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Full-Text Articles in Chemical Engineering

A Computational Investigation Of The Interstitial Oxidation Thermodynamics Of A Mo-Nb-Ta-W High Entropy Alloy Beyond The Dilute Regime, Adib J. Samin Dec 2020

A Computational Investigation Of The Interstitial Oxidation Thermodynamics Of A Mo-Nb-Ta-W High Entropy Alloy Beyond The Dilute Regime, Adib J. Samin

Faculty Publications

High entropy alloys (HEAs) are promising candidates for high-temperature structural material applications. Oxidation is a major factor that must be accounted for when designing such materials and it is thus important to study the oxidation behavior of HEAs to enable the optimum design of next generation materials. In this study, the thermodynamic behavior of interstitial oxygen in a Mo-Nb-Ta-W high entropy alloy was explored beyond the dilute limit. This was accomplished by sampling configurations of the HEA and HEA-oxygen systems from an isothermal–isobaric ensemble using a series of first-principle-based Monte Carlo simulations. It was found that the interstitial oxygen had …


Noise And Detectivity Limits In Organic Shortwave Infrared Photodiodes With Low Disorder, Zhenghui Wu, Ning Li, Naresh Eedugurala, Jason D. Azoulay, Dong Seok Leem, Tse Nga Ng Dec 2020

Noise And Detectivity Limits In Organic Shortwave Infrared Photodiodes With Low Disorder, Zhenghui Wu, Ning Li, Naresh Eedugurala, Jason D. Azoulay, Dong Seok Leem, Tse Nga Ng

Faculty Publications

© 2020, The Author(s). To achieve high detectivity in infrared detectors, it is critical to reduce the device noise. However, for non-crystalline semiconductors, an essential framework is missing to understand and predict the effects of disorder on the dark current. This report presents experimental and modeling studies on the noise current in exemplar organic bulk heterojunction photodiodes, with 10 donor–acceptor combinations spanning wavelength between 800 and 1600 nm. A significant reduction of the noise and higher detectivity were found in devices using non-fullerene acceptors (NFAs) in comparison to those using fullerene derivatives. The low noise in NFA blends was attributed …


Swarm-Based Design Of Proportional Integral And Derivative Controllers Using A Compromise Cost Function: An Arduino Temperature Laboratory Case Study, Paulo De Moura Oliveira, John Hedengren, Eduardo Solteiro Pires Nov 2020

Swarm-Based Design Of Proportional Integral And Derivative Controllers Using A Compromise Cost Function: An Arduino Temperature Laboratory Case Study, Paulo De Moura Oliveira, John Hedengren, Eduardo Solteiro Pires

Faculty Publications

Simple and easy to use methods are of great practical demand in the design of Proportional, Integral, and Derivative (PID) controllers. Controller design criteria are to achieve a good set-point tracking and disturbance rejection with minimal actuator variation. Achieving satisfactory trade-offs between these performance criteria is not easily accomplished with classical tuning methods. A particle swarm optimization technique is proposed to design PID controllers. The design method minimizes a compromise cost function based on both the integral absolute error and control signal total variation criteria. The proposed technique is tested on an Arduino-based Temperature Control Laboratory (TCLab) and compared with …


Using Reactive Dissipative Particle Dynamics To Understand Local Shape Manipulation Of Polymer Vesicles, Qinyu Zhu, Timothy R. Scott, Douglas R. Tree Oct 2020

Using Reactive Dissipative Particle Dynamics To Understand Local Shape Manipulation Of Polymer Vesicles, Qinyu Zhu, Timothy R. Scott, Douglas R. Tree

Faculty Publications

Biological cells have long been of interest to researchers due to their capacity to actively control their shape. Accordingly, there is significant interest in generating simplified synthetic protocells that can alter their shape based on an externally or internally generated stimulus. To date, most progress has been made towards controlling the global shape of a protocell, whereas less is known about generating a local shape change. Here, we seek to better understand the possible mechanisms for producing local morphological changes in a popular protocell system, the block copolymer vesicle. Accordingly, we have combined Dissipative Particle Dynamics (DPD) and the Split …


