Chemical Engineering Commons^™

Frontiers In The Self-Assembly Of Charged Macromolecules, Khatcher O. Margossian

Doctoral Dissertations

The self-assembly of charged macromolecules forms the basis of all life on earth. From the synthesis and replication of nucleic acids, to the association of DNA to chromatin, to the targeting of RNA to various cellular compartments, to the astonishingly consistent folding of proteins, all life depends on the physics of the organization and dynamics of charged polymers. In this dissertation, I address several of the newest challenges in the assembly of these types of materials. First, I describe the exciting new physics of the complexation between polyzwitterions and polyelectrolytes. These materials open new questions and possibilities within the context …

Direct Printing Of Conductive Inks For Organic Electronics And Wearable Microfluidics, Aditi Naik

Doctoral Dissertations

This dissertation examines the direct printing of conductive inks on polymeric substrates for applications in organic electronics, microfluidic valving systems, and wearable sweat sensors. The inexpensive production of solution-based electrodes with high electrical conductivity is necessary to enable the next-generation of printed, flexible, and organic electronics. Specifically, the optimization and printing of liquid-phase graphene ink and nanoparticle-based silver ink by soft nanoimprint lithography and inkjet-printing is discussed to achieve printed functional devices. Using scalable low-cost patterning systems, these flexible applications are compatible with roll-to-roll processing, enabling large-scale manufacturing. This research expands the knowledge of high-resolution printing optimization for the direct …

Analyses Of Densely Crosslinked Phenolic Systems Using Low Field Nmr, Jigneshkumar Patel

Doctoral Dissertations

A uniform dispersion of reactants is necessary to achieve a complete reaction involving multi-components, especially for the crosslinking of rigid high-performance materials. In these reactions, miscibility is crucial for curing efficiency. This miscibility is typically enhanced by adding a third component, a plasticizer. For the reaction of the highly crystalline crosslinking agent hexamethylenetetramine (HMTA) with a strongly hydrogen-bonded phenol formaldehyde resin, furfural has been traditionally used as the plasticizer. However, the reason for its effectiveness is not clear. In this doctoral thesis work, miscibility and crosslinking efficiency of plasticizers in phenolic curing reactions are studied by thermal analysis and spectroscopic …

Integrated Solar Technologies With Outdoor Pedestrian Bridge Superstructure Decking, Richard K. Racz

Masters Theses

Solar technology has been a major topic in sustainable design for many years. In the last five years, however, the solar technology industry has seen a rapid growth in installations and technological advances in cell design. Combined with a rapidly declining overall system cost, the idea of introducing solar technology into a wider range of applications is becoming a focus for engineers and scientists around the world. So many variables which alter solar energy production, such as the sun and surrounding environment, determine whether a solar design is beneficial. This thesis presents a bridge deck surface integrated with solar cells …

Where To Buy Materials For The Activities, Morton Sternheim

Nanotechnology Teacher Summer Institutes

Sources for some of the less common materials used in the activities.

Seeing At The Nanoscale: New Microscopies For The Life Sciences, Jennifer Ross

Nanotechnology Teacher Summer Institutes

Visualizing single modules with fluorescence microscopy

Data Fusion For The Problem Of Protein Sidechain Assignment, Yang Lei

Masters Theses 1911 - February 2014

In this thesis, we study the problem of protein side chain assignment (SCA) given

multiple sources of experimental and modeling data. In particular, the mechanism

of X-ray crystallography (X-ray) is re-examined using Fourier analysis, and a novel

probabilistic model of X-ray is proposed for SCA's decision making. The relationship

between the measurements in X-ray and the desired structure is reformulated in terms

of Discrete Fourier Transform (DFT). The decision making is performed by developing

a new resolution-dependent electron density map (EDM) model and applying

Maximum Likelihood (ML) estimation, which simply reduces to the Least Squares

(LS) solution. Calculation of the …

Synthesize A Nanoscale Ferrofluid, Rob Snyder

Nanotechnology Teacher Summer Institutes

The chemical synthesis of a ferrofluid is a nanoscale science activity that originally appears in the Journal of Chemical Education. Access to the following website requires a subscription to the journal. J. Chem. Educ., 76, 943-948 (1999). The article was authored by Jonathan Breitzer and George Lisensky.