fuel Injection System For One Cylinder Motor Cycle Engine, Bambang Sugiarto

Makara Journal of Technology

Fuel Injection System for One Cylinder Motor Cycle Engine. Fuel injection has been developed for many years. But its common application is limited on car’s engine. With many reason fuel injection systems in motorcycle one cylinder engine has not been widely used yet. Fuel Injection System allows the amount of fuel, injected to be controlled appropriate to engine parameters such as engine speed, amount of air inducted to cylinder, temperature, for each cycle, over the entire engine operating conditions. This fuel injection research is done to find out the Volumetric Efficiency of the intake manifold system, the amount of fuel …

Electrochemical Behaviours Of Hemoglobin-Ddab-Modified Powder Microelectrode And The Application Of The Powder Microelectrode In Determination Of Nitric Oxide, Zhi-Mou Guo, Huan Liu, Jian Chen, Wen-Ting Zhang

Journal of Electrochemistry

The electrochemical behaviours of DDAB-Hb-PME were studied in this paper. The (apparent) surface concentration of Hb was enhanced greatly by using the powder microelectrode (technique). NO reacts with Hb and absorbs on the surface of the modified carbon powder. Therefore, the output of the electrode was enhanced greatly by employing PME with higher reaction surface (area). The sensitivity of DDAB-Hb-PME is 3.1 mA/μmol·L~(-1)·cm~(2), which is much larger than the values obtained with the traditional electrodes. The detection limit is 9 nmol·L~(-1) and the linear response range is 9～100 nmol·L~(-1).

Electrocatalytic Performances Of Carbon Nanotube Air Electrode For Oxygen Reduction, Feng-Ming Zhao, Chun-An Ma

Journal of Electrochemistry

The air electrodes with different mass ratio of Pt/active carbon or carbon nanotube as catalyst layer material have been prepared. The electrocatalytic performances for oxygen reduction were evaluated by means of polarization curve and electrochemical impedance spectroscopy (EIS). The results disclosed that carbon nanotubes dealt with nitric acid in the catalyst layer had been improved obviously on the electrocatalytic activity. After the surface of carbon nanotube was oxygenated and aggraded with platinum, the catalyst had obviously effects on the electrocatalytic activity. The air electrode with the mass ratio of active carbon to Pt/carbon nanotube in 4∶1 showed better electrocatalytic activity, …

Anodic Dissolution Of Aluminum In Koh-Ethanol Solutions, Hai-Bo Shao, Jian-Ming Wang, Xiao-Yan Wang, Yi Zheng, Jian-Qing Zhang

Journal of Electrochemistry

The feasibility of employing aluminum in KOH ethanol solution as a battery anode system was discussed. Weight loss measurement showed that the corrosion rate of Al is low enough to be used in sealed batteries. Through the measurements done by anodic polarization, EIS and galvanostatic discharge, it was found that A1 is electrochemical active in a wide potential range in this system, and its discharge mechanism is similar to that of A1 in aqueous solution. The discharge potential increased rapidly after a period of time, which might be caused by the discharge products depositing on the electrode surface.

Preparation And Photo-Catalyst Properties Of The Α-Fe_2o_3-Tio_2 Films On Sodium Alginate Polymer, Li-Qin Chen, Huai-Zhen Zhong, Ri-Yao Chen, Xi Zheng, Zhen Chen

Journal of Electrochemistry

Three new nano thin films of α-Fe_2O_(3)、TiO_2 and α-Fe_2O_(3)-TiO_2 by doping their powder with sodium alginate polymer were prepared. Surface structure and catalytic activities of the films were characterized by FTIR、XRD、PL、TEM and I-V techniques. The results of UV-visible absorption showed that the methylene blue was mineralized in aqueous of α-Fe_2O_(3)/SA、TiO_2/SA and (α-(Fe_2O_(3)))-TiO_2 /SA upon radiation with ultra violet light. α-Fe_2O_(3) enhanced their photo-decolorized-activities by doping 15% TiO_2.

