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Articles 1 - 30 of 56
Full-Text Articles in Chemical Engineering
Mixed Complex Compounds Of Palmitate, Oleate Calcium With Acetamide, Nicotinamide And Thiocarbamide, Ibadullaeva Tursunoy, Azizov Tokhir, Ibragimova Мavluda
Mixed Complex Compounds Of Palmitate, Oleate Calcium With Acetamide, Nicotinamide And Thiocarbamide, Ibadullaeva Tursunoy, Azizov Tokhir, Ibragimova Мavluda
CHEMISTRY AND CHEMICAL ENGINEERING
The purpose of the study was the synthesis and study of the structure of mixed complexes of palmitate, calcium oleate with acetamide, nicotinamide and thiocarbamide. The mixed coordination compounds of palmitate and calcium oleate were synthesized. The composition, individuality, thermal behavior, methods of coordinating the palmitate and oleate fragments, acetamide, nicotinamide and thiocarbamide molecules have been established. Comparison of the diffraction patterns of calcium palmitate and oleate, free ligand molecules and synthesized compounds showed the mismatch of the diffractograms, conseqently that the synthesized complexes have an individual crystal lattice different from the starting materials. The method of coordination of amide …
Synthesis Of Esters Of Halogenoacetic Acids, Yuldasheva Muxabbat, Turaev Sherzod
Synthesis Of Esters Of Halogenoacetic Acids, Yuldasheva Muxabbat, Turaev Sherzod
CHEMISTRY AND CHEMICAL ENGINEERING
Amidoalkylating reagents containing a phthalimide group are used in the synthesis of hard-to-reach primary amines and complex heterocyclic compounds. These types of amidoalkylating compounds are suitable reagents for nucleophilic substituted reactions in acidic media due to their resistance to acids. Result of reactions of amidoalkylating reagents-N-hydroxyethylphthalimide and N-hydroxymethylphthalimide with aliphatic carbonic acids can also produce new bactericidal and fungicidal esters. In this study, halogen acids reacted with N-hydroxymethylphthalimide monochloric acetic acid, monobromic acetic acid, monoiodic acetic acid, trifluoric acetic acid and trichloroacetic acid, as well as, N-b-hydroxyethylphthaleidyl monohydric acid. As a result of the reactions, new phthalimidomethyl and phthalimidoethyl esters …
Numerical Simulations Of Current And Temperature Distribution Of Symmetrical Double-Cathode Solid Oxide Fuel Cell Stacks Based On The Theory Of Electric-Chemical-Thermal Coupling, Cheng-Rong Yu, Jian-Guo Zhu, Cong-Ying Jiang, Yu-Chen Gu, Ye-Xin Zhou, Zhuo-Bin Li, Rong-Min Wu, Zheng Zhong, Wan-Bing Guan
Numerical Simulations Of Current And Temperature Distribution Of Symmetrical Double-Cathode Solid Oxide Fuel Cell Stacks Based On The Theory Of Electric-Chemical-Thermal Coupling, Cheng-Rong Yu, Jian-Guo Zhu, Cong-Ying Jiang, Yu-Chen Gu, Ye-Xin Zhou, Zhuo-Bin Li, Rong-Min Wu, Zheng Zhong, Wan-Bing Guan
Journal of Electrochemistry
Solid oxide fuel cell (SOFC) is a high-efficient clean conversion device for future energy management. Because of the low antioxidant reduction ability and complex thermal stress, the structure of traditional asymmetrical thin anode-supported planar SOFC is easily to be broken under stack operating conditions. To overcome these defects, a new complete symmetrical SOFC based on double-sided cathodes was developed. To study the influences of gas flow direction and current collection mode on the cell performance inside stack, a numerical model was established by finite element method based on the theory of electro-thermo-chemo multiphysical coupling. By applying this model, the molar …
Core-Shell Structured Ru@Ptru Nanoflower Electrocatalysts Toward Alkaline Hydrogen Evolution Reaction, Xue-Liang Wang, Yuan-Yuan Cong, Chen-Xi Qiu, Sheng-Jie Wang, Jia-Qi Qin, Yu-Jiang Song
Core-Shell Structured Ru@Ptru Nanoflower Electrocatalysts Toward Alkaline Hydrogen Evolution Reaction, Xue-Liang Wang, Yuan-Yuan Cong, Chen-Xi Qiu, Sheng-Jie Wang, Jia-Qi Qin, Yu-Jiang Song
Journal of Electrochemistry
