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Articles 1 - 8 of 8
Full-Text Articles in Chemical Engineering
Effect Of Pt Promotion On The Ni-Catalyzed Deoxygenation Of Tristearin To Fuel-Like Hydrocarbons, Ryan Loe, Kelsey Huff, Morgan Walli, Tonya Morgan, Dali Qian, Robert Pace, Yang Song, Mark Isaacs, Eduardo Santillan-Jimenez, Mark Crocker
Effect Of Pt Promotion On The Ni-Catalyzed Deoxygenation Of Tristearin To Fuel-Like Hydrocarbons, Ryan Loe, Kelsey Huff, Morgan Walli, Tonya Morgan, Dali Qian, Robert Pace, Yang Song, Mark Isaacs, Eduardo Santillan-Jimenez, Mark Crocker
Center for Applied Energy Research Faculty and Staff Publications
Pt represents an effective promoter of supported Ni catalysts in the transformation of tristearin to green diesel via decarbonylation/decarboxylation (deCOx), conversion increasing from 2% over 20% Ni/Al2O3 to 100% over 20% Ni-0.5% Pt/Al2O3 at 260 °C. Catalyst characterization reveals that the superior activity of Ni-Pt relative to Ni-only catalysts is not a result of Ni particle size effects or surface area differences, but rather stems from several other phenomena, including the improved reducibility of NiO when Pt is present. Indeed, the addition of a small amount of Pt to the supported Ni …
Continuous Catalytic Deoxygenation Of Waste Free Fatty Acid-Based Feeds To Fuel-Like Hydrocarbons Over A Supported Ni-Cu Catalyst, Ryan Loe, Yasmeen Lavoignat, Miranda Maier, Mohanad Abdallah, Tonya Morgan, Dali Qian, Robert Pace, Eduardo Santillan-Jimenez, Mark Crocker
Continuous Catalytic Deoxygenation Of Waste Free Fatty Acid-Based Feeds To Fuel-Like Hydrocarbons Over A Supported Ni-Cu Catalyst, Ryan Loe, Yasmeen Lavoignat, Miranda Maier, Mohanad Abdallah, Tonya Morgan, Dali Qian, Robert Pace, Eduardo Santillan-Jimenez, Mark Crocker
Center for Applied Energy Research Faculty and Staff Publications
While commercial hydrodeoxygenation (HDO) processes convert fats, oils, and grease (FOG) to fuel-like hydrocarbons, alternative processes based on decarboxylation/decarbonylation (deCOx) continue to attract interest. In this contribution, the activity of 20% Ni-5% Cu/Al2O3 in the deCOx of waste free fatty acid (FFA)-based feeds—including brown grease (BG) and an FFA feed obtained by steam stripping a biodiesel feedstock—was investigated, along with the structure-activity relationships responsible for Ni promotion by Cu and the structural evolution of catalysts during use and regeneration. In eight-hour experiments, near quantitative conversion of the aforementioned feeds to diesel-like hydrocarbons was achieved. …
Assembling Of Niox/Mwcnts-Gc Anodic Nanocatalyst For Water Electrolysis Applications, Islam M. Al-Akraa Dr., Yaser M. Asal Mr, Saher D. Khamis Eng
Assembling Of Niox/Mwcnts-Gc Anodic Nanocatalyst For Water Electrolysis Applications, Islam M. Al-Akraa Dr., Yaser M. Asal Mr, Saher D. Khamis Eng
Chemical Engineering
Glassy carbon (GC) electrode is intended to be modified with nickel oxide (NiOx) and multiwalled carbon nanotubes (MWCNTs) in the anodic reaction of water electrolysis. NiOx deposition time is optimized and a 5 min was enough to attain the maximum activity. A further modification of the catalyst with MWCNTs could greatly enhance its stability during continuous electrolysis. As an outcome, an energy amount of 21.7 kWh/KgO2 is minimized. Several electrochemical and materials characterization setups will be utilized to test the catalyst activity and to know its geometry and structure.
