Chemical Engineering Commons^™

Analysis Of The Effect Of Different Surface Preparation Methods On Corrosion Resistance And Adhesion Strength Of Astm A36 Steel Substrate With Surface Tolerant Epoxy Paint As Coating Material, Irwan Wijaya Santoso, Daffa Aqila, Rini Riastuti, Rizal Tresna Ramadhani

Journal of Materials Exploration and Findings

In the industrial world, to extend the service life of materials, protection methods are carried out to slow down the material's corrosion rate. The protection method that is often used is the coating method. The coating method is a protection method by coating the substrate material using a coating material to prevent contact between the substrate material and the environment. In this research, the substrate material used is ASTM A36 steel and the coating material used is Surface Tolerant Epoxy paint. The independent variable used in this study lies in the surface preparation method which consists of: solvent cleaning, hand …

An Overview Of How To Measure The Kinetic Properties Of An Anode Material For The Chlorine Evolution Reaction, Cameron Vann

Reviews, Analyses, and Instructional Studies in Electrochemistry (RAISE)

The process of generating chlorine gas using electrolysis in aqueous systems is well established. However, a new process requires chlorine to be generated at high temperatures using molten salt. This harsh environment requires a new study of anode materials for the chlorine evolution reaction. Anode materials can be compared by their kinetic parameters, the transfer coefficient α and the exchange current i0. The basic theory of these properties as they relate to the chlorine evolution reaction has been detailed and an analysis method for finding these effective parameters has been shown and demonstrated.

Review Of Cyclic Voltammetry Measurements For Uranium In Flinak Molten Salt, Jackson Ivory

Reviews, Analyses, and Instructional Studies in Electrochemistry (RAISE)

The electrochemical behavior of uranium FLiNaK molten salts is explored, focusing on cyclic voltammetry (CV) as a powerful tool for redox characterization and diffusion studies. Through a comprehensive review of recent research, the study highlights the significance of CV in understanding electrode kinetics, material compatibility, and process optimization in molten salt environments. The findings underscore the potential of FLiNaK molten salt reactors in advancing nuclear energy technologies, fuel processing, and waste management strategies. Collaborative interdisciplinary efforts are emphasized to address challenges and accelerate innovation in electrochemical methods for nuclear applications.

Study Of Reactive Distillation Equipment For Eterification Process, Abbos Elmanov, Abdulaziz Bakhtiyorov, Adham Norkobilov, Olimjon Maksudov, Zarif Oripov

CHEMISTRY AND CHEMICAL ENGINEERING

The purpose of this work is to study the chemical technological processes for eterification processes, and the reactive distillation unit, which carries out the reaction and separation process in one device, was chosen as the object of research. А reаctive distillаtion system is exаmined to produce for the production of Ethyl Acetate (EtAc) viа eterificаtion of acetic acid (HAc) with ethаnol. Optimizаtion methods using sensitivity analysis аre аlso conducted. Cаlculаtion of vаpor liquid equilibrium of the mixture system is done using UNIFАC model. Heat integration from the distillate stream of the column to the acid feed stream and from bottom …

Globular Protein For Surface Modification Of Cellulosecontaining Materials, Nodira Saydaliyeva

Technical science and innovation

The purpose of this work is the chemical modification of cotton fabrics with natural globular protein. Modification was carried out in the process of finishing cotton fabrics, after decoction and bleaching in a continuous mode. The effect of modification on the strength, protein content and functional groups of cotton fabric has been studied. According to the results obtained using the AUTOGRAPH AGS-N machine, it was found that the modification of cotton fabrics with a solution of globular protein increases the strength of the treated fabrics, depending on the concentration of the modifier and the temperature regime. Treatment with a highly …

Recent Advances In Solar Photo(Electro)Catalytic Nitrogen Fixation, Jun-Bo Ma, Sheng Lin, Zhiqun Lin, Lan Sun, Chang-Jian Lin

Journal of Electrochemistry

Ammonia (NH₃) is an essential chemical in modern society. It is currently produced in industry by the Haber-Bosch process using H₂ and N₂ as reactants in the presence of iron-based catalysts at high-temperature (400–600 ^oC) and extremely highpressure (20–40 MPa) conditions. However, its efficiency is limited to 10% to 15%. At the same time, a large amount of energy is consumed, and CO₂ emission is inevitably. The development of a sustainable, clean, and environmentally friendly energy system represents a key strategy to address energy crisis and environmental pollution, ultimately aiming to achieve carbon neutrality. …

The Top Ten Scientific Questions In Electrochemistry, Chinese Society Of Electrochemistry

Journal of Electrochemistry

No abstract provided.