Water electrolysis for hydrogen production is beneficial for solving the problem of energy crisis and environmental issues. It is necessary to study highly active and cost-effective catalysts toward hydrogen evolution reaction (HER) to reduce the consumption of noble metals. Herein, we report the synthesis of core-shell structured Ru@Pt0.24Ru nanoflowers electrocatalyst by stepwise reduction of Ru and Pt precursors in the mixture of oleylamine and benzyl alcohol at 160 oC. The average diameter of the resultant Ru@Pt0.24Ru was 16.5±4.0 nm with a bulk atomic ratio between Pt and Ru of 0.24:1 and a surface ratio of 3.3:1 …
Effect Of Reaction Conditions On Cu⁃Catalyzed Co2 Electroreduction, Chang Zhu, Wei Chen, Yan-Fang Song, Xiao Dong, Gui-Hua Li, Wei Wei, Yu-Han Sun
Effect Of Reaction Conditions On Cu⁃Catalyzed Co2 Electroreduction, Chang Zhu, Wei Chen, Yan-Fang Song, Xiao Dong, Gui-Hua Li, Wei Wei, Yu-Han Sun
Journal of Electrochemistry
Electrochemical conversion of carbon dioxide (CO2) driven by renewable electricity that can meet both carbon emission reduction and renewable energy utilization has been rapidly developed in recent years. Copper (Cu) catalyst has long been a promising candidate for CO2 electroreduction applications because of its natural abundance and specific capability of producing a substantial amount of C2 products. However, various metallic Cu electrodes reported have been significantly influenced by the adsorption of certain cation/anion ions, resulting in wide-span catalytic activities and selectivity for various products. In addition, a recent report demonstrated that by virtue of gas-diffusion flow cell …
Reduction Of Copper And Iron Oxide Mixture With Local Reducing Gases, Shokhrukh Khojiev
Reduction Of Copper And Iron Oxide Mixture With Local Reducing Gases, Shokhrukh Khojiev
Acta of Turin Polytechnic University in Tashkent
The article analyzes the scientific problems of the copper industry. In particular, the main problem with the classical production of copper is the causes of large amounts of slag and the negative impact of these wastes on the environment. Accordingly, the main component that forms the slag is iron, and the higher its content in the original copper concentrate, the more slag is formed, and at the same time a large amount of copper metal is released into the waste. The departure is indicated by evidence. To prevent this problem, a technology has been proposed to reduce copper sulfide concentrates …
A Model For The Anodic Carbonization Of Alkaline Polymer Electrolyte Fuel Cells, Qi-Hao Li, Ying-Ming Wang, Hua-Long Ma, Li Xiao, Gong-Wei Wang, Jun-Tao Lu, Lin Zhuang
A Model For The Anodic Carbonization Of Alkaline Polymer Electrolyte Fuel Cells, Qi-Hao Li, Ying-Ming Wang, Hua-Long Ma, Li Xiao, Gong-Wei Wang, Jun-Tao Lu, Lin Zhuang
Journal of Electrochemistry
The alkaline polymer electrolyte fuel cell (APEFC) has made appreciable progress in recent years but is still suffering performance loss during discharge with air as the oxidant. Several theories have been suggested to interpret the loss. However, efforts are still needed to reach a clear quantitative understanding. Based on the major experimental findings in combination with thermodynamics and kinetics of the reactions involved in the anode, this paper presents a model featuring layered carbonization in the anode and relevant grouped equations. The simulation results generated from the latter are compared with experiments, and possible principles to suppress the performance loss …
Facile Synthesis Of Nitrogen-Doped Graphene-Like Active Carbon Materials For High Performance Lithium-Sulfur Battery, Quan-Hua Meng, Wen-Wen Deng, Chang-Ming Li
Facile Synthesis Of Nitrogen-Doped Graphene-Like Active Carbon Materials For High Performance Lithium-Sulfur Battery, Quan-Hua Meng, Wen-Wen Deng, Chang-Ming Li
Journal of Electrochemistry
