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Articles 1 - 30 of 41
Full-Text Articles in Chemical Engineering
Fabrication Of Micro-Meltblown Filtration Media Using Parallel Plate Die Design, Mohammad A. Hassan
Fabrication Of Micro-Meltblown Filtration Media Using Parallel Plate Die Design, Mohammad A. Hassan
Mohammad Abouelreesh Hassan
Meltblown fibers are typically produced using a die technology based on the slot concept, an extension of the sheet die technology with a series of holes substituting the center rectangular slot of the sheet die. While this prevalent technology has met with considerable success, an economical, facile design would be desirable. In this study a new parallel plate die concept to fabricate micro-meltblown fibers that offers simplicity, ease of use, and low cost was examined. The new die concept had parallel plates forming channels for polymer melt to flow through with a set of air holes surrounding them. This die …
Metallurgical Chemistry, Fathi Habashi
Metallurgical Chemistry, Fathi Habashi
Fathi Habashi
Metallurgical chemistry is the most ancient science of chemistry. It is related to the recovery of metals from ores and their refining. In its modern form, it involves separation of finely ground minerals by flotation, melting of ores, aqueous processing of ores, and the application of electric current to separate and purify metals from aqueous solution or from a fused salt. Metallurgical chemistry is closely related to the chemical industry.
Hydrometallurgy Of Phosphate Rock And The Recovery Of Uranium, Fathi Habashi
Hydrometallurgy Of Phosphate Rock And The Recovery Of Uranium, Fathi Habashi
Fathi Habashi
Phosphate rock of sedimentary origin contains on the average 0.01 % uranium. Since large tonnage of this rock is used annually to produce fertilizers, this represented an important potential source of uranium. Before the discovery of rich uranium deposits this source was developed on industrial scale. The production of phosphoric acid by sulfuric acid process is at present facing the problem of disposal of gypsum; about 1.5 tons of gypsum is produced per ton of rock processed. This material contains all the radium originally present in the rock which results from the radioactive decay of uranium. As a result, phospho-gypsum …
Production Of Greenhouse Gas Free Hydrogen By Thermocatalytic Decomposition Of Methane – A Review, Upm Ashik, Wma Wan Daud, Hf Abbas
Production Of Greenhouse Gas Free Hydrogen By Thermocatalytic Decomposition Of Methane – A Review, Upm Ashik, Wma Wan Daud, Hf Abbas
upm ashik
Thermocatalytic decomposition of methane (TCD) is a fully green single step technology for producing hydrogen and nano-carbon. This review studying all development in laboratory-scale research on TCD, especially the recent advances like co-feeding effect and catalyst regeneration for augmenting the productivity of the whole process. Although a great success on the laboratory-scale has been fulfilled, TCD for greenhouse gas (GHG) free hydrogen production is still in its infancy. The need for commercialization of TCD is greater than ever in the present situation of huge GHG emission. TCD usually examined over various kind of catalysts, such as monometallic, bimetallic, trimetallic, combination …
Driving Force For Binary Alloy Solidification Under Far From Local Equilibrium Conditions, Sergey Sobolev
Driving Force For Binary Alloy Solidification Under Far From Local Equilibrium Conditions, Sergey Sobolev
Sergey Sobolev
No abstract provided.
Travelling In Cuba, Fathi Habashi
Travelling In Cuba, Fathi Habashi
Fathi Habashi
Contact with Cuban scientists was established in 1986 when two researchers from Centro de Investigaciones para Industria Minero Metalurgica in Havana visited Laval University to get acquainted with research activities in the area of extractive metallurgy. This was followed in early 1987 by two more researchers from the same centre. Invitations were then received in late 1987, 1989, and 2008 to visit the nickel refineries in Cuba and to hold seminars at the University of Havana. The present report outlines these activities.
