Chemical Engineering Commons^™

A Quantitative Analysis By Emission Spectroscopy Of The Metallic Constituents Of Biological Samples After Treatment By A Carcinogenic Agent, Charles R. Frydrych

Masters Theses

No abstract provided.

Kinetics And Dynamics Of Continuous Crystallization, Karichangal C. Parthasarathy

Chemical and Biological Engineering ETDs

A design correlation is presented for the prediction of steady state product size distributions resulting from a continuous crystal­lizer, based upon a single experimental determination. This has been accomplished by the definition of a new parameter called the "degree of crystallization," which has been related to the experimental nuclea­tion and growth rates in a salting-out crystallizer. The correlation resulted from the detection of variations in the suspension density of the mother liquor which has previously been assumed constant in cer­tain power law models. The degree of crystallization has also been described in terms of dimensionless number, length and area moments …

The Fate Of Hazardous Polluting Substances In An Aqueous Environment, Robert Paul Casani

Theses

The fate of Hazardous Polluting. Substances (HPS) in an aqueous environment has been investigated using ultraviolet light. Chlorobenzene, o-cresol and nitrobenzene were used as model HPS for this study. The kinetics were followed and good first order plots were obtained for all compounds. The temperature of the reaction was shown to effect the rate. Solid insoluble and soluble non-volatile products were formed in the photolytic reaction of the three model systems.

The Preparation Of Cis- And Trans-1,2-Dimethoxyethylene. The Study Of The Cis-Trans-Rearrangement And Evaluation Of Equilibrium Constants, James T. Waldron

Dissertations

Equilibrium constants for the mercuric acetate-catalyzed reaction, cis-CH₃ OCH=CHOCH₃ D trans-CH₃ OCH=CHOCH₃, have been determined in the liquid and vapor phase over the temperature range 30° - 175°C by gas chromatography analysis. A novel synthesis of the cis- and trans-isomers of 1,2-dimethoxyethylene is discussed. From a screening of 29 catalysts, mercuric acetate, mercuric benzoate, and mercuric salicylate were found to be favorable isomerization catalysts. For the liquid phase reaction,

ln K = -779.8/T + 0.6748

with ΔH° = +1.549 ± 0.019 Kcal/mole
and ΔS° = +1.34 ± 0.05 e.u./mole

Similarly, for the vapor phase reaction, …

The Aging Of Sbr Vulcanizates, Arthur Robert Leckart

Theses

A literature survey was conducted on SBR aging, Being vulnerable to attack by the forces of nature (such as ozone, oxygen, heat and light), SBR vulcanizates requires the addition of chemicals to retard aging. Phenylamines were found to be the best type of antiaging additives, The effectiveness of other antiaging additives were examined. Although the mechanisms of aging are not perfectly understood; sane theories and aging reactions are discussed.

Continuous Crystallization Of High Explosives, Larry E. Hatler

Chemical and Biological Engineering ETDs

Nitroguanidine (NQ) is a high explosive which is commercially available in low bulk density form (0.20 to 0.30 gms/cm³). This low bulk density limits its usefulness as an explosive. High bulk density NQ can be produced from a NQ-N, N-dime-thylformamide-Versamid 125 system when crystallized in a mixed suspension mixed product removal crystallizer. Bulk densities ranged from 0.92 to 1.05 gms/cm³ for the operating conditions used. The effect of agitator speed, growth rate, and solids concentration on nucleation rates was determined using a multiple linear regression technique. The resulting equation is: B₀ = 0.19 (RPM) ^1.54 (G) …

Dispersion In Laminiar Flow Of Non-Newtonian Fluids, Subhash N. Shah

Chemical and Biological Engineering ETDs

In the present investigation, Taylor's analysis of the dispersion of solutes in laminar flow of a Newtonian fluid through a circular tube was extended to the case of a non-Newtonian Eyring model fluid. A new approach was taken to solve the convective diffusion equation for the Eyring model fluid. This approach incorporates the use of the dimensionless longitudinal pressure gradient and the mean velocity to obtain the dimensionless concentration. Using an approach similar to that of Taylor, a solution of the diffusion equation was obtained for quantities such as the dimensionless concentration, mean concentration, and effective dispersion coefficient as a …

Structure And Magnetic Properties Of Rare Earth Garnets, Milan R. Kokta

Dissertations

This study deals with preparation and magnetic properties of garnet compounds containing rare earth ions and scandium ions on two crystallographic sites: the dodecahedral and the octahedral. A number of compounds of the types {R_3-yr_y}[r_x Ga_2-x](Ga₃) O_12' {R₃}[Sc₂](Fe_z Ga_3-x) O_12' {R_3-y Sc_y}[Sc₂] (Fe₃) O_12' and {R_3-y r_y)[r₂ (Fe_z Ga_3-z) O_12' where R stands for large rare earth ions such as Nd³⁺ and Pr³⁺, …

Computer Simulation Of A Linde "Double Column", John A. Bazan

Theses

The purpose of this thesis is to develop a Fortran Computer Program to simulate the operation of a Linde "Double Column" for the separation of air into oxygen and nitrogen. The model outputs the number of contact stages required, the reflux ratio, the heat loads (condenser and reboiler, and the five profiles of temperature, pressure, vapor flow rate, liquid flow rate, and light component composition. From this data, the proposed design can be evaluated, and the effect of varying operating conditions explored.