Mechanisms Of Asymmetric Membrane Formation In Nonsolvent-Induced Phase Separation, Jan Ulric Garcia, Tatsuhiro Iwama, Eva Y. Chan, Douglas R. Tree, Kris T. Delaney, Glenn H. Fredrickson Oct 2020

Mechanisms Of Asymmetric Membrane Formation In Nonsolvent-Induced Phase Separation, Jan Ulric Garcia, Tatsuhiro Iwama, Eva Y. Chan, Douglas R. Tree, Kris T. Delaney, Glenn H. Fredrickson

Faculty Publications

We report the first simulations of nonsolvent-induced phase separation (NIPS) that predict membrane microstructures with graded asymmetric pore size distribution. In NIPS, a polymer solution film is immersed in a nonsolvent bath, enriching the film in nonsolvent, and leading to phase separation that forms a solid polymer-rich membrane matrix and polymer-poor membrane pores. We demonstrate how mass-transfer-induced spinodal decomposition, thermal fluctuations, and glass-transition dynamics—implemented with mobility contrast between the polymer-rich and polymer-poor phases—are essential to the formation of asymmetric membrane microstructures. Specifically, we show that the competition between the propagation of the phase-separation and glass-transition fronts determines the degree of …


Bio-Oils From Vacuum Ablative Pyrolysis Of Torrefied Tobacco Residues, Nattawut Khuenkaeo, Blake Macqueen, Thossaporn Onsree, Sangu Daiya, Nakorn Tippayawong, Jochen A. Lauterbach Sep 2020

Bio-Oils From Vacuum Ablative Pyrolysis Of Torrefied Tobacco Residues, Nattawut Khuenkaeo, Blake Macqueen, Thossaporn Onsree, Sangu Daiya, Nakorn Tippayawong, Jochen A. Lauterbach

Faculty Publications

Fast pyrolysis, in combination with torrefaction pretreatment, was used to convert tobacco residues to value-added bio-fuels and chemicals. Tobacco plant residues were torrefied at 220, 260, and 300 °C, before being pyrolyzed at 450, 500, 550, and 600 °C in a rotating blade ablative reactor under vacuum conditions to test the effects on product yields. With torrefaction, tobacco residues thermally decomposed 20-25% w/w at low temperatures. Torrefaction and pyrolysis temperatures were found to markedly affect pyrolytic product yields of bio-chars and bio-oils, while having no effect on gas-phase products. Bio-oil yields exhibited a direct relation with pyrolysis temperature and an …


Bio-Oils From Vacuum Ablative Pyrolysis Of Torrefied Tobacco Residues, Nattawut Khuenkaeo, Blake Macqueen, Thossaporn Onsree, Sangu Daiya, Nakorn Tippayawong, Jochen A. Lauterbach Sep 2020

Bio-Oils From Vacuum Ablative Pyrolysis Of Torrefied Tobacco Residues, Nattawut Khuenkaeo, Blake Macqueen, Thossaporn Onsree, Sangu Daiya, Nakorn Tippayawong, Jochen A. Lauterbach

Faculty Publications

Fast pyrolysis, in combination with torrefaction pretreatment, was used to convert tobacco residues to value-added bio-fuels and chemicals. Tobacco plant residues were torrefied at 220, 260, and 300 °C, before being pyrolyzed at 450, 500, 550, and 600 °C in a rotating blade ablative reactor under vacuum conditions to test the effects on product yields. With torrefaction, tobacco residues thermally decomposed 20-25% w/w at low temperatures. Torrefaction and pyrolysis temperatures were found to markedly affect pyrolytic product yields of bio-chars and bio-oils, while having no effect on gas-phase products. Bio-oil yields exhibited a direct relation with pyrolysis temperature and an …


