Open Access. Powered by Scholars. Published by Universities.®
Articles 1 - 3 of 3
Full-Text Articles in Chemical Engineering
Chemical Structural Features Of Pyridine Extracts Of The Argonne Premium Coals Using 13c Nmr Spectroscopy, Thomas H. Fletcher, S Bai, Ronald J. Pugmire, Steven Wood, David M. Grant
Chemical Structural Features Of Pyridine Extracts Of The Argonne Premium Coals Using 13c Nmr Spectroscopy, Thomas H. Fletcher, S Bai, Ronald J. Pugmire, Steven Wood, David M. Grant
Faculty Publications
Soxhlet extractions were performed on the eight Argonne Premium coals using pyridine purged with argon and followed by a novel washing procedure to remove the pyridine. Mass closure (extracts plus residues) on duplicate experiments accounted for 94-96% of the original coal, repeatable to within 2%. Chemical structural features determined from 13C NMR analyses of the extracts and residues showed more attachments per aromatic cluster for the residues, indicating a greater degree of covalent bonding in the residue than in the extract. 1H NMR analysis of the extracts showed a gradual increase in the hydrogen aromaticity with rank, along …
An Overview Of Acerc Research In Fuel Characterization And Reaction Mechanisms, Ronald J. Pugmire, Thomas H. Fletcher
An Overview Of Acerc Research In Fuel Characterization And Reaction Mechanisms, Ronald J. Pugmire, Thomas H. Fletcher
Faculty Publications
A major objective of the Advanced Combustion Engineering Research Center is the development and verification of data on fuel characterization and reaction mechanisms and rates that can be incorporated into submodels for use in the comprehensive combustion codes. As technology has advanced, the levels of analytical sophistication has also advanced, making it possible to augment the existing body of information with new data. From this new data it is possible to draw new insights regarding the complex nature of coal and the various processes associated with combustion. The ACERC program has made it possible to bring different disciplines together to …
Progress In Coal Pyrolysis, Peter R. Solomon, Thomas H. Fletcher, Ronald J. Pugmire
Progress In Coal Pyrolysis, Peter R. Solomon, Thomas H. Fletcher, Ronald J. Pugmire
Faculty Publications
The heterogeneous nature of coal and the complexity of the pyrolysis process have made it very difficult to perform unambiguous experiments to determine the rates and mechanisms in coal pyrolysis. However, recent years have seen a number of new experimental and theoretical approaches which shed new light on the subject. This paper considers the recent progress on kinetics, the formation of volatile products, network models, cross-linking, rank effects, and the ‘two-component’ model of coal structure. Recent experiments which measured coal particle temperatures at high heating rates provide reasonable agreement on kinetic rate constants. These rates also agree with those derived …