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University of Kentucky

Theses/Dissertations

Photocatalysis

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Synthesis And Energy Applications Of Mesoporous Titania Thin Films, Syed Z. Islam Jan 2017

Synthesis And Energy Applications Of Mesoporous Titania Thin Films, Syed Z. Islam

Theses and Dissertations--Chemical and Materials Engineering

The optical and electronic properties of TiO2 thin films provide tremendous opportunities in several applications including photocatalysis, photovoltaics and photoconductors for energy production. Despite many attractive features of TiO2, critical challenges include the innate inability of TiO2 to absorb visible light and the fast recombination of photoexcited charge carriers. In this study, mesoporous TiO2 thin films are modified by doping using hydrogen and nitrogen, and sensitization using graphene quantum dot sensitization.

For all of these modifiers, well-ordered mesoporous titania films were synthesized by surfactant templated sol-gel process. Two methods: hydrazine and plasma treatments have been …