Challenges To Levulinic Acid And Humins Valuation In The Sugarcane Bagasse Biorefinery Concept, Emília Savioli Lopes, Jean Felipe Leal Silva, Elmer Ccopa Rivera, Alana Petrina Gomes, Melina Savioli Lopes, Rubens Maciel Filho, Laura Plazas Tovar Sep 2020

Challenges To Levulinic Acid And Humins Valuation In The Sugarcane Bagasse Biorefinery Concept, Emília Savioli Lopes, Jean Felipe Leal Silva, Elmer Ccopa Rivera, Alana Petrina Gomes, Melina Savioli Lopes, Rubens Maciel Filho, Laura Plazas Tovar

Faculty Publications

© 2020, Springer Science+Business Media, LLC, part of Springer Nature. Levulinic acid (LA) is currently one of the most promising chemicals derived from biomass. However, its large-scale production is hampered by the challenges in biomass hydrolysis and the poor selectivity due to the formation of humins (HUs). This study addresses these challenges using the biorefinery concept of biomass fractionation. A three-step process (pretreatment, delignification, and acid-catalyzed conversion) was optimized to produce LA from SCB considering the yield (YLA), efficiency (ELA), and concentration of LA (CLA) as functions of temperature, reaction time, acid concentration, and solids loading. By means of a …


A Review Of Coal Heating Value Correlations With Application To Coal Char, Tar, And Other Fuels, Andrew P. Richards, Denver Haycock, Jacob F. Frandsen, Thomas H. Fletcher Aug 2020

A Review Of Coal Heating Value Correlations With Application To Coal Char, Tar, And Other Fuels, Andrew P. Richards, Denver Haycock, Jacob F. Frandsen, Thomas H. Fletcher

Faculty Publications

Accurately measuring a fuel’s heating value is one of the first steps in the classification of a new fuel. Heating values are widely used in coal combustion research and are becoming more useful in other fuel types as well. Many different empirical correlations to predict heating values based on primary organic (CHONS) elemental composition are found in the literature, many of which were originally created to predict heating values of parent coal, and some of which have been extended for biomass. However, no correlations exist for heating values of coal chars and tars. Thirteen literature heating value correlations (10 model …


Air Quality Improvement During Triple-Lockdown In The Coastal City Of Kannur, Kerala To Combat Covid-19 Transmission, C. T. Resmi, T. Nishanth, M. K. Satheesh Kumar, M. G. Manoj, M. Balachandramohan, K. T. Valsaraj Jul 2020

Air Quality Improvement During Triple-Lockdown In The Coastal City Of Kannur, Kerala To Combat Covid-19 Transmission, C. T. Resmi, T. Nishanth, M. K. Satheesh Kumar, M. G. Manoj, M. Balachandramohan, K. T. Valsaraj

Faculty Publications

The novel SARS-CoV-2 coronavirus that emerged in the city of Wuhan, China, last year has since become the COVID-19 pandemic across all continents. To restrict the spread of the virus pandemic, the Government of India imposed a lockdown from 25 March 2020. In India, Kannur district was identified as the first "hotspot" of virus transmission and a "triple-lockdown" was implemented for a span of twenty days from 20 April 2020. This article highlights the variations of surface O-3, NO, NO2, CO, SO2, NH3, VOC's, PM10, PM2.5 and meteorological parameters at the time of pre-lockdown, lockdown and triple-lockdown days at Kannur …


Survey Of 8 Uav Set-Covering Algorithms For Terrain Photogrammetry, Joshua Hammond, Cory Vernon, Trent Okeson, Benjamin Barrett, Samuel Arce, Valerie Newell, Joseph Janson, Kevin Franke, John Hedengren Jul 2020

Survey Of 8 Uav Set-Covering Algorithms For Terrain Photogrammetry, Joshua Hammond, Cory Vernon, Trent Okeson, Benjamin Barrett, Samuel Arce, Valerie Newell, Joseph Janson, Kevin Franke, John Hedengren

