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Full-Text Articles in Chemical Engineering
Faceted Nanomaterial Synthesis, Characterizations And Applications In Reactive Electrochemical Membrane Filtration, Qingquan Ma
Faceted Nanomaterial Synthesis, Characterizations And Applications In Reactive Electrochemical Membrane Filtration, Qingquan Ma
Dissertations
Facet engineering of nanomaterials, especially metals and metal oxides has become an important strategy for tuning catalytic properties and functions from heterogeneous catalysis to electrochemical catalysis, photocatalysis, biomedicine, fuel cells, and gas sensors. The catalytic properties are highly related to the surface electronic structures, surface electron transport characteristics, and active center structures of catalysts, which can be tailored by surface facet control. The aim of this doctoral dissertation research is to study the facet-dependent properties of metal or metal oxide nanoparticles using multiple advanced characterization techniques. Specifically, the novel atomic force microscope-scanning electrochemical microscope (AFM-SECM) and density functional theory (DFT) …
Feasibility Of Cathodic Protection In Grouted Post Tensioned Tendons - Exploratory Model Calculations, Jacob Dharma Bumgardner
Feasibility Of Cathodic Protection In Grouted Post Tensioned Tendons - Exploratory Model Calculations, Jacob Dharma Bumgardner
USF Tampa Graduate Theses and Dissertations
Recent corrosion related failures of grouted post tensioned tendons, even after the introduction of improved grouts, have led to renewed interest in supplemental or backup means of corrosion control for these systems. A finite element model is presented to explore feasibility of impressed current cathodic protection of strand in grouted tendons. The model examines polarization evolution as function of service time and includes consideration of anode placement and size, grout porosity, pore water alkalinity, electrochemical species diffusivity and applied voltage on the polarization efficacy and durability of such a system. The exploratory model projections suggested that, within the context of …