Effect Of Fe~(3+) Dopen Of Titanium Dioxide Film On Absorption Spectra And Photo Catalysis, Mei-Qun Xiao, Jia-Nian Shen, Moucheng Li, Peng-Fei Wu, Dong Liu, Yu-Juan Zhang

Journal of Electrochemistry

Photo-catalytic titanium dioxide film in nano crystalline has been prepared by electrochemical oxidation process and adding different amount of ferric ion into the electrolyte during the anodic oxidation.The effects of Fe~(3+) dopen on absorption spectra and photo-catalytic of the titanium dioxide films have been studied. It shows that the Fe~(3+) dopen caused the red shife of the absorption edge for the incoming light and exhibited the improved photocatalytic reactivity.

Layer-By-Layer Nanoassembly Combined With Microfabrication Techniques For Microelectronics And Microelectromechanical Systems, Jingshi Shi

Doctoral Dissertations

The objective of this work is to investigate the combination of layer-by-layer self-assembly with microfabrication technology and its applications in microelectronics and MEMS.

One can assemble, on a standard silicon wafer, needed multilayers containing different nanoparticles and polymers and then apply various micromanufacturing techniques to form microdevices with nanostructured elements.

Alternate layer-by-layer self-assembly of linear polyions and colloidal silica at elevated temperatures have been firstly studied by QCM and SEM. LbL self-assembly and photolithography were combined to fabricate an indium resistor. The RTA method was employed in the fabrication. Hot-embossing technique as a reasonably fast and moderately expensive technique was …

Synthesis And Electrochemical Behavior Of Layered-Structure Limn_(1-X)Cr_Xo_2, Jie Xiao, Hui Zhan, Yun-Hong Zhou

Journal of Electrochemistry

The Layered-structure LiMn_(1-x)Cr_xO_(2 )(x=0,0.15) solid solution has been prepared by the rheological phase method. From the XRD results, undoped LiMnO_(2) crystallized almost entirely in the orthorhombic phase while the structure of LiMn_(0.85)Cr_(0.15)O_(2) belongs to monoclinic phase. TEM investigation shows that the final powder product consists of ultrafine spherical particles which are distributed homogeneously, with the average diameter ranging from 60 to 300nm. The initial discharge capacity of LiMn_(0.85)Cr_(0.15)O_(2) is much higher than that of undoped LiMnO_(2). After 40 cycles, the capacity retention for m-LiMn_(0.85)Cr_(0.15)O_(2 )is 94% at the current rate of 50mA/g under room temperature. The results of electrochemistry tests …

Lithium Insertion Into Tio_2(B) Nanobelts Synthesized By The "Soft Chemical" Method, Cha-Geng Nie, Zheng-Liang Gong, Lan Sun, Juan Zuo, Yue-Kun Lai, Chang-Jian Lin

Journal of Electrochemistry

TiO_(2)(B) Nanobelts were synthesized by using the "Soft chemical"method. The products were characterized by means of transmission electron microscope(TEM), X-ray diffraction(XRD), Raman spectrum and energy dispersive spectrum(EDS). Galvanostatic charging and discharging tests showed that lithium-ion intercalation/deintercalation occurred reversibly in the TiO_(2)(B) nanobelts electrode, and a high capacity (265 mAh·g~(-1)) can be obtained. The results suggested that TiO_(2)(B) Nanobelts might be a promising negative electrode material of second Lithium battery.

Study On An Intermediate Temperature Planar Solid Oxide Fuel Cell, Shao-Rong Wang, Wen-Xia Chen, Ting-Lian Wen, Jia-Di Cao, Zhi-Yi Lv, Da-Qian Wang

Journal of Electrochemistry

Tape cast method was applied to prepare green sheets of Ni/YSZ anode supported YSZ thin film. After isostatic pressure treatment and cosintering, the YSZ film on the Ni/YSZ anode was gas-tight dense, and 15~30 μm thick. The area of the composite film was over 100 cm~(2). A Ce_(0.8)Sm_(0.2)O_(1.9 )(CSO) interlayer was sintered on to the YSZ electrolyte film to protect La_(0.6)Sr_(0.4)CoO_(3 )(LSCO) cathode from reaction with YSZ at high temperatures. The LSCO cathode layer was screen printed onto the CSO interlayer and sintered at 1 200 ℃ for 3h to form a single cell. The obtained single cell was operated …