Faculty Publications

Remote sensing with unmanned aerial vehicles (UAVs) facilitates photogrammetry for environmental and infrastructural monitoring. Models are created with less computational cost by reducing the number of photos required. Optimal camera locations for reducing the number of photos needed for structure-from-motion (SfM) are determined through eight mathematical set-covering algorithms as constrained by solve time. The algorithms examined are: traditional greedy, reverse greedy, carousel greedy (CG), linear programming, particle swarm optimization, simulated annealing, genetic, and ant colony optimization. Coverage and solve time are investigated for these algorithms. CG is the best method for choosing optimal camera locations as it balances number of …


Automated 3d Reconstruction Using Optimized View-Planning Algorithms For Iterative Development Of Structure-From-Motion Models, Samuel Arce, Cory Vernon, Joshua Hammond, Valerie Newell, Joseph Janson, Kevin Franke, John Hedengren Jul 2020

Automated 3d Reconstruction Using Optimized View-Planning Algorithms For Iterative Development Of Structure-From-Motion Models, Samuel Arce, Cory Vernon, Joshua Hammond, Valerie Newell, Joseph Janson, Kevin Franke, John Hedengren

Faculty Publications

Unsupervised machine learning algorithms (clustering, genetic, and principal component analysis) automate Unmanned Aerial Vehicle (UAV) missions as well as the creation and refinement of iterative 3D photogrammetric models with a next best view (NBV) approach. The novel approach uses Structure-from-Motion (SfM) to achieve convergence to a specified orthomosaic resolution by identifying edges in the point cloud and planning cameras that “view” the holes identified by edges without requiring an initial model. This iterative UAV photogrammetric method successfully runs in various Microsoft AirSim environments. Simulated ground sampling distance (GSD) of models reaches as low as 3.4 cm per pixel, and generally, …


Effects Of Temperature And Antioxidants On The Oxidation Of Biodiesel Derived From Waste Vegetable Oil, Randy L. Maglinao, Torrey J. Wagner, Keegan Duff Jun 2020

Effects Of Temperature And Antioxidants On The Oxidation Of Biodiesel Derived From Waste Vegetable Oil, Randy L. Maglinao, Torrey J. Wagner, Keegan Duff

Faculty Publications

Biodiesel offers several environmental benefits and improvements to some fuel performance properties, but its poor oxidative stability has been a major concern. Currently, the accepted practice to improve biodiesel oxidative stability is the addition of antioxidants; numerous antioxidants have been studied but their effectiveness in inhibiting biodiesel oxidation is difficult to predict due to variation with resonance stability, solubility, reactivity, and volatility. To improve prediction efforts, this study explored the Rapid Small-Scale Oxidation Test (RSSOT) as a means to investigate how biodiesel oxidation is affected by antioxidant concentration and temperature, and compared its results with the oxidative stability index test. …


Model Predictive Control And Estimation Of Managed Pressure Drilling Using A Real-Time High Fidelity Flow Model, Junho Park, Cameron Price, David Pixton, Manuel Aghito, Roar Nybø, Knut Bjørkevoll, John Hedengren May 2020

Model Predictive Control And Estimation Of Managed Pressure Drilling Using A Real-Time High Fidelity Flow Model, Junho Park, Cameron Price, David Pixton, Manuel Aghito, Roar Nybø, Knut Bjørkevoll, John Hedengren

Faculty Publications

When drilling an oil or gas well, well pressures may be controlled using a technology called managed pressure drilling. This technology often relies on model predictive control schemes; however, practical limitations have generally led to the use of simplified controller models that do not optimally handle certain perturbations in the physical system. The present work reports on the first implementation of a highly accurate system model that has been adapted for real-time use in a controller. This real-time high-fidelity model approximates the results of offline high-fidelity models without requiring operation by model experts. The effectiveness of the model is demonstrated …