High-Throughput Screening Of Shape Memory Alloy Thin-Film Spreads Using Nanoindentation, Arpit Dwivedi, Thomas Wyrobek, Oden Warren, Jason Hattrick-Simpers, Olubenga Famodu, Ichiro Takeuchi
High-Throughput Screening Of Shape Memory Alloy Thin-Film Spreads Using Nanoindentation, Arpit Dwivedi, Thomas Wyrobek, Oden Warren, Jason Hattrick-Simpers, Olubenga Famodu, Ichiro Takeuchi
Jason R. Hattrick-Simpers
We have demonstrated the utility of nanoindentation as a rapid characterization tool for mapping shape memoryalloy compositions in combinatorial thin-film libraries. Nanoindentation was performed on Ni–Mn–Al ternary composition spreads. The indentation hardness and the reduced elastic modulus were mapped across a large fraction of the ternary phase diagram. The large shape memoryalloy composition region, located around the Heusler composition (Ni2MnAl), was found to display significant departure in these mechanical properties from the rest of the composition spread. In particular, the modulus and the hardness values are lower for the martensite region than those of the rest of the phase diagram.
Travelling In Cuba, Fathi Habashi
Travelling In Cuba, Fathi Habashi
Fathi Habashi
Contact with Cuban scientists was established in 1986 when two researchers from Centro de Investigaciones para Industria Minero Metalurgica in Havana visited Laval University to get acquainted with research activities in the area of extractive metallurgy. This was followed in early 1987 by two more researchers from the same centre. Invitations were then received in late 1987, 1989, and 2008 to visit the nickel refineries in Cuba and to hold seminars at the University of Havana. The present report outlines these activities.
High-Throughput Screening Of Shape Memory Alloy Thin-Film Spreads Using Nanoindentation, Arpit Dwivedi, Thomas J. Wyrobek, Oden L. Warren, Jason R. Hattrick-Simpers, Olubenga O. Famodu, Ichiro Takeuchi
High-Throughput Screening Of Shape Memory Alloy Thin-Film Spreads Using Nanoindentation, Arpit Dwivedi, Thomas J. Wyrobek, Oden L. Warren, Jason R. Hattrick-Simpers, Olubenga O. Famodu, Ichiro Takeuchi
Faculty Publications
We have demonstrated the utility of nanoindentation as a rapid characterization tool for mapping shape memoryalloy compositions in combinatorial thin-film libraries. Nanoindentation was performed on Ni–Mn–Al ternary composition spreads. The indentation hardness and the reduced elastic modulus were mapped across a large fraction of the ternary phase diagram. The large shape memoryalloy composition region, located around the Heusler composition (Ni2MnAl), was found to display significant departure in these mechanical properties from the rest of the composition spread. In particular, the modulus and the hardness values are lower for the martensite region than those of the rest of the …
Electrochemical Synthesis And Characterization Of The Nickel Electropolyurushiol Coordination Polymer, Feng Gao, Guo-Cai Shen, Jie-Yuan Tang, Wen-Gong Zhang
Electrochemical Synthesis And Characterization Of The Nickel Electropolyurushiol Coordination Polymer, Feng Gao, Guo-Cai Shen, Jie-Yuan Tang, Wen-Gong Zhang
Journal of Electrochemistry
The nickel electropolyurushiol coordination polymer(EPU Ni 2+ ) was obtained by the reaction between nickel chloride isopropyl alcohol solution with electropolyurushiol (EPU).The electrochemical polymerization of urushiol and the preparation of nickel electropolyurushiol coordination polymer were investigated.The coordination polymer was characterized by XPS,FT_IR,DMTA and AES methods,and its composition and structure were determined.The content of Ni 2+ reached up to 7.5%. It was shown that there was certain coordination between Ni 2+ and electropolyurushiol in the coordination polymer,thus cross_links were formed.Therefore the glass transition temperature of the coordination polymer increased and heat resistance was enhanced considerably.
Investigation Of A Complex Lithium Cobalt Nickel Oxide As Lithium Ion Battery Cathode Materials Prepared By A New Citrate Sol-Gel Method, Jing-Li Han, Qing Guo Liu
Investigation Of A Complex Lithium Cobalt Nickel Oxide As Lithium Ion Battery Cathode Materials Prepared By A New Citrate Sol-Gel Method, Jing-Li Han, Qing Guo Liu
Journal of Electrochemistry
The synthesis and electrochemical characteristics of lithium cobalt nickel oxide as cathode materials for rechargeable lithium batteries were investigated. It was clarified from these investigations that lithium cobalt nickel oxide has been produced from basic cobalt carbonate,basic nickel carbonate, lithium carbonate, and citrate. LiNi 0.8 Co 0.2 O 2 prepared under the stream of oxygen gas showed a higher cycling capacity of (～190 mAhg 1 ).