A Solid State Kinetic Study Of Potassium Permanganate In Alkali Halide Disks, Joseph Paul Cusumano

Theses

The stoichiometry and the kinetics of the reactions of KMnO₄ in KCl and KIO₄ in KCl were studied. The kinetics of the reactions were studied at three different temperatures to obtain the thermodynamic parameters. In addition, these reactions were studied in KBr and RbI matrices. The data was obtained using infrared spectrophotometer measurements.

The reactions all appeared to be first order with respect to the permanganate ion. The stoichiometric studies indicate that the Mn₄^- is converted to Mn⁺⁺ and the Mn⁺⁺ ion apparently catalyzes the reduction of KI₄. The results indicate the …

Separations Via Semicontinuous Parametric Pumping, Edward H. Reiss

Theses

A semicontinuous parametric pump with batch operation during one half-cycle and continuous operation in the other half-cycle was experimentally investigated in the model system, toluene-n-heptane on silica gel adsorbent. Comparison was made with analytical results obtained by the equilibrium theory. It was shown that when the penetration distance for the cold cycle was less than or equal to that of the hot cycle and the height of the column, the rate of production of pure solvent in the semicontinuous pump may become quite large relative to that in the continuous pump.

Predictions Of Catalyst Utilization With Continuous Replacement In Multistage Continuous Reactors From Batch Reactor Data, Norman M. Feinberg

Theses

This thesis presents a new equation for predicting catalyst utilization with continuous replacement in multistage continuous reactors from batch reactor data.

An equation is derived from experimental data for a. no-replacement system which predicts catalyst activity as a function of time. The assumption of constant inventory, constant replacement rate and perfect mixing permit the calculation of catalyst age distribution. By combining age distribution with a measure of catalyst productivity, as determined from activity as a function of time, an equation for catalyst utilization was derived. The case used to prepare this equation was where the activity decline curve appears as …

Computerized Computation Of Counter-Current Extraction Problems For Ternary Liquid Systems, Albert Warren Patterson

Theses

A Fortran computer program has been developed that will calculate the number of theoretical equilibrium stages required for a countercurrent liquid-liquid extraction design problem. It also furnishes a complete stagewise material balance. Further utility can be found by using it for optimization studies. The program can be utilized for three-component systems that form one pair of partially miscible liquids, the most frequently occuring situation. The program was written for the General Electric Mark I Time-Sharing System.

The program has a practical advantage in that isothermal liquid equilibria data are used directly for calculation purposes. No use is made of theoretically …

Analysis Of Decomposition Gases And Leach Water From Controlled Sanitary Landfill, Robert Gargano

Theses

A sanitary landfill was simulated by placing "refuse" between two layers of soil in 6" by 24" cylinders. Canine nutriment was used to simulate the refuse. Once the refuse began to decompose, the decomposition gases were collected in a gas cell and analyzed in an Infrared Spectrophotometer. When gas samples were not taken, the decomposition gases were vented through a water trap (to prevent air from backing up into the system) into the atmosphere. Distilled water was added and withdrawn at two week intervals to leach out the pollutants.

From the Infrared analysis, the decomposition gases were determined to be …

The Effect Of Ultrasonic Vibration On Mass Transfer In A Packed Column, Joseph Walter Stanecki

Theses

The object of this research was to investigate the possibility of using externally supplied ultrasonic vibration to surface of a packed distillation column operating at total reflux to improve the separation. The apparatus used for this experimentation consisted of a 2 inch ID Pyrex column having three pairs of ultrasonic transducers epoxied equidistance along the external surface of the column. Each pair of transducers was driven separately by a 50 watt amplifier! power supply and a sine/square wave generator.