Lithium-sulphur (Li-S) battery is regarded as a promising energy storage device because of its high theoretical capacity. However, the low S utilization and short cycling life limit the commercial applications. In this work, nitrogen-doped graphene-like carbon (NGC) materials were synthesized by simply pyrolyzing and carbonizing the mixture of melamine (C3H6N6) and L-cysteine (C3H7NO2S). The graphene-like structure in NGC effectively buffered the volume change of S during the discharge/charge process and improved the cycling stability. Meanwhile, nitrogen-containing functional groups in NGC facilitated the transportation of ions and suppressed the …
Modification Of Inuline By Iodic Acid, Rakhmanberdiyev Gappar, Ibragimova Кomila, Аxmedov Оliy
Modification Of Inuline By Iodic Acid, Rakhmanberdiyev Gappar, Ibragimova Кomila, Аxmedov Оliy
CHEMISTRY AND CHEMICAL ENGINEERING
In order to further modify inulin with drugs, the process of introducing reactive aldehyde groups into the inulin macromolecule was carried out. Aldehyde groups were introduced by oxidizing inulin with iodic acid. The process of oxidation of inulin and cellulose with iodic acid was compared. The quantities of aldehyde groups in the oxidized samples were estimated, their molecular weights were determined, IR spectra were measured, the iodine number of the inulin dialdehyde and their oxidation state were determined.
Synthesis Of 1,2,3-Triazoles Based On Propargyl Ethers Of Carbamate, Djuraev Abdukahhor, Yakubxodjaeva Malika, Ataxodjaeva Matluba, Gaibullaev Oibek
Synthesis Of 1,2,3-Triazoles Based On Propargyl Ethers Of Carbamate, Djuraev Abdukahhor, Yakubxodjaeva Malika, Ataxodjaeva Matluba, Gaibullaev Oibek
CHEMISTRY AND CHEMICAL ENGINEERING
By the interaction of propargyl esters of carbamate derivatives with phenylazide, 1,2,3- triazole derivatives were synthesized. Their anti-inflammatory activity was subsequently studied.During the study of biological activity, a relationship was established between the anti- inflammatory activity and the chemical structure in the studied series of 1,2,3-triazole derivatives.
The Research Of Conditions For The Formation Of Phenol Formaldehyde Resins Modified With Hydroxyl Containg Polyether Polyol, Magrupov Farkhad, Umarov Sherali, Tohirov Murodjon, Radjabova Zukhra
The Research Of Conditions For The Formation Of Phenol Formaldehyde Resins Modified With Hydroxyl Containg Polyether Polyol, Magrupov Farkhad, Umarov Sherali, Tohirov Murodjon, Radjabova Zukhra
CHEMISTRY AND CHEMICAL ENGINEERING
The aim of the study was to study the conditions of copolycondensation of phenol alcohol with hydroxyl-containing polyether polyol in the presence of maleic anhydride chain extender in order to obtain modified thermoset phenolic-formaldehyde oligomers. Investigation of the dependence of the content of free phenol, formaldehyde and methylol groups on time during the synthesis of the modified phenol-formaldehyde resin with the ratios hydroxyl-containing polyether polyol:phenol alcohol 1:60 mol/mol and 1:100 mol/mol. It was revealed that maleic anhydride, present in the reaction medium as a copolycondensation catalyst, also participates in copolycondensation reactions as a chain extender. Moreover, as the molar fraction …
Vinylation By 3,6-Dimetyloctin-4-Diol-3,6 Acetylene, Yusupova Lola, Abdukarimova Saida, Rajabov Rustambek, Khalimova Oygul
Vinylation By 3,6-Dimetyloctin-4-Diol-3,6 Acetylene, Yusupova Lola, Abdukarimova Saida, Rajabov Rustambek, Khalimova Oygul
CHEMISTRY AND CHEMICAL ENGINEERING
The aim of the research work elaboration of technology of obtaine of acetylene diols and their vinyl ethers. Reaction of formation mono di vinyl ethers as a result vinyl 3,6-dimetyloktin-4-diol-3,6 by acetylene, and also influence of solvents, the catalyst and its quantity, duration of reaction, temperatures is investigated. Are defined speed of reaction. Recommended vinyl 3,6-dimetyloktin-4-diol-3,6 acetylene in the presence of highly basic systems at atmospheric pressure.