Rational Design Of Heterostructured Nanomaterials For Accelerating Electrocatalytic Hydrogen Evolution Reaction Kinetics In Alkaline Media, Hai-Bin Ma, Xiao-Yan Zhou, Jia-Yi Li, Hong-Fei Cheng, Ji-Wei Ma

Journal of Electrochemistry

Owing to the merits of high energy density, as well as clean and sustainable properties, hydrogen has been deemed to be a prominent alternative energy to traditional fossil fuels. Electrocatalytic hydrogen evolution reaction (HER) has been considered to be mostly promising for achieving green hydrogen production, and has been widely studied in acidic and alkaline solutions. In particular, HER in alkaline media has high potential to achieve large-scale hydrogen production because of the increased durability of electrode materials. However, for the currently most prominent catalyst Pt, its HER kinetics in an alkaline solution is generally 2–3 orders lower than that …

Application Of Quantum Algorithms In The Synthesis Of Dynamic Objects, Noilakhon Yakubova

Chemical Technology, Control and Management

Around the world, the food industry is focusing on achieving energy and resource efficiency. One of the main challenges in the field of process automation is the creation of effective control systems using intelligent technologies to improve the quality of processes and achieve the production of high-quality products with less energy and resources. Therefore, it is necessary to work with a large amount of data. Particular attention is paid to the development of computational algorithms for automated high-speed computational analysis systems for processing this data at high speed. Therefore, the article discusses the use of quantum computing methods in controlling …

Reducing Food Scarcity: The Benefits Of Urban Farming, S.A. Claudell, Emilio Mejia

Journal of Nonprofit Innovation

Urban farming can enhance the lives of communities and help reduce food scarcity. This paper presents a conceptual prototype of an efficient urban farming community that can be scaled for a single apartment building or an entire community across all global geoeconomics regions, including densely populated cities and rural, developing towns and communities. When deployed in coordination with smart crop choices, local farm support, and efficient transportation then the result isn’t just sustainability, but also increasing fresh produce accessibility, optimizing nutritional value, eliminating the use of ‘forever chemicals’, reducing transportation costs, and fostering global environmental benefits.

Imagine Doris, who is …

An In-Situ Raman Spectroscopic Study On The Interfacial Process Of Carbonate-Based Electrolyte On Nanostructured Silver Electrode, Yu Gu, Yuan-Fei Hu, Wei-Wei Wang, En-Ming You, Shuai Tang, Jian-Jia Su, Jun Yi, Jia-Wei Yan, Zhong-Qun Tian, Bing-Wei Mao

Journal of Electrochemistry

The solid-electrolyte interphase (SEI) plays a key role in anodes for rechargeable lithium-based battery technologies. However, a thorough understanding in the mechanisms of SEI formation and evolution remains a major challenge, hindering the rapid development and wide applications of Li-based batteries. Here, we devise a borrowing surface-enhanced Raman scattering (SERS) activity strategy by utilizing a size optimized Ag nanosubstrate to in-situ monitor the formation and evolution of SEI, as well as its structure and chemistry in an ethylene carbonate-based electrolyte. To ensure a reliable in-situ SERS investigation, we designed a strict air-tight Raman cell with a three-electrode configuration. Based on …

Electrochemical Performance Of Porous Ceramic Supported Tubular Solid Oxide Electrolysis Cell, Heng-Ji Wang, Wen-Guo Chen, Zhou-Yi Quan, Kai Zhao, Yi-Fei Sun, Min Chen, Ogenko Volodymyr