Fabrication Of Solid Oxide Fuel Cells And Analysis Of Their Structure And Performance, Nai-Tao Yang

Journal of Electrochemistry

An intermediate temperature solid oxide fuel cell (IT-SOFC) was fabricated by co-copressing-sintering methods, and the electrolyte of Ce_(0.8)Gd_(0.2)O_(1.9) (CGO) and cathode materials of La_(0.6)Sr_(0.4)Co_(0.2)Fe_(0.8)O_(3-α) (LSCF) were prepared by sol-gel method. The effect of preparation methods on the microstructure of the prepared fuel cells was analyzed by SEM . It shows that the cells prepared by the co-pressing/co-sintering method possess a dense electrolyte layer and a compact interface between electrolyte and anode but a curved configuration, while those prepared by the colloidal technique have a flat configuration but the electrolyte layer is not dense enough. The maximum output power density of …

Electrochemical Reduction Of Nitrobenzene On The Wc Electrode In Acidic Solution, Chun-An Ma

Journal of Electrochemistry

The tungsten carbide (WC) electrode was constructed by using polyterafluoroethylene as binder. The electrochemical behavior of nitrobenzene on the WC electrode in acidic solution was investigated by cyclic voltammetry, linear scan method and chronoamperometry. Experimental results showed that WC electrode had good activity for the electrochemical reduction of nitrobenzene, and the electrode process was controlled by diffusion and electrochemical stepssimultaneously. The apparent active energy of the electrode process is 23.7kJ mol~(-1), while the active energy of the electrochemicalstep is 10.91kJ mol~(-1).

Synthesis Of (S)-3-Phenylpropane-2-Tert-Butoxycarbonylamino- 1-Thiol And Its Electrochemical Behavior Self-Assembled On Gold, Sun Ru

Journal of Electrochemistry

The synthesis of (S)-3-Phenylpropane-2-tert-butoxycarbonylamino- 1-thiol(N-Boc-APT) from L-phenylalanine was reported. L-Phenylalanine was reduced to the corresponding amino alcohol, protection of the amino group using tert-butyl pyrocarbonate gave (S)-2-tert-butoxycarbonylamino-3-phenylpropane-1-ol, which was then O-mesylated and treated with potassium thioacetate in DMF to give 3-phenylpropane-2-tert- butoxycarbonylamino-1-etylmercapto. After the acetyl group was removed with ammonia in alcohol, the desired target molecular was obtained. The structure of intermediate and target molecular was conformed by IR and ~(1)HNMR. We made N-Boc-APT self-assemble-modificated gold electrode and investigated its electrochemical behavior. The CV results of methylene blue on nano-Au/N-Boc-APT SAM/Au electrode showed that nano-Au could speed this electron transfer …

Solid State Synthesis And Electrocatalysis Of Pt/Moo_3 For The Oxidation Of Methanol, Wang Qing

Journal of Electrochemistry

The electrocatalyst, Pt/MoO_(3) synthesized by solid state reaction, was used for the oxidation of methanol in direct methanol fuel cells. The X-Ray diffraction and cyclic voltammetry were employed to investigate the performance of the material. It was shown that the typical diffraction peaks for Pt appeared in XRD. And a good electrocatalysis for methanol oxidation was observed. The peak potential of the methanol oxidation appeared at ca. 0.63V(vs.SCE) and the peak current density for the oxidation was 78.1 mA cm~(-2) .

Preliminary Study Of Speek Membranes For Direct Methanol Fuel Cells Application, Su-Zhen Ren

Journal of Electrochemistry

This paper describes the methanol permeability characterization of SPEEK membranes and their feasibility for DMFC application. The SPEEK membranes showed a significant lower methanol permeation than Nafion~115 determined from voltammetric methods. An increase in open circuit voltage was found in the performance of SPEEK membranes in DMFC. The power density of the cell using SPEEK membrane was considerably poorer than that of Nafion~115. If modified properly, the SPEEK membranes can be chosen for DMFC application based on this study.