Synthesis And Research Of New Heterometal Complexes Cо(Ii), Ni(Ii), Cu(Ii) And Mn(Ii) Based On V(V) And 5-(4-Pyridyl)-1,3,4-Oxadiazole-2(3h)-Thione Lubricants, Pirimova Mehribon, Kadirova Shakhnoza, Rakhmonоva Dilnoza, Ziyayev Abduhakim
Synthesis And Research Of New Heterometal Complexes Cо(Ii), Ni(Ii), Cu(Ii) And Mn(Ii) Based On V(V) And 5-(4-Pyridyl)-1,3,4-Oxadiazole-2(3h)-Thione Lubricants, Pirimova Mehribon, Kadirova Shakhnoza, Rakhmonоva Dilnoza, Ziyayev Abduhakim
CHEMISTRY AND CHEMICAL ENGINEERING
The oxadiazole derivatives complex compounds with metals are biologically active substances. The aim of the study was to study the interaction of the chlorides of Co (II), Ni (II), Cu (II) and Mn (II) with 5-(4-pyridyl)-1,3,4-oxadiazole-2(3H)–thione, ammonium vanadate. Competitive coordination of donor centers, electronic and geometric structures of the ligand molecule were studied on the basis of the quantum-chemical software package Gaussian09 LanL2DZ. It was shown that 5-(4-pyridyl)-1,3,4-oxadiazole-2(3H)-thione ligand is partially coordinated through a localized nitrogen or sulfur atoms at formation of the complex. А procedure was developed for the synthesis of new mixed-metal complexes. The composition and structure of …
Research Of Kinetic Characteristics Of The Process Of Decomposition Of Zinc Concentrate With Hydrochloric Acid, Rosilov Mansur, Deng Tianlong, Usmanov Ilham, Samadiy Murodjon
Research Of Kinetic Characteristics Of The Process Of Decomposition Of Zinc Concentrate With Hydrochloric Acid, Rosilov Mansur, Deng Tianlong, Usmanov Ilham, Samadiy Murodjon
CHEMISTRY AND CHEMICAL ENGINEERING
The aim of the study was the theoretical justification of the kinetic characteristics of the process of producing zinc chloride from zinc concentrate of the Khandiza deposit. For this, the effect of temperature and duration of the process of autoclave zinc extraction in a 28% hydrochloric acid solution was studied at a ratio of Zn: HCI = 1:1.1. Variable parameters were the temperature of 70, 80 and 90 °C and the duration of the leaching process of 6, 8 and 10 hours. The optimal parameters for the production of zinc chloride were determined.