Journal of Electrochemistry

Solid oxide electrolysis cell (SOEC) is an efficient and clean energy conversion technology that can utilize electricity obtained from renewable resources, such as solar, wind, and geothermal energy to electrolyze water and produce hydrogen. The conversion of abundant intermittent energy to hydrogen energy would facilitate the efficient utilization of energy resources. SOEC is an all-ceramic electrochemical cell that operates in the intermediate to high temperature range of 500–750 ℃. Compared with traditional low temperature electrolysis technology (e.g., alkaline or proton exchange membrane cells operating at ~100 ℃), the high-temperature SOEC can increase the electrolysis efficiency from 80% to ~100%, providing …

Combined Risk Based Inspection And Fault Tree Analysis For Repetitive 3-Phase Line Piping Leakage At West Java Offshore Topside Facility, Dona Yuliati, Akhmad Herman Yuwono, Datu Rizal Asral, Donanta Dhaneswara

Journal of Materials Exploration and Findings

Hydrocarbon releases might result in serious consequences in various aspects. In addition to the contribution to environmental pollution, repetitive leakages need high repair costs. This study aim is to minimize potential repetitive leakage for other typical 3-phase piping systems. We conducted the risk assessment by adopting Risk Based Inspection (RBI) API 581 to identify risk level, calculating piping lifetime, recommended inspection plan and mitigations. The most relevant root causes can be obtained through quantitative Fault Tree Analysis (FTA). Observation and investigation was taken from eight 3-phase piping systems that experienced repetitive leakages. It has been found that the risk level …

Nitrogen Gas Quenching Pressure Effect On Bs S155 Alloy Steel In Vacuum Furnace, Agus Mulyadi Hasanudin, Eddy Sumarno Siradj

Journal of Materials Exploration and Findings

The production of metal and alloy products requires the use of heat treatment, when during the heat treatment process, quenching is a crucial step. The quenching medium can be anything from water, a salt bath, oil, air and gas. In a vacuum furnace, pressurized gas, most frequently nitrogen (N₂) gas, serves as one of the quenching mediums. One of the drawbacks of the quenching process is the distortion and dimensional change of the parts. This paper aims to investigate the influence of nitrogen gas quenching pressure on the distortion and dimensional change of aerospace actuator gear planet parts …

Isolation And Characterization Of Caffeine-Degrading Bacteria From Coffee Plantation Areas In Malaysia, Elvina Clarie Dullah, Mohd Fazli Farida Asras

Makara Journal of Technology

Decaffeination by microbial degradation is currently the most optimal and low-cost approach, involving only microbial cells and/or their enzymes. The bacterium was characterized using a series of biochemical tests. Positive results were obtained from carbohydrate fermentation, citrate utilization, and catalase tests, while negative results were obtained from Voges-Proskauer (VP) and indole tests. Three different caffeine concentrations of 0.25%, 0.4%, and 2% were tested and measured through Gas Chromatography-Mass Spectrophotometry (GC-MS) analysis. The highest caffeine reduction (89.25%) was found when 0.25% caffeine was used in the media. Only a small amount of caffeine was reduced to 0.4% and 2%, with 34.78% …

Optimization Of The Building Envelope And Roof Shading To Reduce The Energy Consumption Of College Low-Rise Buildings In Indonesia, Nasruddin Nasruddin, Azimil Gani Alam, Mohammad Imroz Sohel

Makara Journal of Technology

Energy consumption in buildings is a crucial concern globally, prompting researchers to explore innovative solutions to mitigate its impact. This study investigates the optimization of building envelopes and roof shading systems of existing buildings in Indonesia to realize notable energy savings. Multiple scenarios were explored, with modifications to building envelopes and roof shading, highlighting the overall thermal transfer value as a key parameter. Using EnergyPlus simulations, the efficacy of natural ventilation in corridors and roof shading modifications was assessed in reducing energy consumption. The findings revealed that renovating existing buildings by optimization of the building envelope and roof shading by …