Kinetic Insights Into The Lignocellulosic Biomass-Based Levulinic Acid Production By A Mechanistic Model, Emília Savioli Lopes, Elmer Ccopa Rivera, Julio César De Jesus Gariboti, Luis Henrique Zimmermann Feistel, João Vitor Dutra, Rubens Maciel Filho, Laura Plazas Tovar May 2020

Kinetic Insights Into The Lignocellulosic Biomass-Based Levulinic Acid Production By A Mechanistic Model, Emília Savioli Lopes, Elmer Ccopa Rivera, Julio César De Jesus Gariboti, Luis Henrique Zimmermann Feistel, João Vitor Dutra, Rubens Maciel Filho, Laura Plazas Tovar

Faculty Publications

© 2020, Springer Nature B.V. Abstract: In this work, a mechanistic model was developed to simulate the kinetics of the production of levulinic acid (LA) from sugarcane bagasse (SCB), rice husk (RH) and soybean straw (SS). The production of LA from those agro-industrial wastes followed the methodology of biorefining in three stages. Experimental data from the third stage (catalytic depolymerization of cellulose) obtained under a wide range of operating conditions were used to estimate the parameters of the model. An optimization procedure based on a genetic algorithm was used to determine the optimal parameter values. The prediction of the concentrations …


Chemical And Thermal Sintering Of Supported Metals With Emphasis On Cobalt Catalysts During Fischer−Tropsch Synthesis, Mahmood Rahmati, Mohammad-Saeed Safdari, Thomas H. Fletcher, Morris D. Argyle, Calvin H. Bartholomew May 2020

Chemical And Thermal Sintering Of Supported Metals With Emphasis On Cobalt Catalysts During Fischer−Tropsch Synthesis, Mahmood Rahmati, Mohammad-Saeed Safdari, Thomas H. Fletcher, Morris D. Argyle, Calvin H. Bartholomew

Faculty Publications

This comprehensive critical review combines, for the first time, recent advances in nanoscale surface chemistry, surface science, DFT, adsorption calorimetry, and in situ XRD and TEM to provide new insights into catalyst sintering. This work provides qualitative and quantitative estimates of the extent and rate of sintering as functions of nanocrystal (NC) size, temperature, and atmosphere. This review is unique in that besides summarizing important, useful data from previous studies, it also advances the field through addition of (i) improved or new models, (ii) new data summarized in original tables and figures, and (iii) new fundamental perspectives into sintering of …


Material Discovery And High Throughput Exploration Of Ru Based Catalysts For Low Temperature Ammonia Decomposition, Katherine Mccullough, Pei-Hua Chiang, Juan D. Jimenez, Jochen A. Lauterbach Apr 2020

Material Discovery And High Throughput Exploration Of Ru Based Catalysts For Low Temperature Ammonia Decomposition, Katherine Mccullough, Pei-Hua Chiang, Juan D. Jimenez, Jochen A. Lauterbach

Faculty Publications

High throughput experimentation has the capability to generate massive, multidimensional datasets, allowing for the discovery of novel catalytic materials. Here, we show the synthesis and catalytic screening of over 100 unique Ru-Metal-K based bimetallic catalysts for low temperature ammonia decomposition, with a Ru loading between 1–3 wt% Ru and a fixed K loading of 12 wt% K, supported on γ-Al2O3. Bimetallic catalysts containing Sc, Sr, Hf, Y, Mg, Zr, Ta, or Ca in addition to Ru were found to have excellent ammonia decomposition activity when compared to state-of-the-art catalysts in literature. Furthermore, the Ru content could be reduced to 1 …


Benchmark Temperature Microcontroller For Process Dynamics And Control, Junho Park, Ronald Abraham Martin, Jeffrey Kelly, John Hedengren Apr 2020

Benchmark Temperature Microcontroller For Process Dynamics And Control, Junho Park, Ronald Abraham Martin, Jeffrey Kelly, John Hedengren

