Chemical Engineering Commons^™

Impedance-Resolved Performance And Durability In Redox Flow Batteries, Alan Michael Pezeshki

Doctoral Dissertations

The realization of redox flow batteries (RFBs) as a grid-scale energy solution depends on improving the performance and lifetime of the technology to decrease the high capital costs. The electrodes are a key component in the RFB; performance enhancement is often achieved through chemical or thermal treatments of commercially available porous carbon materials.

This dissertation uses impedance spectroscopy-based methods to gain insight into performance and durability in RFBs, enabling intelligent cell design. Initial work focused on understanding the impact of improved electrode and membrane properties on system performance. An accelerated stress test was then developed that can be used to …

Polymer And Small Molecule Designs For Anion Conducting Membranes: Connected Ion-Channel Morphologies And Highly Alkaline Stable Ammonium Cations, Sedef P. Ertem

Doctoral Dissertations

Fuel cells are one of the oldest sustainable energy generation devices, converting chemical energy into electrical energy via reverse-electrolysis reactions. With the rapid development of polymer science, solid polymer electrolyte (SPE) membranes replaced the conventional liquid ion transport media, rendering low-temperature fuel cells more accessible for applications in portable electronics and transportation. However, SPE fuel cells are still far from commercialization due to high operation cost, and insufficient lifetime and performance limitations. Anion exchange membrane fuel cells (AEMFCs) are inexpensive alternatives to current proton exchange membrane fuel cell (PEMFC) technology, which relies on utilizing expensive noble-metal catalysts and perfluorinated SPE …

Modeling Pyrolysis Of Large Coal Particles With Many Species, Jianqing Li

Master's Theses (2009 -)

Coal currently supplies 40% of the world’s electricity needs, and is one of the most important energy sources. As the initial stage of coal combustion, pyrolysis is a thermal decomposition process which converts coal into light gases and tars, which are subsequently consumed in combustion reactions, as well as solid char. Recently there has been interest in using slow pyrolysis as a stand-alone process for the production of chemicals and fuels from large (mm-scale) coal particles. Simulations can be used to efficiently study the impact of pyrolysis conditions on gas, tar and char yields, as well as gas and tar …

Go With The Flow –Thermoelectric Energy, Shawn Bell

Middle School Lesson Plans

In this unit, students will learn how thermal energy be transferred and transformed. They will carry out investigations to gather evidence to support an explanation about direct conversion of heat into electrical energy. They will develop a model that shows the components of the system and changes in the system being investigated, and they will use evidence from the investigation to construct an explanation for how the energy flows.

Gasoline Confined In Nano-Porous Media, Matthew Giso

Honors Theses

The heat of combustion was determined for gasoline confined in nano-porous media of differing pore size by bomb calorimetry. The heat of combustion of the confined fuels was comparable to that of bulk within the experimental uncertainty. This suggests that all of the confined fuel burns without any flame quenching and no chemical interactions at the interface between pore walls and fuel mitigate combustion.

Fluid Analysis In Solar Heat Pipes, Ben Krumholz, Michael Agavo, William Dundon

Mechanical Engineering

Evacuated tube solar collectors are efficient systems that use heat pipes to facilitate heat transfer. They use incoming solar radiation to heat water. Professor Mason Medizade tasked the team with choosing a component of the system to research and test its influence on system performance. The team investigated the working fluid that runs through the heat pipes. Distilled water, acetone, and ethanol at a range of fill volumes form 1 mL to 11 mL were tested. The team's goal was to find a volume for each fluid to maximize performance of the system. Performance was defined as average temperature rise …

Procesy Cieplne I Aparaty (Lab), Wojciech M. Budzianowski

Wojciech Budzianowski

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Inżynieria Chemiczna Lab., Wojciech M. Budzianowski

Wojciech Budzianowski

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Design And Commissioning Of A Community Scale Solar Powered Membrane-Based Water Purification System In Haiti, Shavin Pinto, Yung Wong, Kyle Fennesy, Yan Tang, Marc Compere

Publications

This paper presents the design and commissioning of a solar powered water purification system at the Ryan Epps Home for Children (REHC) in Michaud, Haiti. This system supplies clean drinking water to the 200 children who live and go to school at REHC and also to the community in the form of a micro-business. This micro-business is the mechanism for income generation for sustainable system operation. The purifier uses a three stage filtration system with a disc-type sediment filter, a 0.1 micron ultrafiltration membrane, and an ultraviolet light for disinfection. The backwash cycle extends the life of the ultrafiltration membrane …

Hybrid Metal Oxide Cycle Water Splitting, Richard B. Diver Jr, Robert D. Palumbo, Nathan P. Siegel, James E. Miller

Other Faculty Research and Publications

Hybrid thermochemical water splitting cycles are provided in which thermally reduced metal oxides particles are used to displace some but not all of the electrical requirements in a water splitting electrolytic cell. In these hybrid cycles, the thermal reduction temperature is significantly reduced compared to two-step metal-oxide thermochemical cycles in which only thermal energy is required to produce hydrogen from water. Also, unlike the conventional higher temperature cycles where the reduction step must be carried out under reduced oxygen pressure, the reduction step in the proposed hybrid cycles can be carried out in air, allowing for thermal input by a …