Constructing Carbon-Encapsulated Nifev-Based Electrocatalysts By Alkoxide-Based Self-Template Method For Oxygen Evolution Reaction, En-Hui Ma, Xu-Po Liu, Tao Shen, De-Li Wang

Journal of Electrochemistry

The development of green and sustainable water-splitting hydrogen production technology is beneficial to reducing the over-reliance on fossil fuels and realizing the strategic goal of "carbon neutral". As one of the half reactions for water splitting, oxygen evolution reaction has suffered the problems of sluggish four-electron transfer process and relatively slow reaction kinetics. Therefore, exploring efficient and stable catalysts for oxygen evolution reaction is of critical importance for water-splitting technology. Metal alkoxides are a series of compounds formed by the coordination function of metal ions with alcohol molecules. Metal alkoxides possess the double advantages of organic materials and inorganic materials, …

The Effects Of Engineering Summer Camps On Middle And High School Students’ Engineering Interest And Identity Formation: A Multi-Methods Study, Timothy Robinson, Adam Kirn, Jenny Amos, Indira Chatterjee

Journal of Pre-College Engineering Education Research (J-PEER)

This multi-methods study explores changes in engineering interest and identity of middle and high school students (n = 79) attending introductory-level engineering summer camps at a large western land grant university. Middle school is a critical time when student interest, identity, and subsequently career choice begin to emerge and hence it is important that at this age students are given accurate information about engineering majors in college and future career opportunities in engineering. Data were collected over a period of two years in six summer camps. Three separate populations of middle and high school students participated in the summer …

Surface Modifications Of Lini0.96Co0.02Mn0.02O2 With Tungsten Oxide And Phosphotungstic Acid, Gang Zhao, Zheng-Liang Gong, Yi-Xiao Li, Yong Yang

Journal of Electrochemistry

With the rapid development of electric vehicles, enormous demands are made for higher energy density, better cycling performance and lower cost of lithium-ion batteries (LIBs). As an important high capacity cathode material for LIBs, the high nickel layered oxide material LiNi_0.8Co_0.1Mn_0.1O₂(NCM811) can reach an energy density of 760 Wh·kg^-1. The ultra-high nickel ternary positive electrode material (LiNi_1-x-yCo_xMn_yO₂, x ≥ 0.90) has a specific capacity of more than 210 mAh·g^-1, and can realize higher energy density. Besides, an ultra-high nickel material …

Preparation And Electrocatalytic Performance Of Feni-Cop/Nc Bifunctional Catalyst, Si-Miao Liu, Jing-Jiao Zhou, Shi-Jun Ji, Zhong-Sheng Wen

Journal of Electrochemistry

Rechargeable zinc-air batteries have gradually attracted much attention worldwide due to their high capacity, high energy density and low price. Oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) correspond to the charging and discharging processes in rechargeable zinc-air battery, respectively. At present, commercial Pt/C and IrO₂ catalysts hinder the large-scale application of zinc-air batteries due to low reserves, high prices and poor stability. Therefore, exploring high performance, low cost and high stability with dual functional catalysts is important for the development of rechargeable zinc-Air batteries. The metal-organic frameworks (MOFs) have high specific surface area, structural stability, good catalytic …

Hydrophobicity Optimization Of Cathode Catalyst Layer For Proton Exchange Membrane Fuel Cell, Hao-Jie Chen, Mei-Hua Tang, Sheng-Li Chen

Journal of Electrochemistry

Hydrophobicity of the cathode catalyst layers (CCLs) crucially determines the performance of proton exchange membrane fuel cells (PEMFCs) by affecting the transports of oxygen and liquid water. In this regard, polytetrafluoroethylene (PTFE) is usually used as a hydrophobic additive to facilitate the oxygen and water transports in CCLs. So far, there remains lacking systematic effort to optimize the addition methods of PTFE in CCLs and the mechanisms behind. In this work, the effects of the approaches for PTFE addition and the distribution of PTFE on the mass transport of oxygen and the proton conduction in CCLs were studied by using …

Challenges In Optimization For The Performance On Sustainability Dimensions In Reverse Logistics Social Responsibility, Sumarsono Sudarto, Katsuhiko Takahashi, Mochammad Dewo