Secondary Flow Experimental Study For Axial Compressor Cascade Strong Stagger With And Without Tip- Clearance: Static Pressure Distribution On Blade Surface, Syamsuri Syamsuri

Makara Journal of Technology

Secondary Flow Experimental Study for Axial Compressor Cascade Strong Stagger With and Without Tip- Clearance: Static Pressure Distribution on Blade Surface. The performance of blade cascade is influenced by the growth and boundary layer’s separation along blade surface and endwall (casing and hub). The secondary flow which happens near hub and casing compressors is three dimentional flow separation phenomenon comes from interaction blade boundary layer with casing and hub boundary layers in the compressor. The secondary flow causes secondary losses, blockage effect, and turning angle (deflection) distribution along blade span. The result of the research shows that the increase of …

Synthesize Of Emulsion Polymer Latex For Sub-Grade Cbr Improvement In The Road Construction, Keba Moto, V. Julian, Syamsudin Syamsudin, T. A. Wiradi, S. R. Wijaya

Makara Journal of Technology

Synthesize of emulsion polymer latex for sub-grade CBR improvement in the road construction. Latex polymer for California Bearing Ratio (CBR) enhancement in sub-grade soil of road building has been prepared by emulsion polymerizations technique. The prepared polymer then characterize by Fourier Transform Infrared (FTIR). For application purpose, CBR test was done to the compacted polymer added-soil. The CBR test is done also for both soaked and unsoaked samples. It is found that our latex polymer is better then other imported latex polymer. For the latex polymer, which is design to have Temperatur glass (Tg) around 9.8-19.6o, indicating the formation of …

Effect Of Photoperiodicity On Co2 Fixation By Chlorella Vulgaris Buitenzorg In Bubble Column Photobioreactor For Food Supplement Production, Anondho Wijanarko, Dianursanti Dianursanti, Arief Budi Witarto, Roekmijati Widaningroem Soemantojo

Makara Journal of Technology

To reduce the level of CO2 content in air, effort on converting CO2 to useful products is required. One of the alternatives includes CO2 fixation to produce biomass using Chlorella vulgaris Buitenzorg. Chlorella vulgaris Buitenzorg is applied for production of food supplement. Chlorella vulgaris Buitenzorg is also easy to handle due to its superior adaptation. Currently, Chlorella vulgaris Buitenzorg has been analyzed by some experts for its cellular composition, its ability to produce high quality biomass and the content of essential nutrition. A series of experiments was conducted by culturing Chlorella vulgaris Buitenzorg using Beneck medium in bubbling column photobioreactor. …

Wavelenght-Dispersive X-Ray Flourescence Accuration, H. Widyatmoko

Makara Journal of Technology

Wavelenght–Dispersive X-Ray Flourescence Accuration. X-Fuorescence spectrometry is a method, which is increasingly applied in the geochemical analysis. X-Fuorescence spectrometry is classified under two categories – WDXRF (wavelenght – dispersive X-ray fluorescence spectrometer) and EDXRF (energy-dispersive X – ray fluorescence spectrometer). WDXRF can be configured as a sequential spectrometer , a simultaneous spectrometer or a hibrid instrument, which combines the advantages of the simultaneous and sequential spectrometers into one instrument. Each instrument is different in some characteristics, and each has applications for which it is specifically suited. In this investigation sequential spectrometer PW 1450 was used to analyze the major, minor …

Project-Based Introduction To Engineering - A University Core Course, Samuel Bogan Daniels, Bouzid Aliane, Jean Nocito-Gobel, Michael Collura

Engineering and Applied Science Education Faculty Publications

This paper describes a first year engineering course that is taken by both engineering and non-engineering students. The project-based Introduction to Engineering course, EAS107P, fulfills a university core curriculum elective. Although engineering students take the course during their first year, students from other majors typically elect to take the course later in their curriculum. The focus of EAS107P is to have students experience the engineering design and problem solving process in a multi-disciplinary, team-based setting. In addition to learning about design, students develop an interest in the engineering profession and build a foundation of skills for future work. An additional …

Development Of A Multidisciplinary Engineering Foundation Spiral, Samuel Bogan Daniels, Bouzid Aliane, Jean Nocito-Gobel, Michael Collura