There were three types of binary mixtures covered during experimentation: minimum boiling azeotropes, maximum boiling azeotropes and full range mixtures. In …

A Study Of The Optimization Of Ethylene Production In A Tubular Reactor, Richard W. J. Robertson

Theses

The pyrolysis of ethane is a complex reaction involving six individual reactions in a reactant mixture of thirteen components. It is further complicated by the deposition of carbon along the reactor walls. The carbon buildup eventually necessitates reactor shutdown, During the intermediate stages the reactor experiences a gradual increase in inlet pressure which affects the reaction conditions, Optimum temperature profiles exist because the yield goes up with increasing temperature, but, consequently, the reactor must be shut down and cleaned out with increasing frequency. The combined effect causes the yearly production of ethylene to go through an optimum.

To find this …

The Reaction Of P-Nitrophenyl Acetate With Lysine Hydrochloride And Poly-1-Lysine Hydrobromide, Emmanuel Plange Matteer

Theses

The reactions of p-nitrophenylacetate with L-lysine hydrochloride and poly-L-lysine hydrobromide as a function of pH were investigated.

The results indicate that both compounds react with the substrate in the pH range 7.0-10.0 with an apparent optimum pH in the region near 9.65.

Poly-L-lysine reacts more rapidly over the entire pH range investigated than does L-lysine.

A Study Of The Effect Of A Dielectric Field On The Solvolysis Rate Of Tert-Butyl Bromide In A Recycle Reactor, Rolf L. Ball

Theses

Previous experiments at Newark College of Engineering have shown that a dielectric field can effect the rate of a chemical reaction. A theory was developed in this thesis to postulate how a dielectric field can increase the rate of a first order reaction whose rate determining step is an ionization. An experimental procedure was developed to measure the reaction rate constant of a tertiary alkyl halide with a solvent to test this theory. The solvolysis of tortbutyl bromide in aqueous ethanol (80%), aqueous dioxane (75%) and aqueous acetone (75%) solvent systems were the reactions selected for study. A total of …

The Development Of Langmuir's Adsorption Isotherms For Glucose And Fructose And The Separation Via Continuous Parametric Pumping, Jafir Abbas Jaferi

Theses

The adsorption equilibria and adsorption rates of fructose and of glucose on aqueous suspensions of fullers earth were determined at various temperatures. The Langmuir adsorption equations were fitted to the equilibrium data and the Langmuir constants were determined so that isotherms could be developed for any pair of parametric pumping operating temperatures.

This glucose+fructose+water system was then subjected to continuous thermal parametric pumping for the separation of glucose and fructose. The operating conditions required for the separation were determined from the experimental adsorption rates and equilibrium isotherms. Samples taken from the continuous top and bottom streams were analyzed by polarimetry …

Studies Of Rare Earth Compounds, Rostam Mondegarian

Theses

The work reported herein has consisted of miscellaneous studies of rare earth compounds.

1. The Pr—As system was studied with a view to obtaining a ferromagnetic composition.
2. Attempts were made to prepare ternary compounds by solid state reaction of PrAs, GdAs or YbAs with MnAs, CrAs or FeAs, and PrP, GdP, or YbP with MnP, CrP or FeP.
3. Attempts were made to prepare quaternary compounds by solid state reaction of YbAs, YbP and GdAs with CdI2 in various molar ratios. In many cases new compouns appeared to be formed but because of complexity of the X—ray patterns it was not possible …

Equilibrium Calculations Via The Benedict-Webb-Rubin Equation Of State, Steven L. Sincoff

Theses

The performance of various vapor-liquid equilibrium calculations requires phase equilibrium data. One of the most versatile sources of this data is an equation of state, re-lating the pressure, temperature, and phase compositions it a single expression. The equation under study herewith is the eight constant Benedict-Webb-Rubin Equation of State.

This paper provides a computer program which evaluates the following types of phase equilibria: bubble-points, dew-points, and two phase flash calculations. Also included in this paper is the theoretical backround of the Benedict-Webb-Rubin Equation of State, calculational techniques, and the data used in the program.

Flow Behavior Of Molten Polymer Blends, Kryspin Pawel Maciejewski

Theses

An experimental study of molten polymer blends was made using the Instron Capillary Rheometer. The materials investigated were two phase blends of non-crystalline polymers (poIymethylmethacrystate-low Mw-polyvinylacetate, polyvinylacetate-polystyrene, polymethylmethacrylate-low Mw-polystyrene, polymethylmethacrylate-high Mw-polystyrene), crystalline polymers (polyethylene-polypropylene) and combinations of non-crystalline-crystalline polymers (polyethylene-polystyrene). Two methods of sample preparation were used, blending of a polymer pair in a molten state by the use of Brabender blender, and a simple manual blending of pellets in desired proportion. The Brabender blended polymer pairs show lower viscosities, this is interpreted molecularly as a result of a reduction of the amount of chain entanglement on shearing of the …