Makara Journal of Technology

Reverse logistics social responsibility is preferred as the most acceptable solution for addressing the challenges in stakeholders’ debate regarding social responsibility in supply chains because it involves as many actors as possible in the supply chain to perform social responsibility to achieve sustainability. This paper explores the challenges in achieving optimal policies in sustainability dimensions for collection and recycling facilities in reverse logistics. Sustainability dimensions include economic, environmental, and social aspects. The reverse logistics is modeled on System Dynamics, and a simplified statistical analysis using a contour chart is employed in numerical experiments. Results show a narrow area of optimal …

Synthesis And Evaluation Of Organic Additives For Copper Electroplating Of Interconnects, Yue-Hui Zhai, Yi-Xiao Peng, Yan Hong, Yuan-Ming Chen, Guo-Yun Zhou, Wei He, Peng-Ju Wang, Xian-Ming Chen, Chong Wang

Journal of Electrochemistry

Copper interconnects are essential to the functionality, performance, power efficiency, reliability, and fabrication yield of electronic devices. They are widely found in chips, packaging substrates and printed circuit boards, and are often produced by copper electroplating in an acidic aqueous solution. Organic additives play a decisive role in regulating copper deposition to fill microgrooves, and micro-vias to form fine lines and interlayer interconnects. Generally, an additive package consists of three components (brightener, suppressor, and leveler), which have a synergistic effect of super-filling on electroplating copper when the concentration ratio is appropriate. Many works of literature have discussed the mechanism of …

Retracted: Fabrication And Characterization Of Wood Fiber Reinforced Polymer Composites, Firoz Ahmed, Omar Faroque, Saif Hasan, Khan Rajib Hossain, Rezaul Karim Sheikh

Al-Bahir Journal for Engineering and Pure Sciences

Wood-polymer composites (WPCs) combine the properties of wood and polymers. Creating composites involves adding plant or wood fibers as fillers to a polymer matrix. This study used mahogany and mango wood sawdust as reinforcement materials, while high-density polyethylene (HDPE) and polyvinyl chloride (PVC) were used as matrices. The investigated data in this study comprises four different (10, 20, 30, and 40) weight percentages (wt%) of mahogany and mango sawdust paired with corresponding wt% (90, 80, 70, and60) of HDPE and PVC matrices. The extrusion method produced composites with different amounts of sawdust and polymer matrices. Wood polymer composites were characterized …

Recent Progress Of Bifunctional Electrocatalysts For Oxygen Electrodes In Unitized Regenerative Fuel Cells, Tian-Long Zheng, Ming-Yu Ou, Song Xu, Xin-Biao Mao, Shi-Yi Wang, Qing-Gang He

Journal of Electrochemistry

Unitized regenerative fuel cells (URFCs), which oxidize hydrogen to water to generate electrical power under thefuel cells (FCs) mode and electrolyze water to hydrogen under the water electrolysis (WE) mode for recycling, areknown as clean and sustainable energy conversion devices. In contrast to the hydrogen oxidation reaction (HOR) andhydrogen evolution reaction (HER) on the hydrogen electrode side, the sluggish kinetics of oxygen reduction reaction(ORR) and oxygen evolution reaction (OER) on the oxygen electrode side requires highly efficient bifunctional oxygencatalysts. Conventional precious metal oxygen catalysts combine Pt and IrO₂ with excellent ORR and OER activities toachieve bifunctional electrocatalysis performance, but …

Band Alignments Of Metal/Oxides-Water Interfaces Using Ab Initio Molecular Dynamics, Yong-Bin Zhuang, Jun Cheng

Journal of Electrochemistry

Band alignments of electrode-water interfaces are of crucial importance for understanding electrochemical interfaces. In the scenario of electrocatalysis, applied potentials are equivalent to the Fermi levels of metals in the electrochemical cells; in the scenario of photo(electro)catalysis, semiconducting oxides under illumination have chemical reactivities toward redox reactions if the redox potentials of the reactions straddle the conduction band minimums (CBMs) or valence band maximums (VBMs) of the oxides. Computational band alignments allow us to obtain the Fermi level of metals, as well as the CBM and VBM of semiconducting oxides with respect to reference electrodes. In this tutorial, we describe …