The Study Of The Component Composition Of The Reaction Mixture Containing Formaldehyde Reaction Products, Hurramov Lochinbek, Alimukhamedova Nozima, Adilov Ravshan, Alimukhamedov Muzafar
The Study Of The Component Composition Of The Reaction Mixture Containing Formaldehyde Reaction Products, Hurramov Lochinbek, Alimukhamedova Nozima, Adilov Ravshan, Alimukhamedov Muzafar
CHEMISTRY AND CHEMICAL ENGINEERING
The aim of this work is to study the effect of the conditions of the reaction of monoethanolamine (Meol) with formaldehyde (FD) on the composition of the reaction mixture. Interaction of monoethanolamine with formaldehyde leads to the formation of N,N’,N”-tris(β-oxyethyl) hexahydro-S-triazine or N,N-bisoxazolidine. The type of final product was determined by the conditions of the reaction and the molar ratio of aminoalcohol:formaldehyde. The chromatogram of the vacuum-distilled final product obtained at the molar ratio of monoethanolamine:formaldehyde=1:1 shows on an individual compound with a retention time of 4.173 s. With increase in the molar ratio of monoethanolamine:formaldehyde=1: 2, the final product …
Electrochemical Carbon Dioxide Reduction In Flow Cells, Jia Fan, Na Han, Yan-Guang Li
Electrochemical Carbon Dioxide Reduction In Flow Cells, Jia Fan, Na Han, Yan-Guang Li
Journal of Electrochemistry
Electrochemical carbon dioxide reduction (CO2RR) is an appealing approach to convert atmospheric CO2 to value-added fuels and industrial chemicals, and may play an important role during the transition to a carbon-neutral economy. In order to make this technology commercially viable, it is essential to pursue CO2RR in flow reactors instead of conventional H-type reactors, and to combine electrocatalyst development with system engineering. In this review, we overview the cell configurations and performance advantages of the two types of flow reactors, analyze their shortcomings, and discuss the effects of their different components including gas diffusion electrode …
Research Progress Of Metal-Nitrogen-Carbon Catalysts Toward Oxygen Reduction Reaction Inm Changchun Institute Of Applied Chemistry, Ming-Jun Xu, Jie Liu, Jun-Jie Ge, Chang-Peng Liu, Wei Xing
Research Progress Of Metal-Nitrogen-Carbon Catalysts Toward Oxygen Reduction Reaction Inm Changchun Institute Of Applied Chemistry, Ming-Jun Xu, Jie Liu, Jun-Jie Ge, Chang-Peng Liu, Wei Xing
Journal of Electrochemistry
The development of highly active and stable catalysts toward oxygen reduction reaction (ORR) has been facing severe challenges. In recent years, pyrolytic M-N-C catalysts and metal-organic framework derived materials made the performance of non-noble metal catalysts greatly improved, however, the molecular and atomic level understanding in the reaction active sites and the mechanism are still lacking. Here, we summarize the recent research progress made in the Changchun Institute of Applied Chemistry. We present a microporous metal-organic-framework confined strategy toward the preferable formation of ORR catalysts. Firstly, we studied the active site and proposed a new active site structure for the …
Recent Progress In Bifunctional Catalysts For Zinc-Air Batteries, Neng-Neng Xu, Jin-Li Qiao
Recent Progress In Bifunctional Catalysts For Zinc-Air Batteries, Neng-Neng Xu, Jin-Li Qiao
Journal of Electrochemistry
Zinc-air battery has attracted great attention from researchers due to its high energy density and power density, which is expected to be widely used in energy conversion and storage. Air electrode as the core area of oxygen catalytic reaction is the focus of the entire zinc-air battery research. Recently, many research achievements have been made in non-noble metal bifunctional catalysts/electrodes with high activity, low cost and abundant species. In this review, we mainly focus on the reaction mechanism and the recent progress in non-noble metal oxide catalyst, carbon-based catalyst, and carbon-based transition metal compound composite and self-supporting electrode. In addition, …
Recent Progress On Enhancing Effect Of Nanosized Metals For Electrochemical Co2 Reduction, Yu-Ning Zhang, Dong-Fang Niu, Shuo-Zhen Hu, Xin-Sheng Zhang
Recent Progress On Enhancing Effect Of Nanosized Metals For Electrochemical Co2 Reduction, Yu-Ning Zhang, Dong-Fang Niu, Shuo-Zhen Hu, Xin-Sheng Zhang
Journal of Electrochemistry