High Pressure Water Jet Cutting Of Rock, Richard Lee Henry

Masters Theses

"Three experiments are described that investigate the impingement of high pressure water jets on rock. The effect of jet pressure, stand-off distance, and time of impact on penetration and specific energy of rock removal are determined on Berea sandstone, Georgia marble, and Missouri granite. Pressures range from 5,000 psi to 25,000 psi, stand-off distances from 2.0 inches to 4.0 inches and time from 0.1 seconds to 5.0 seconds. The nozzle diameter used was 0.023 inches. The effect of nozzle speed and number of passes over the same area on depth of cut and specific energy are investigated on the above …

Preliminary Studies With A Variable Transfer Composite Polymer Membrane., Samuel Walter Dortch

Masters Theses

"A preliminary study was done to determine the feasibility of using a compressed fibrous teflon (PTFE) silicone polymer membrane in extracorporeal oxygenation devices. A series of composite membranes were fabricated, using different concentrations of a dimethyl silicone polymer dissolved in petroleum ether, to give membranes having variable oxygen transfer properties. A gas-gas system was chosen to obtain the necessary transfer data. Data were obtained by transferring pure oxygen through the membranes into a mixture of 47 mole percent oxygen and 53 mole percent carbon dioxide. All analyses were obtained by chromatographic techniques. The results of these experiments show that membranes …

Drag Reduction On Non-Ionic Surfactants In Aqueous Systems, Jen-Lin Chang

Masters Theses

"The use of polyoxyethylene alcohol non-ionic surfactants as drag reducing additives in aqueous systems was investigated. Significant drag reduction was obtained with suitable combinations of one percent Alfonic 1214 and salts at 30°C such that the surfactant was near or above its upper critical solubility temperature. Maximum drag reduction was observed at the cloud point. Relative viscosity values also peaked at this point. No upper critical shear stress was attained up to wall shear stresses of 2,000 dynes/cm² with one percent Alfonic 1214 solutions at their cloud points.

At a fixed temperature, the salt concentration required to reach the …

Mass Transfer With Second-Order Chemical Reaction Inside Circulating Fluid Droplets, Roy James Brunson

Doctoral Dissertations

"The solution of a mathematical model is presented which describes mass transfer accompanied by a second-order chemical reaction inside a circulating, fluid sphere for the laminar flow region. The values for eight different mass transfer indices are presented as a function of the Peclet number, reaction number, diffusivity ratio, concentration ratio, and the dimensionless contact time. The results of this work are compared with the film and penetration theories for mass transfer with reaction as modified to apply inside a fluid sphere. This work corrects the three factors which limit the accuracy of applying previous theories to fluid spheres: geometrical …

A Study Of Three Methods Which Solve A Suboptimum Control Problem On An Iterative Analog Computer, Joseph Camp Finney

Masters Theses

"Three methods for optimizing a proportional and a proportional-integral controller parameter problem were investigated on an iterative analog computer. The three methods were the parameter-perturbation correlation method, the absolute biasing method, and the variable step size method. The process controlled was third order linear. The performance function used to judge the quality of the controller was the time integral of the absolute value of error. All three methods required a trial and error adjustment of the parameters used in these methods. The optimum solution was obtained by all methods. The absolute biasing method, for both the proportional and the proportional-integral …

Synthesis And Characterization Of Poly-(P-Phenylene Pyromellitamic Acid), Constantine William Tsimpris

Doctoral Dissertations

"Poly-(p-phenylenepyromellitamic acid)s have been synthesized over the weight average molecular weight range from 8,000 to 22,000 by reaction of pyromellitic dianhydride and p-phenylenediamine in dimethylformamide. The polymers were recovered as amorphous yellow powders having planar dimensions of 3-4 x 1-2 µm with thicknesses of 0.1-0.2 µm and contained 20-30% associated dimethylformamide. Consumption of reactants and attainment of the ultimate molecular weight of the polymer was found to occur within one minute. Thermogravimetry of the solid poly(amic acid)s was used in a method developed to determine the amount of associated dimethylformamide, to study the cyclization of poly(amic acid) to polyimide, and …

The Electrochemical Reduction Of Fumaric Acid On Hg-Bi Cathodes, Chen Hwei Chi

Doctoral Dissertations

"The electrochemical reduction of fumaric acid was studied on Hg, Hg/1%Bi amalgam, and Bi at 60ºC in acidic solutions of various pH ranging from 0.3 to 3.7. The fumaric acid was reduced to succinic acid with high efficiency on each electrode. The steady state kinetic parameters included Tafel slopes of ca. 2.3 RT/F and first order concentration dependences for both undissociated fumaric acid and H⁺. Transient measurements indicated low coverages of adsorbed fumaric acid and no adsorbed hydrogen species in the potential region of the reaction. A reaction mechanism is proposed which involves a chemical rate determining step between an …