Faculty Publications

Standard benchmarks are important repositories to establish comparisons between competing model and control methods, especially when a new method is proposed. This paper presents details of an Arduino micro-controller temperature control lab as a benchmark for modeling and control methods. As opposed to simulation studies, a physical benchmark considers real process characteristics such as the requirement to meet a cycle time, discrete sampling intervals, communication overhead with the process, and model mismatch. An example case study of the benchmark is quantifying an optimization approach for a PID controller with 5.4% improved performance. A multivariate example shows the quantified performance improvement …


Catalysts For Polymer Membrane Fuel Cells, William E. Mustain, Bryan Pivovar Jan 2020

Catalysts For Polymer Membrane Fuel Cells, William E. Mustain, Bryan Pivovar

Faculty Publications

No abstract provided.


Carbon-Based Artificial Sei Layers For Aqueous Lithium-Ion Battery Anodes, Usha Subramanya, Charleston Chua, Victor Gin He Leong, Ryan Robinson, Gwenlyn Cruz Cabiltes, Prakirti Singh, Bonnie Yip, Anuja Bokare, Folarin Erogbogbo, Dahyun Oh Jan 2020

Carbon-Based Artificial Sei Layers For Aqueous Lithium-Ion Battery Anodes, Usha Subramanya, Charleston Chua, Victor Gin He Leong, Ryan Robinson, Gwenlyn Cruz Cabiltes, Prakirti Singh, Bonnie Yip, Anuja Bokare, Folarin Erogbogbo, Dahyun Oh

Faculty Publications

Replacing flammable organic electrolytes with aqueous electrolytes in lithium-ion batteries (LIB) can greatly enhance the safety of next-generation energy storage systems. With the extended electrochemical stability window of electrolytes, 'water-in-salt' (WIS) electrolytes containing LIB presented significant performance improvements. However, the solubility limits of lithium salts in water restrain the extent of kinetic protection offered by the high salt concentration. Here, we report design strategies of anode structure to improve the cycle life of LIB with WIS electrolytes. We introduced partially graphitic protective carbon layers on anode particles using a versatile coating method. This protective layer not only improved charge transfer …


Comparison Of Pyrolysis Of Live Wildland Fuels Heated By Radiation Vs. Convection, Mohammad-Saeed Safdari, Elham Amini, David R. Weise, Thomas H. Fletcher Jan 2020

Comparison Of Pyrolysis Of Live Wildland Fuels Heated By Radiation Vs. Convection, Mohammad-Saeed Safdari, Elham Amini, David R. Weise, Thomas H. Fletcher

Faculty Publications

During wildland fires, which include both planned (prescribed fire) and unplanned (wildfire) fires, live and dead plants may be subject to both radiative and convective heat transfer mechanisms. In this study, the pyrolysis of 14 live plant species native to the forests of the southern United States was investigated using a flat-flame burner (FFB) apparatus under three heating modes in order to mimic pyrolysis of plants during wildland fires. The heating modes were: (1) radiation-only, where the plants were pyrolyzed under a moderate heating rate of 4 °C s−1 (radiative flux of 50 kW m−2); (2) convection-only, where the FFB …


Modeling The Influence Of Changes In Aliphatic Structure On Char Surface Area During Coal Pyrolysis, He Yang, Thomas H. Fletcher, Yang Li, Lijun Jin, Sufen Li, Yan Shang, Haoquan Hu Jan 2020

Modeling The Influence Of Changes In Aliphatic Structure On Char Surface Area During Coal Pyrolysis, He Yang, Thomas H. Fletcher, Yang Li, Lijun Jin, Sufen Li, Yan Shang, Haoquan Hu

Faculty Publications

The influence of changes in aliphatic structure on char surface area during coal pyrolysis was modeled, and the effect was introduced to a previous char surface area model for lignite pyrolysis established based on the chemical percolation devolatilization (CPD) model. The modified model can predict not only the N2 and CO2 char surface area during rapid pyrolysis of three lignites but also the CO2 char surface area of two high-volatile bituminous coals; the agreement of the modified model with experiments is improved at high temperatures. The decrease in aliphatic chain length can reduce adsorption positions around aromatic core, and decrease …


