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Full-Text Articles in Bioresource and Agricultural Engineering
Copper Sorption Mechanisms On Smectites, Daniel G. Strawn, Noel E. Palmer, Luca J. Furnare, Carmen Goodell, James E. Amonette, Ravi K. Kukkadapu
Copper Sorption Mechanisms On Smectites, Daniel G. Strawn, Noel E. Palmer, Luca J. Furnare, Carmen Goodell, James E. Amonette, Ravi K. Kukkadapu
US Department of Energy Publications
Due to the importance of clay minerals in metal sorption, many studies have attempted to derive mechanistic models that describe adsorption processes. These models often include several different types of adsorption sites, including permanent charge sites and silanol and aluminol functional groups on the edges of clay minerals. To provide a basis for development of adsorption models it is critical that molecular-level studies be done to characterize sorption processes. In this study we conducted X-ray absorption fine structure (XAFS) and electron paramagnetic resonance (EPR) spectroscopic experiments on copper (II) sorbed on smectite clays using suspension pH and ionic strength as …
Transformation Of 1-Aminonapththalene At The Surface Of Smectite Clays, Calvin C. Ainsworth, Bruce D. Mcveety, Steven C. Smith, John M. Zachara
Transformation Of 1-Aminonapththalene At The Surface Of Smectite Clays, Calvin C. Ainsworth, Bruce D. Mcveety, Steven C. Smith, John M. Zachara
US Department of Energy Publications
One-aminonaphthalene is sorbed onto the Na-saturated smectite clays, montmorillonite and hectorite, by cation exchange. In the presence of Fe3+ either in the clay structure or on the clay surface, sorption is followed by the formation of a blue-colored complex, with the continuous disappearance of aminonaphthalene from solution and the clay surface. The rate of aminonaphthalene disappearance decreases as pH increases. With time, four major products that appear to be structural isomers of N(4- aminonaphthyl)-1-naphthylamine are produced. A simplified model of this transformation is suggested to be the oxidation by Fe3+ of sorbed aminonaphthalene forming a radical cation-clay complex. …