The electrochemical conversion of CO2 to chemical raw material for further utilization shows promising future to alleviate global warming and realize carbon cycle in nature, which is of great significance to the green chemistry and sustainable development. This review briefly introduces the advantages of CO2 electrochemical reduction (CO2ER) and its basic reaction principles, and summarizes the recent progress in a series of activity enhancement strategies based on nanosized metal catalysts. The influences of alloy effect, interface engineering, synergistic effect, surface defect engineering and support effect on the catalytic performance of nanosized metals for CO2ER …
Electrolyte Tailoring For Electrocatalytic Reduction Of Stable Molecules, Jin-Han Li, Fang-Yi Cheng
Electrolyte Tailoring For Electrocatalytic Reduction Of Stable Molecules, Jin-Han Li, Fang-Yi Cheng
Journal of Electrochemistry
Reduction of stable molecules such as CO2 and N2 is important process in electrochemical energy conversion and storage technologies for electrofuels production. However, for the inert nature of CO2/N2 molecule and competitive proton reduction in conventional aqueous electrolytes, selective electrochemical carbon/nitrogen fixation suffers from high overpotential, low reaction rate and low selectivity. While addressing these issues has witnessed substantial advances in electrocatalysts, much less attention has been placed on the electrolytes, which play an important role in regulating the local environment and thus the performance of catalysts under operating conditions. Rational design of electrolytes has …
Fuel Cell Performance Of Non-Precious Metal Based Electrocatalysts, Yan-Feng Zhang, Fei Xiao, Guang-Yu Chen, Min-Hua Shao
Fuel Cell Performance Of Non-Precious Metal Based Electrocatalysts, Yan-Feng Zhang, Fei Xiao, Guang-Yu Chen, Min-Hua Shao
Journal of Electrochemistry
The commercialization of proton exchange membrane fuel cells (PEMFCs) is hindered by high cost and low durability of Pt based electrocatalysts. Developing efficient and durable non-precious metal catalysts is a promising approach to addressing these conundrums. Among them, transition metals dispersed in a nitrogen (N)-doped carbon support (M-N-C) show good oxygen reduction reaction activity. This article reviews recent progress in M-N-C catalysts development, focusing on the catalysts design, membrane electrode assembly fabrication, fuel cell performance, and durability testing. Template-assisted approach is an efficient way to synthesize M-N-C materials with homogeneously dispersed single atom active site and reduced metal particles, carbides …
The Research Of Conditions For The Formation Of Phenol Formaldehyde Resins Modified With Hydroxyl Containg Polyether Polyol, Magrupov Farkhad, Umarov Sherali, Tohirov Murodjon, Radjabova Zukhra
The Research Of Conditions For The Formation Of Phenol Formaldehyde Resins Modified With Hydroxyl Containg Polyether Polyol, Magrupov Farkhad, Umarov Sherali, Tohirov Murodjon, Radjabova Zukhra
CHEMISTRY AND CHEMICAL ENGINEERING
The aim of the study was to study the conditions of copolycondensation of phenol alcohol with hydroxyl-containing polyether polyol in the presence of maleic anhydride chain extender in order to obtain modified thermoset phenolic-formaldehyde oligomers. Investigation of the dependence of the content of free phenol, formaldehyde and methylol groups on time during the synthesis of the modified phenol-formaldehyde resin with the ratios hydroxyl-containing polyether polyol:phenol alcohol 1:60 mol/mol and 1:100 mol/mol. It was revealed that maleic anhydride, present in the reaction medium as a copolycondensation catalyst, also participates in copolycondensation reactions as a chain extender. Moreover, as the molar fraction …
Vinylation By 3,6-Dimetyloctin-4-Diol-3,6 Acetylene, Yusupova Lola, Abdukarimova Saida, Rajabov Rustambek, Khalimova Oygul
Vinylation By 3,6-Dimetyloctin-4-Diol-3,6 Acetylene, Yusupova Lola, Abdukarimova Saida, Rajabov Rustambek, Khalimova Oygul
CHEMISTRY AND CHEMICAL ENGINEERING
The aim of the research work elaboration of technology of obtaine of acetylene diols and their vinyl ethers. Reaction of formation mono di vinyl ethers as a result vinyl 3,6-dimetyloktin-4-diol-3,6 by acetylene, and also influence of solvents, the catalyst and its quantity, duration of reaction, temperatures is investigated. Are defined speed of reaction. Recommended vinyl 3,6-dimetyloktin-4-diol-3,6 acetylene in the presence of highly basic systems at atmospheric pressure.