Sulfonic Acid Functionalized Mcm-41 As Solid Acid Catalyst For Tert-Butylation Of Hydroquinone Enhanced By Microwave Heating, Eng-Poh Ng
Eng-Poh Ng
Covalently linked sulfonic acid (-SO3H) modified MCM-41 mesoporous catalysts was prepared, characterized and its catalytic activity under microwave irradiation was evaluated. The NH2-MCM-41 was first prepared by anchoring (3-aminopropyl)triethoxysilane (APTES) on Si-MCM-41 and further reacted with 1,4-butane-sultone to yield the desired acid catalyst. The mesophase and porosity of samples were determined by XRD, TEM and N2 sorption isotherm analyses. The presence of sulfonic acid moiety was confirmed by FT-IR, TG/DTA, sulfur elemental analysis and in situ IR study of pyridine and ammonia adsorptions. The catalyst showed high catalytic activity and high selectivity in tert-butylation of hydroquinone under microwave irradiation. No …
Modelling Three-Phase Flow In Metallurgical Processes, Christoph Goniva, Gijsbert Wierink, Kari Heiskanen, Stefan Pirker, Christoph Kloss
Modelling Three-Phase Flow In Metallurgical Processes, Christoph Goniva, Gijsbert Wierink, Kari Heiskanen, Stefan Pirker, Christoph Kloss
Gijsbert Wierink
The interaction between gasses, liquids, and solids plays a critical role in many processes, such as coating, granulation and the blast furnace process. In this paper we present a comprehensive numerical model for three phase flow including droplets, particles and gas. By means of a coupled Computational Fluid Dynamics (CFD) - Discrete Element Method (DEM) approach the physical core phenomena are pictured at a detailed level. Sub-models for droplet deformation, breakup and coalescence as well as droplet-particle and wet particle-particle interaction are applied. The feasibility of this model approach is demonstrated by its application to a rotating drum coater. The …
The Impact Of Controlled Solvent Exposure On The Morphology, Structure And Function Of Bulk Heterojunction Solar Cells, Raghavendra R. Hegde Dr
The Impact Of Controlled Solvent Exposure On The Morphology, Structure And Function Of Bulk Heterojunction Solar Cells, Raghavendra R. Hegde Dr
Raghavendra R Hegde Dr
Films of poly(3-hexyl thiophene) (P3HT):[6,6]-phenyl C61-butyric acid methyl ester (PCBM) were controllably exposed to CS2 vapor in a column with a linear solvent vapor pressure gradient. Changes in the morphology of the P3HT:PCBM thin film were monitored and correlated to the ability of this thin film to act as the active layer in an organic solar cell. The results show that the crystallinity and crystal size of the P3HT increase initially with solvent vapor pressure and annealing time, but longer exposure to solvent decreases P3HT crystallinity and photovoltaic efficiency. Neutron reflectivity indicates that the PCBM segregates to the Si substrate …
Pyrite. History, Chemistry, And Metallurgy, Fathi Habashi
Pyrite. History, Chemistry, And Metallurgy, Fathi Habashi
Fathi Habashi
The Book covers the history of pyrite - - how it was a strategic mineral necessary for the production of elemental sulfur needed for making gunpowder for military purposes and for the production of SO2 needed for making sulfuric acid for the chemical industry. Now its presence is a nuisance in tailings ponds. The book also covers the processing of pyrite containing gold, its chemistry and technology, the processing of pyrite cinder for the production of a variety of metals, and its behaviour towards autotrophic microorganisms.
Capturing Ultrasmall Emt Zeolite From Template-Free Systems, Eng-Poh Ng Dr.
Capturing Ultrasmall Emt Zeolite From Template-Free Systems, Eng-Poh Ng Dr.
Eng-Poh Ng
No abstract provided.
Transferts De Chaleur Dans Un Réacteur Thermochimique Solaire Muni D’Un Récepteur Volumique Poreux, Hernando Romero Paredes Rubio
Transferts De Chaleur Dans Un Réacteur Thermochimique Solaire Muni D’Un Récepteur Volumique Poreux, Hernando Romero Paredes Rubio
Hernando Romero Paredes Rubio
Un réacteur thermochimique solaire de 1 kW muni d’une structure céramique poreuse en céramique est modélisé pour simuler les transferts thermiques a l’intérieur du récepteur volumétrique. Le modèle développé a été utilisé pour prévoir le comportement thermique du réacteur en fonction des différentes conditions opératoires qui concernent le débit de gaz inerte, le flux solaire incident, la porosité, la longueur du récepteur, et la prise en compte de réactions chimiques. Les résultats montrent que la température maximale est de 1850K pour une concentration solaire de 1000 soleils. La température diminue de manière significative lorsque le débit de gaz augmente. Un …
Pigments For Improving Plant Health In Organic Systems, Gregory Keith Bartley Jr.