The Effect Of Heat Treatment And Chemical Treatment On Natural Fibre To The Durability Of Wood Plastic Composites – A Review, Nuratiqah Asyiqin Mohd Nasharudin, Nur Fatihah Sulaiman, Nurul Aziemah Mohammad, Wan Nor Raihan Wan Jaafar, Falah Abu Dr., Siti Norasmah Surip

Journal of Materials Exploration and Findings

The application of WPC is not only limited to indoor applications but has been extended to exterior applications where properties of WPC could compromise during service life. WPC was derived from wood fiber of various sizes to reinforce polymers. Wood fiber has the advantage of a cheaper price, being abundantly available, and ease of processing, however, the critical factor is its hydrophilic nature, where moisture absorption is likely to occur. Thus, treatments for reducing the hydrophilicity of wood fibers are applied. By treatment of wood fiber, the surface impurities were removed, leaving the roughened surface of fibers, thus providing a …

Fe Nanoparticles Encapsulated In N-Doped Porous Carbon For Efficient Oxygen Reduction In Alkaline Media, Chun-Yan Li, Rui Zhang, Xiao-Jie Ba, Xiao-Le Jiang, Yao-Yue Yang

Journal of Electrochemistry

Rational design and synthesis of non-precious-metal catalyst plays an important role in improving the activity and stability for oxygen reduction reaction (ORR) but remains a major challenge. In this work, we used a facile approach to synthesize iron nanoparticles encapsulated in nitrogen-doped porous carbon materials (Fe@N-C) from functionalized metal-organic frameworks (MOFs, MET-6). Embedding Fe nanoparticles into the carbon skeleton increases the graphitization degree and the proportion of graphitic N as well as promotes the formation of mesopores in the catalyst. The Fe@N-C-30 catalyst showed the excellent ORR activity in alkaline solutions (E₀ = 0.97 V vs. RHE, E_{1/2 …}

P-Doped Ru-Pt Alloy Catalyst Toward High Performance Alkaline Hydrogen Evolution Reaction, Rong-Qin Huang, Wei-Ping Liao, Meng-Xuan Yan, Shi Liu, Yuan-Ming Li, Xiong-Wu Kang

Journal of Electrochemistry

Electrocatalytic water splitting represents grand promise for hydrogen fuel in modern energy equipment, and the design and fabrication of higher performance catalysts are at the central. Herein, we report the sequential phosphorus (P)-doping into ruthenium (Ru) nanoparticles (Ru-P/C) by thermal annealing of Ru nanoparticles in phosphine (PH₃) atmosphere and deposition of extremely low concentration of platinum (Pt) to obtain P-doped Ru-Pt alloy catalyst supported on carbon nanotubes (CNTs), which is denoted as (Ru-P)#Pt/C. The data by X-ray diffraction spectroscopy and transmission electron microscopy show that the Ru nanoparticles existed in the form of hexagonal close-packed (hcp) phase with …

Deep Euteceic Solvents-Assisted Synthesis Of Novel Network Nanostructures For Accelerating Formic Acid Electrooxidation, Jun-Ming Zhang, Xiao-Jie Zhang, Yao Chen, Ying-Jian Fan, You-Jun Fan, Jian-Feng Jia

Journal of Electrochemistry

Deep eutectic solvents (DESs) have been reported as a type of solvent for the controllable synthesis of metal nanostructures. Interestingly, flower-like palladium (Pd) nanoparticles composed of staggered nanosheets and nanospheres are spontaneously transformed into three-dimensional (3D) network nanostructures in choline chloride-urea DESs using ascorbic acid as a reducing agent. Systematic studies have been carried out to explore the formation mechanism, in which DESs itself acts as a solvent and soft template for the formation of 3D flower-like network nanostructures (FNNs). The amounts of hexadecyl trimethyl ammonium bromide and sodium hydroxide also play a crucial role in the anisotropic growth and …