Synthesis And Research Of New Heterometal Complexes Cо(Ii), Ni(Ii), Cu(Ii) And Mn(Ii) Based On V(V) And 5-(4-Pyridyl)-1,3,4-Oxadiazole-2(3h)-Thione Lubricants, Pirimova Mehribon, Kadirova Shakhnoza, Rakhmonоva Dilnoza, Ziyayev Abduhakim
Synthesis And Research Of New Heterometal Complexes Cо(Ii), Ni(Ii), Cu(Ii) And Mn(Ii) Based On V(V) And 5-(4-Pyridyl)-1,3,4-Oxadiazole-2(3h)-Thione Lubricants, Pirimova Mehribon, Kadirova Shakhnoza, Rakhmonоva Dilnoza, Ziyayev Abduhakim
CHEMISTRY AND CHEMICAL ENGINEERING
The oxadiazole derivatives complex compounds with metals are biologically active substances. The aim of the study was to study the interaction of the chlorides of Co (II), Ni (II), Cu (II) and Mn (II) with 5-(4-pyridyl)-1,3,4-oxadiazole-2(3H)–thione, ammonium vanadate. Competitive coordination of donor centers, electronic and geometric structures of the ligand molecule were studied on the basis of the quantum-chemical software package Gaussian09 LanL2DZ. It was shown that 5-(4-pyridyl)-1,3,4-oxadiazole-2(3H)-thione ligand is partially coordinated through a localized nitrogen or sulfur atoms at formation of the complex. А procedure was developed for the synthesis of new mixed-metal complexes. The composition and structure of …
Electrochemical Oxidation Of Metal Chromium In Odium Hydroxide Aqueous Solution, Ping Han, Hai-Tao Feng, Ya-Ping Dong, Sen Tian, Bo Zhang, Wu Li
Electrochemical Oxidation Of Metal Chromium In Odium Hydroxide Aqueous Solution, Ping Han, Hai-Tao Feng, Ya-Ping Dong, Sen Tian, Bo Zhang, Wu Li
Journal of Electrochemistry
Ferrochrome electrolysis technology is a novel method for preparing sodium chromate (Na2CrO4). Although the method performs well at soft reaction conditions, controllable process, environmentally friendly production process, etc., the electrochemical oxidation process of metal chromium in NaOH aqueous electrolyte is still unclear. At present, there are few research articles about specific electrochemical oxidation of metal chromium in NaOH aqueous electrolyte. It is, therefore, meaningful to carry out the research in electrochemical oxidation mechanism of chromium. The electrochemical oxidation of metal chromium in 0.01 mol·L-1 ~ 10 mol·L-1 NaOH aqueous electrolytes at 20 °C was studied by …
Preparation Of Α-Hydroxylated Acetal From 2-Butanone By Indirect Electrooxidation, Hai-Qing Huang, Ye Miao, Xin-Sheng Zhang
Preparation Of Α-Hydroxylated Acetal From 2-Butanone By Indirect Electrooxidation, Hai-Qing Huang, Ye Miao, Xin-Sheng Zhang
Journal of Electrochemistry
Acetoin (3-hydroxy-2-butanone) is an important food spice. As a platform compound, it is widely used in medicine, tobacco, cosmetics, chemical material and other industries. In this paper, α-hydroxylated acetal, an intermediate of acetoin, was prepared from 2-butanone by indirect electrooxidation in the plate and frame electrolytic cell, in which graphite plates were used as both an anode and a cathode, while KOH as an electrolyte and KI as a catalyst. Acetoin could be prepared by hydrolysis in acidic aqueous solution from acetoin intermediate. The effects of current density, electrolyte flow rate between the plates, 2-butanone concentration and electrolysis temperature …
Preparations Of Nano-MnoX/Ti Electrocatalytic Membrane Electrode For Catalytic Oxidation Of Cyclohexane Using Intermittent Electrodeposition, Xue Zhou, Hong Wang, Zhen Yin, Yu-Jun Zhang, Jian-Xin Li
Preparations Of Nano-MnoX/Ti Electrocatalytic Membrane Electrode For Catalytic Oxidation Of Cyclohexane Using Intermittent Electrodeposition, Xue Zhou, Hong Wang, Zhen Yin, Yu-Jun Zhang, Jian-Xin Li
Journal of Electrochemistry