Chemical And Thermal Sintering Of Supported Metals With Emphasis On Cobalt Catalysts During Fischer−Tropsch Synthesis, Mahmood Rahmati, Mohammad-Saeed Safdari, Thomas H. Fletcher, Morris D. Argyle, Calvin H. Bartholomew Jan 2020

Chemical And Thermal Sintering Of Supported Metals With Emphasis On Cobalt Catalysts During Fischer−Tropsch Synthesis, Mahmood Rahmati, Mohammad-Saeed Safdari, Thomas H. Fletcher, Morris D. Argyle, Calvin H. Bartholomew

Faculty Publications

This comprehensive critical review combines, for the first time, recent advances in nanoscale surface chemistry, surface science, DFT, adsorption calorimetry, and in situ XRD and TEM to provide new insights into catalyst sintering. This work provides qualitative and quantitative estimates of the extent and rate of sintering as functions of nanocrystal (NC) size, temperature, and atmosphere. This review is unique in that besides summarizing important, useful data from previous studies, it also advances the field through addition of (i) improved or new models, (ii) new data summarized in original tables and figures, and (iii) new fundamental perspectives into sintering of …


Evaluation Of Nox‑Reduction Measures For Iron-Ore Rotary Kilns, Rikard Ekland, Thomas Allguren, Christian Fredriksson, Denver Haycock, Colson Johnson, Jacob Fransen, Thomas H. Fletcher, Klas Andersson Jan 2020

Evaluation Of Nox‑Reduction Measures For Iron-Ore Rotary Kilns, Rikard Ekland, Thomas Allguren, Christian Fredriksson, Denver Haycock, Colson Johnson, Jacob Fransen, Thomas H. Fletcher, Klas Andersson

Faculty Publications

The grate-kiln process is employed for sintering and oxidation of iron-ore pellets. In this process, a fuel (typically coal) is combusted with a large amount of excess air in a rotary kiln, and the high air-to-fuel ratio leads to significant NOx formation. The current Article is an assessment of NOx reduction measures that have been tested in pilot-scale and in full-scale by the Swedish iron-ore company Luossavaara-Kiirunavaara Aktiebolag (LKAB). The results show that the scaling between the full-scale kiln and the pilot-scale kiln is crucial, and several primary measures that reduce NOx significantly in pilot-scale achieve negligible reduction in full-scale. …


Homotopy Simulation Of Dissipative Micropolar Flow And Heat Transfer From A Two-Dimensional Body With Heat Sink Effect: Applications In Polymer Coating, O. A. Bég, B. Vasu, A. K. Ray, T. A. Beg, A. Kadir, H. J. Leonard, Rama S. R. Gorla Jan 2020

Homotopy Simulation Of Dissipative Micropolar Flow And Heat Transfer From A Two-Dimensional Body With Heat Sink Effect: Applications In Polymer Coating, O. A. Bég, B. Vasu, A. K. Ray, T. A. Beg, A. Kadir, H. J. Leonard, Rama S. R. Gorla

Faculty Publications

Non-Newtonian flow from a wedge constitutes a fundamental problem in chemical engineering systems and is relevant to processing of polymers, coating systems, etc. Motivated by such applications, the homotopy analysis method (HAM) was employed to obtain semi-analytical solutions for thermal convection boundary layer flow of incompressible micropolar fluid from a two-dimensional body (wedge). Viscous dissipation and heat sink effects were included. The non-dimensional boundary value problem emerges as a system of nonlinear coupled ordinary differential equations, by virtue of suitable coordinate transformations. The so-called Falkner-Skan flow cases are elaborated. Validation of the HAM solutions was achieved with earlier simpler models, …