Pigments For Improving Plant Health In Organic Systems, Gregory Keith Bartley Jr.
Gregory Keith Bartley Jr.
Photosynthesis, arguably the most important biological process on earth, solely relies on the ability of pigments to capture, utilize, and convert the sun‟s energy to form life. The adequate conversion of light into harvestable food, fuel, and fiber regulates rates of population and economic growth. In order to meet the expanding needs of humanity with the earth‟s potential for agricultural production, new sustainable techniques for increased photosynthetic efficiency in plants must be implemented. The earth's pattern of light exposure is extremely dynamic, exhibiting constant changes in quantity and quality throughout time and space. For photosynthetic organisms, this meant evolving various …
Efficiency Of Ionic Liquids In The Dissolution Of Rice Husk, Teck Nam Ang Dr., Li Wan Yoon Ms., Kiat Moon Lee Ms., Gek Cheng Ngoh Dr., Adeline Seak May Chua Dr., Min Gyu Lee Prof.
Efficiency Of Ionic Liquids In The Dissolution Of Rice Husk, Teck Nam Ang Dr., Li Wan Yoon Ms., Kiat Moon Lee Ms., Gek Cheng Ngoh Dr., Adeline Seak May Chua Dr., Min Gyu Lee Prof.
Teck Nam Ang Dr.
Ionic liquids that dissolve cellulose provide an option to pretreat lignocellulosic biomass. In this study, potential application of three ionic liquids in pretreating rice husk and their abilities in dissolving rice husk cellulose were investigated. The ionic liquids applied were 1-butyl-3- methylimidazolium chloride ([BMIM]Cl), 1-ethyl-3-methylimidazolium acetate ([EMIM]OAc), and 1-ethyl-3-methylimidazolium diethyl phosphate ([EMIM]DEP). Dissolution of rice husk was conducted by heating 1.5% (w/v) rice husk-ionic liquid mixture at 100oC for 20 hours. The dissolved cellulose was subsequently regenerated with deionised water. All the ionic liquids were able to dissolve rice husk cellulose to varying extents, with the highest dissolution (36.7%) given …
Metalurgia Extractiva Y Política Nacional, Fathi Habashi
Metalurgia Extractiva Y Política Nacional, Fathi Habashi
Fathi Habashi
Should a country export its mineral wealth in form of concentrates or should it locally treat its ores to produce metals as final products? In the past centuries pyrometallurgy was the only route to extract metals from ores and this required a large capital investment many countries could not afford to raise. This situation encouraged marketing of concentrates. Today, metallurgists have the option to use the hydrometallurgical route to process ores and concentrates at a reasonable capital investment. This opened the way to the possibility of processing ores locally. When need arises to increase production new units can be added …
Nanosized Molecular Sieves Utilized As An Environmentally Friendly Alternative To Antioxidants For Lubricant Oils, Eng-Poh Ng Dr.
Nanosized Molecular Sieves Utilized As An Environmentally Friendly Alternative To Antioxidants For Lubricant Oils, Eng-Poh Ng Dr.
Eng-Poh Ng
Lubricants play a significant part in current environmental considerations since they are an integral and indispensable component of modern technology. The production, application and disposal of the lubricants have to follow increasingly strict requirements for protecting the environment and living organisms. In this respect, molecular sieve (LTL type zeolite) is investigated as a potential environmentally friendly alternative to traditional antioxidant additives for lubricant oils. Accelerated oxidation experiments using pure base oil and additivated base oil in the presence of the LTL molecular sieve are carried out in parallel, and the oxidation processes are monitored by FT-IR spectroscopy, spectrophotometry, chromatography, total …
Leaching Mechanism Of Semiconducting Minerals, Fathi Habashi
Leaching Mechanism Of Semiconducting Minerals, Fathi Habashi
Fathi Habashi
The mechanism of leaching of semiconducting minerals such as PbS, ZnS, UO2, etc., has been the subject of intensive speculation by hydrometallurgists in the early 1950s. The electrochemical mechanism proposed in 1970 by the author in volume 2 of his Principles of Extractive Metallurgy avoids the assumption of forming intermediate complexes that cannot be isolated or identified.