Cyclohexanone and cyclohexanol (KA oil) obtained from highly selective oxidation of cyclohexane (CHA) show important industrial value and application prospects. In this work, the intermittent electrodeposition was developed to prepare nano-MnOx catalyst loading porous tubular titanium membrane electrode (MnOx/Ti), which was employed to constitute an electro-catalytic membrane reactor (ECMR) for the oxidation of cyclohexane to produce cyclohexanol and cyclohexanone. The surface morphology, crystal structure and electrochemical property of the catalysts were characterized by FESEM, XRD and electrochemical workstation, respectively. The results show that the catalyst prepared by the intermittent electrodeposition displayed nano-flower-like γ-MnO2. Compared …
Poly(Ethylene Oxide) Based Polymer Electrolytes For All-Solid-State Li-S Batteries, Xue Li, Zheng-Liang Gong
Poly(Ethylene Oxide) Based Polymer Electrolytes For All-Solid-State Li-S Batteries, Xue Li, Zheng-Liang Gong
Journal of Electrochemistry
In recent years, research on lithium-sulfur (Li-S) batteries has received much attention because the sulfur positive electrode and the lithium metal negative electrode produce a high theoretical specific capacity (lithium metal ~ 3800 mAh·g-1, sulfur ~ 1675 mAh·g-1). In addition, sulfur is considered to be the most promising cathode material for secondary lithium batteries, due to its advantages of low price and environmental friendly. However, the practical application of conventional liquid Li-S batteries is still obstructed by several critical issues, such as lithium ploysulfides shuttle effect, long-term stability of lithium metal anode with organic liquid electrolytes, and the safety concerns …
Stability Studies For A Membrane Electrode Assembly Type Co2 Electro-Reduction Electrolytic Cell, Qing Mao, Bing-Yu Li, Wei-Yun Jing, Jian Zhao, Song Liu, Yan-Qiang Huang, Zhao-Long Du
Stability Studies For A Membrane Electrode Assembly Type Co2 Electro-Reduction Electrolytic Cell, Qing Mao, Bing-Yu Li, Wei-Yun Jing, Jian Zhao, Song Liu, Yan-Qiang Huang, Zhao-Long Du
Journal of Electrochemistry
Electro-catalytic reduction is an efficient way to achieve resourcable transformation of CO2, which is one of the important techniques to solve the global environmental problems originated from excessive CO2 emission. In this study, a membrane electrode assembly(MEA) type CO2 electro-reduction electrolytic cell was constucted, which enables CO2 feeding and real-time KHCO3 aqueous updating on both sides of the cathode gas diffusion electrode (GDE). By means of the electrolytic cell, effects of KHCO3 concentration and updating inside the liquid electrolytic chamber on CO2 electro-reduction activity, production distribution and stability were investigated. The experimental …
Synthesis And Raman Study Of Hollow Core-Shell Ni1.2Co0.8P@N-C As An Anode Material For Sodium-Ion Batteries, Jia-Hui Chen, Xiao-Bin Zhong, Chao He, Xiao-Xiao Wang, Qing-Chi Xu, Jian-Feng Li
Synthesis And Raman Study Of Hollow Core-Shell Ni1.2Co0.8P@N-C As An Anode Material For Sodium-Ion Batteries, Jia-Hui Chen, Xiao-Bin Zhong, Chao He, Xiao-Xiao Wang, Qing-Chi Xu, Jian-Feng Li
Journal of Electrochemistry
With the increasing demand for large-scale energy storage, great progress has been made in discovering new advanced energy storage materials. Sodium-ion batteries (SIBs) have attracted much attention in recent years due to their use of abundant sodium resources and their comparable electrochemical capacity to lithium-ion batteries (LIBs). In this paper, we developed novel hollow core-shell Ni-Co bimetallic phosphide nanocubes with N-doped carbon coatings (Ni1.2Co0.8P@N-C) as the anode material for SIBs. The material was synthesized through a low-temperature phosphorization method using resorcinol formaldehyde (RF) resin coating with a Ni-Co Prussian blue analogue (PBA) as a template and …