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Full-Text Articles in Chemical Engineering

Development Of Cementitious Materials For Adhesion Type Applications Comprising Calcium Sulfoaluminate (Csa) Cement And Latex Polymer, Joshua V. Brien Jan 2014

Development Of Cementitious Materials For Adhesion Type Applications Comprising Calcium Sulfoaluminate (Csa) Cement And Latex Polymer, Joshua V. Brien

Theses and Dissertations--Civil Engineering

The objective of this research was to develop high performing polymer modified calcium sulfoaluminate (CSA) cement materials for use in applications requiring superior adhesion characteristics. Little information is available describing interactions of CSA cement containing minor phase tri-calcium aluminate (C3A) with commonly used admixtures. Given the scarcity of information, a basic approach for developing cementitious materials was followed. The basic approach consisted of four tasks: cement design, admixture design, polymer design and testing developed materials. The iterative, time consuming process is necessary for understanding the influence of specific constituent components on overall system behavior. Results from the cement …


Thermo-Chemical Conversion Of Coal-Biomass Blends: Kinetics Modeling Of Pyrolysis, Moving Bed Gasification And Stable Carbon Isotope Analysis, Abhijit Bhagavatula Jan 2014

Thermo-Chemical Conversion Of Coal-Biomass Blends: Kinetics Modeling Of Pyrolysis, Moving Bed Gasification And Stable Carbon Isotope Analysis, Abhijit Bhagavatula

Theses and Dissertations--Chemical and Materials Engineering

The past few years have seen an upsurge in the use of renewable biomass as a source of energy due to growing concerns over greenhouse gas emissions caused by the combustion of fossil fuels and the need for energy independence due to depleting fossil fuel resources. Although coal will continue to be a major source of energy for many years, there is still great interest in replacing part of the coal used in energy generation with renewable biomass. Combustion converts inherent chemical energy of carbonaceous feedstock to only thermal energy. On the other hand, partial oxidation processes like gasification convert …


Generation Of Multicomponent Polymer Blend Microparticles Using Droplet Evaporation Technique And Modeling Evaporation Of Binary Droplet Containing Non-Volatile Solute, Venkat N. Rajagopalan Jan 2014

Generation Of Multicomponent Polymer Blend Microparticles Using Droplet Evaporation Technique And Modeling Evaporation Of Binary Droplet Containing Non-Volatile Solute, Venkat N. Rajagopalan

Theses and Dissertations--Chemical and Materials Engineering

Recently, considerable attention has been focused on the generation of nano- and micrometer scale multicomponent polymer particles with specifically tailored mechanical, electrical and optical properties. As only a few polymer-polymer pairs are miscible, the set of multicomponent polymer systems achievable by conventional methods, such as melt blending, is severely limited in property ranges. Therefore, researchers have been evaluating synthesis methods that can arbitrarily blend immiscible solvent pairs, thus expanding the range of properties that are practical. The generation of blended microparticles by evaporating a co-solvent from aerosol droplets containing two dissolved immiscible polymers in solution seems likely to exhibit a …


A Multidisciplinary Techno-Economic Decision Support Tool For Validating Long-Term Economic Viability Of Biorefining Processes, Sumesh Sukumara Jan 2014

A Multidisciplinary Techno-Economic Decision Support Tool For Validating Long-Term Economic Viability Of Biorefining Processes, Sumesh Sukumara

Theses and Dissertations--Chemical and Materials Engineering

Increasing demand for energy and transportation fuel has motivated researchers all around the world to explore alternatives for a long-term sustainable source of energy. Biomass is one such renewable resource that can be converted into various marketable products by the process of biorefining. Currently, research is taking strides in developing conversion techniques for producing biofuels from multiple bio-based feedstocks. However, the greatest concern with emerging processes is the long-term viability as a sustainable source of energy. Hence, a framework is required that can incorporate novel and existing processes to validate their economic, environmental and social potential in satisfying present energy …