Regulating Factors In Anthocyanin Biosynthesis, Gregory Keith Bartley Jr.
Regulating Factors In Anthocyanin Biosynthesis, Gregory Keith Bartley Jr.
Gregory Keith Bartley Jr.
No abstract provided.
Metals: Typical And Less Typical, Transition And Inner Transition, Fathi Habashi
Metals: Typical And Less Typical, Transition And Inner Transition, Fathi Habashi
Fathi Habashi
While most chemists agree on what is a metal and what is a non-metal there is a disagreement with respect to what is a metalloid and what is a transition metal. It is believed that this problem can be solved if two new terms are adopted: typical and less typical metals. These new terms will also help reconcile the European Periodic Table versus the North American regarding numbering of groups as well as the IUPAC numbering which could be as well abandoned in favour of group names as will be shown in the manuscript.
Phosphate Industry And The Radon Problem, Fathi Habashi
Phosphate Industry And The Radon Problem, Fathi Habashi
Fathi Habashi
The problem of radon generated during the treatment of phosphate rock by sulfuric acid to produce fertilizers can be solved by using nitric acid. In this case radium, which is the source of radon, goes into solution and can be precipitated by a controlled method and safely disposed of. A variety of options are discussed. Text in Farsi with English translation.
Effective Sba-15 Supported Gold Catalysts For Gluconic Acid Synthesis, K. Odrozek, J. J. Malinowski, J. Mrowiec-Bialon
Effective Sba-15 Supported Gold Catalysts For Gluconic Acid Synthesis, K. Odrozek, J. J. Malinowski, J. Mrowiec-Bialon
Janusz J. Malinowski
No abstract provided.
My Curriculum Vitae (As January 2013), Yun Hau Ng
My Curriculum Vitae (As January 2013), Yun Hau Ng
Yun Hau Ng
References available upon request
Micro- To Macroscopic Observations Of Mnalpo-5 Nanocrystal Growth In Ionic-Liquid Media, Eng-Poh Ng Dr.
Micro- To Macroscopic Observations Of Mnalpo-5 Nanocrystal Growth In Ionic-Liquid Media, Eng-Poh Ng Dr.
Eng-Poh Ng
Micro- and macroscopic studies of nucleation and growth processes of MnAlPO-5 nanosized crystals under ionothermal synthesis conditions are reported herein. The samples treated at 150 8C were extracted from the reaction mixture at various stages of crystallization, and characterized by XRD; SEM; thermogravimetric analysis (TGA); 31P and 27Al solid-state magic angle spinning (MAS) NMR, Raman, UV/Vis, and X-ray fluorescence spectroscopy (XRF). The starting raw materials (alumina, manganese, and phosphorous) were dissolved completely in the ionic liquid and transformed into an amorphous solid after 5 h of ionothermal treatment. This amorphous solid then undergoes structural changes over the following 5–25 h, …
Aqua Science Through The Ages. An Illustrated History Of Water, Fathi Habashi
Aqua Science Through The Ages. An Illustrated History Of Water, Fathi Habashi
Fathi Habashi
Water a component of the Four Elements considered by the ancient philosophers as essential for survival, played, and is still playing an essential role in society. Great civilizations in ancient times developed along great rivers. The ancient peoples knew how to manage water supplies by digging canals, controlling floods, and using water for irrigation. They designed equipment that used water to measure the time, to determine the density of solids, to fight fires, and to create vacuum. Modern engineers exploited water flow to design and construct huge hydroelectric power stations. Waterways and navigation systems were also an essential element for …
پاسخهای تشریحی سوالات کنکور کارشناسی ارشد رشته شیمی کاربردی-چاپ دوم-ویرایش جدید, A. Khataee, M. H. Rasoulifard, Mir Saeed Seyed Dorraji, V. Vatanpoor
پاسخهای تشریحی سوالات کنکور کارشناسی ارشد رشته شیمی کاربردی-چاپ دوم-ویرایش جدید, A. Khataee, M. H. Rasoulifard, Mir Saeed Seyed Dorraji, V. Vatanpoor
Mir saeed Seyed Dorraji
No abstract provided.