Engineering and Applied Science Education Faculty Publications

To operate effectively in today’s workforce engineers need to have a muti-disciplinary perspective along with substantial disciplinary depth. This broad perspective cannot be achieved by merely taking 2 or 3 engineering courses outside of the major, but rather will require a radical change in the way we educate engineers. The faculty of the School of Engineering and Applied Science at the University of New Haven have developed a new approach: the Multidisciplinary Engineering Foundation Spiral. This curricular model provides the needed mix of breadth and depth, along with the desired professional skills, by providing carefully crafted, well-coordinated curricular experiences in …

Project-Based Introduction To Engineering -- Course Assessment, Samuel Bogan Daniels, Michael Collura, Bouzid Aliane, Jean Nocito-Gobel

Engineering and Applied Science Education Faculty Publications

The School of Engineering and Applied Science at the University of New Haven has a newly developed project-based Introduction to Engineering course. This new course plays a central role in the new Multi-Disciplinary Engineering Foundation Spiral curriculum as the first semester course for all engineering freshmen. An assessment process was developed to determine the effectiveness of this project-based course, specifically with attention towards assessing attitudes, impact on retention, problem-solving and engineering foundation topics. This paper addresses the particular portion of the assessment process for the individual course projects and their contribution to the last two assessment categories.

Project Planning & Development For Engineering Freshmen, Bouzid Aliane, Michael Collura, Samuel Bogan Daniels, Jean Nocito-Gobel

Engineering and Applied Science Education Faculty Publications

The nature and background of students seeking an engineering education has changed drastically in the last decade, as has the expectations of industrial employers. Many students lack the organizational skills needed for academic success. Similar organizational skills, although more advanced, are required for managing engineering projects. A new course was developed by the faculty at the School of Engineering and Applied Science at the University of New Haven. Through this course, a key component of the Multidisciplinary Engineering Foundation Spiral, seeks to promote higher retention rates, increase student motivation and begin a confidence-building transition to professional practice. Project management concepts …

Investigation Of Adsorption And Oxidation Behavior Of Isosafrole On A Smooth Pt, Xiao-Hong Zhang

Journal of Electrochemistry

The electro-oxidation of isosafrole on a smooth platinum electrode was investigated in the non-aqueous solution. The CV curve shows two oxidation peaks and one reduction peak in the potential region between -0.5 V and 1.95 V. The relation between the oxidation and reduction peaks has been determined also by CV. The adsorption behavior of isosafrole on Pt was also investigated.

Study On Reduction Process Of Electrolyic Manganese Dioxide In Situ By Ultraviolet-Visible Absorption Spectroscopy, Li-Cai Zhu, Zhong-Zhi Yuan, Wei-Shan Li

Journal of Electrochemistry

The concentrationsof soluble Mn(Ⅲ) species,during the reduction ofelectrolytic MnO_(2) (EMD)in alkaline solution,have been monitored in situ by UV-visible spectroscopy. The concentration of Mn(Ⅲ) ion in solution changes with discharge time.The first electron discharge process of EMD can be described by three different steps: 1) the reduction of Mn~(4+)ions on the surface of EMD particles and the structural defect regions within the EMD,2) the reduction of Mn~(4+)ions in ramsdellite,3)the reduction of Mn~(4+)ions in pyrolusite. During the second electron discharge of EMD, the soluble Mn(Ⅲ) is reduced to Mn(Ⅱ) , then Mn(OH)_(2)and Mn_(3)O_(4)are formed.

Electrocatalytic And Lifetime Studies Of Commercial Catalystsin A Pemfc, Cheng Xuan

Journal of Electrochemistry

A particularly designed H-type cell was used to simulate the operating condition of a hydrogen-air proton exchange membrane fuel cell (PEMFC). The electrocatalytic activity, morphology, structure and lifetime of commercially available catalysts, carbon support platinum (Pt/C) and unsupported platinum-ruthenium (Pt-Ru), were preliminary studied by carrying out electrochemical measurements and by SEM, XRD techniques. The catalysts were simultaneously tested in the H-cell under operation, and also separately tested in a conventional electrochemical cell for comparison. It was found that the characteristic peaks of hydrogen adsorption/desorption on cyclic voltammograms shifted considerably to a more positive direction for Pt/C, while a more negative …