Chemistry And Metallurgy In The Great Empires, Fathi Habashi
Chemistry And Metallurgy In The Great Empires, Fathi Habashi
Fathi Habashi
It is remarkable that certain countries expand to become great empires then as time goes by they gradually decline while others rise. This book attempts to briefly trace the history of chemistry and metallurgy through the different empires that became at one time great and then faded away. In 272 pages 21.5 x 28 cm, the author outlines the inter-relation of chemistry, metallurgy, mining, and medicine, the idea of the divinity of kings and the formation of nations, and finally the rise and fall of the empires. He then covers the ancient and medieval empires, followed by the empires from …
Science, Technology, And Society, Fathi Habashi
Science, Technology, And Society, Fathi Habashi
Fathi Habashi
Science, technology, and society is a vast and complex question. It is discussed here from five points: social responsibility of scientists, migration and movement of scholars, philanthropy and its role in education and culture, enlightened despots and their influence on science and culture, and finally the social aspects of mining. The book is meant for the general reader but can benefit scientists as well. It is fully illustrated with colored pictures. It is hoped that it will serve as an introduction to this field to the young generation and inspire them to serve society.
Discrete Mnalpo-5 Nanocrystals Synthesized By An Ionothermal Approach, Eng-Poh Ng, Satpal Singh Sekhon, Svetlana Mintova
Discrete Mnalpo-5 Nanocrystals Synthesized By An Ionothermal Approach, Eng-Poh Ng, Satpal Singh Sekhon, Svetlana Mintova
Eng-Poh Ng
Discrete MnAlPO-5 nanocrystals with monomodal particle size distribution (diameter of 80 nm) were synthesized using an ionothermal technique; the pore filling effect of the ionic liquid molecules during the synthesis of microporous nanocrystals is verified.
Selective Capture Of Water Using Microporous Adsorbents To Increase The Lifetime Of Lubricants, Eng-Poh Ng, Luc Delmotte, Svetlana Mintova
Selective Capture Of Water Using Microporous Adsorbents To Increase The Lifetime Of Lubricants, Eng-Poh Ng, Luc Delmotte, Svetlana Mintova
Eng-Poh Ng
Eco-recycling towards an increase of the lifetime of lubricating mineral oil by selective capturing of water with nanosized microporous aluminophosphate and aluminosilicate materials is reported. Quantitative water measurements of oxidized lubricating oil before and after treatment with microporous materials were carried out by FT-IR spectroscopy combined with Karl Fischer titration method. The high selectivity of the nanosized aluminophosphate to water without adsorbing other additives in comparison to nanosized aluminosilicates that are adsorbing altogether polar oxidation products, ionic additives and water are revealed. A removal of nearly 98 % of moisture from the lubricating oil at ambient condition is achieved, which …
Nanoporous Materials With Enhanced Hydrophilicity And High Water Capacity, Eng-Poh Ng, Svetlana Mintova
Nanoporous Materials With Enhanced Hydrophilicity And High Water Capacity, Eng-Poh Ng, Svetlana Mintova
Eng-Poh Ng
The main types of nanoporous adsorbents for water are identified and described with emphasis on the mechanism of adsorption, modification, improvement of the water sorption capacity, possible regeneration, and stabilization. Among the three main groups of water sorbents, i.e. inorganic materials (zeolites, clays, silica), carbon based materials and organic polymers, the first one is described in details. The significance of their porosity, chemical and structural features relative to the water adsorptive properties of each inorganic type materials is reviewed. Important features for silicates, zeolites, aluminophosphates, mesoporous materials and clays are described, which define the interactions between the water and the …